Origin of dolomite in the Late Jurassic platform carbonates,Bolkar Mountains,Central Taurides,Turkey: Petrographic and geochemical evidence

The Late Jurassic-early Senonian Cehennemdere Formation extending in an E-W direction in a wide area at the south of the Bolkar Mountains (Central Taurides, Turkey) is composed of platform carbonates. The formation was deposited in an environment that was being transformed from a shallow carbonate platform to an open shelf and a continental slope, and was buried until late Paleocene uplift. The formation, with a thickness of about 360 m, was chiefly developed as textures consisting of mudstone and wackestone and has been commonly dolomitized. Based on petrographic and geochemical properties, four types of replacement dolomites and two types of dolomite cements were distinguished. Replacement dolomite (RD), which is cut by low-amplitude stylolites developed as (1) fine crystalline planar-s dolomite (RD1); (2) medium crystalline planar-s dolomite (RD2); (3) medium-coarse crystalline planar-e dolomite (RD3) and; (4) coarse crystalline planar-s (e) dolomite (RD4). Two types of dolomite cements (CD) observed in low abundance and overlie low-amplitude stylolites: (1) coarse crystalline dolomite cement (CD1) filling dissolution voids and fractures in RD1 dolomites, and; (2) rim dolomite cement (CD2) that commonly develops on the space-facing surfaces of RD4 dolomite. Replacement dolomites are non-stoichiometric (Ca_54–59Mg_41–46), have similar geochemical properties, and are generally dull red/non luminescent in appearance. Replacement dolomite is represented by δ¹⁸O values from −4.5 to −0.5‰ VPDB, δ¹³C values of −0.7 to 2.7‰ VPDB, and ⁸⁷Sr/⁸⁶Sr ratios ranging from 0.707178 to 0.707692. Petrographic and geochemical data indicate that replacement dolomite (particularly RD2, RD3, and RD4 dolomite) was formed at shallow-intermediate burial depths during the Late Jurassic-Early Cretaceous, from seawater and/or from slightly modified seawater. The replacement dolomite (RD) was then recrystallized at increased burial depths and temperatures. Dolomite cements are similar to replacement dolomites in that they are non-stoichiometric (Ca₅₅Mg₄₅) and have similar trace element compositions. CD1 dolomite, which cuts low-amplitude stylolites, was formed during intermediate to deep burial following stylolite development. CD2 dolomite was precipitated in intercrystal pores in association with RD4 dolomite. Remaining pore space was filled with bitumen.     

Water and sediment quality assessment in the mid-Black Sea coast of Turkey using multivariate statistical techniques

The aim of this study was to investigate the water and sediment quality in the mid-Black Sea coast of Turkey. The samples were collected from six stations during 2007. Investigated parameters were total carbon (TC), total inorganic carbon (TIC), total organic carbon (TOC), ammonium-nitrogen (NH₄-N), nitrate-nitrogen (NO₃-N), nitrite-nitrogen (NO₂-N), total phosphorus (TP), sulphate, total hardness, methylene blue active substances (MBAS), phenol, adsorbable organic halogens (AOX), dissolved oxygen (DO), pH and electrical conductivity (EC) in water samples and TC, TIC, TOC, TP, pH, electrical conductivity (EC), redox potential (Eh) and water content (WC) in sediment samples. Different multivariate statistical techniques were used to evaluate variations in surface water and sediment quality. Principal component analysis helped in identifying the factors or sources responsible for water and sediment quality variations. Five factors were found responsible for 87.63% of the total variance in the surface waters. In sediments, three factors explained 84.73% of the observed total variance. Cluster analysis classified the monitoring sites into two groups based on similarities of water and sediment quality characteristics.     

Spatial Heating Monthly Degree-Day Features and ClimatologicPatterns in Turkey

Summary  Degree-days as a measure of accumulated temperature deviations from a base temperature have many practical applications in various human related activities such as home cooling, heating, plant growth in agriculture and power generation in addition to energy requirement. Long temperature records are necessary for their reliable estimations at given stations. In this paper, degree-day measure has been applied to monthly temperature records for systematically changed base temperature values from − 25 °C to + 35 °C with 5 °C increments at 255 meteorology stations in Turkey. The results are represented in the form of spatial degree-day distribution maps, which are then related to various climatic, meteorological and topographic features of Turkey. For instance, free surface water bodies in forms of surrounding seas, lakes and rivers insert retardation in the expansion of heating degree-days over large regions. On the other hand, cold air penetration from polar regions in the northeastern Turkey originating from Siberia appears at moderate base temperature heating degree-days. Received August 20, 1998 Revised June 21, 1999     

Producing forest fire susceptibility map via multi-criteria decision analysis and frequency ratio methods

Natural Hazards - Located in the Mediterranean basin, one of the world’s leading places in terms of forest fires, Turkey is one of the countries where forest fires are experienced very often...     

Comparison of GPS TEC with modelled values from IRI 2016 and IRI-PLAS over Istanbul,Turkey

The Total Electron Content (TEC) prediction performances of the empirical IRI model and IRI-PLAS model were investigated by comparing the GPS-based TEC values provided by the IONOLAB group. TEC values were obtained on equinox (March 21 and September 23) and solstice (June 21, and December 21) days in low (2009), medium (2012) and high (2015) solar activity periods at Istanbul, Turkey. The prediction performances of the models were statistically analyzed based on the differences between the GPS-TEC and the empirical models, considering the maximum and minimum deviations, the correlation analysis and the root mean square error (RMSE). As a result of the investigation, it is seen that the empirical models have similar predictive performances when the plasmaspheric effects are neglected, and the IRI-PLAS estimations are generally a little closer to the observed GPS-TEC values than all options of IRI-2016 model. Also, it can be said that “IRI2001”, one of the IRI-2016’s “topside” options, can make better predictions than other options and “IG” solar proxy option of IRI-PLAS model is a more appropriate option than the others in TEC calculations over Istanbul, Turkey.     

Upper crustal Poisson’s ratio and coda-wave attenuation beneath Eastern Anatolia

The attenuation of seismic waves reflects the elastic nature of the media within which the waves propagate. In this study, we calculate the Coda-Q(Q_c), frequency dependence(η), Vp/Vs and Poisson's(υ) ratios by using 2621 vertical component seismograms generated by 987 earthquakes recorded by 13 seismic stations in Eastern Anatolia, and creat a 2-D seismic tomographic Q_c model for the region. The obtained model provides significant information for exploring the boundaries of adjacent tectonic units within the upper crust and interpreting their dynamic characteristics. The 2-D Q_c model and the other parameters are consistent with the seismotectonic features of Eastern Anatolia. Highly heterogeneous Q_c values are observed in the study area dividing it into north-south directed bands of low and high attenuation. The highest η values were obtained beneath the northwestern and eastern parts of the study region. Clear, high and low υ values are obtained in the western and eastern parts of the study area, respectively. The spatial variations in the measured parameters are consistent with many geophysical observations including low Pn velocities, efficient Sn blockage, high heat flow, and widespread volcanism. Different upper crustal thicknesses and inhomogeneous stress distribution along the East and North Anatolian Fault Zones may also contribute to the observed heterogeneities.     

Toxic Effects of Copper‐Based and Synthetic Organic Pesticides on Activated Sludge

Toxic effects of five commonly used pesticides on the biomass of a municipal activated sludge system were determined on the basis of the reduction in the oxygen uptake rate (OUR) and specific oxygen uptake rate (SOUR). Toxicity levels of the selected pesticides were determined by employing a modified OECD 209 (Organisation for Economic Cooperation and Development) method which was performed as batch experiments using a respirometer. Copper sulphate (CuSO₄ · 5 H₂O), copper oxychloride (Cu₂Cl(OH)₃), copper calcium oxychloride (CaCu₃Cl₂(OH)₆) as copper‐based pesticides and chlorsulphuron (C₁₂H₁₂ClN₅O₄S), 2,4‐dichlorophenoxyacetic acid (2,4‐D) (C₈H₆Cl₂O₃) as synthetic organic pesticides were selected for the experiments. The EC₅₀ values were determined to be 78, 249 and 281 mg/L for CuSO₄ · 5 H₂O, Cu₂Cl(OH)₃ and CaCu₃Cl₂(OH)₆, respectively. Corresponding values for C₁₂H₁₂ClN₅O₄S and 2,4‐D were 860 and 3664 mg/L, respectively. Results indicated that toxicity effects of copper‐based pesticides were higher than that of synthetic organic pesticides. CuSO₄ · 5 H₂O was found to exert the highest toxicity among the copper‐based pesticides, whereas, C₁₂H₁₂ClN₅O₄S was determined to be the most toxic among the organic pesticides on activated sludge biomass.     

Geological evolution of the Gulf of Saros,NE Aegean Sea

 The Gulf of Saros is an Upper Miocene transtensional basin in NW Anatolia, formed by the interaction between the North Anatolian Fault and the N-S extensional tectonic régime of the Aegean. The present configuration of the basin evolved mainly during the Plio-Quaternary under the increased activity of the North Anatolian Fault. During the late Miocene-late Quaternary, no sedimentation took place on the shelves. After this long hiatus, an important change in tectonic style about 0.2 Ma BP allowed sedimentation to resume in the gulf. Received: 14 February 1997 / Revision received: 12 November 1997