The non‐igneous genesis of angrites: Support from trace element distribution between phases in D'Orbigny

Abstract— D'Orbigny is an exceptional angrite. Chemically, it resembles other angrites such as Asuka‐881371, Sahara 99555, Lewis Cliff (LEW) 87051, and LEW 86010, but its structure and texture are peculiar. It has a compact and porous lithology, abundant glasses, augite‐bearing druses, and chemical and mineralogical properties that are highly unusual for igneous rocks. Our previous studies led us to a new view on angrites: they can possibly be considered as CAIs that grew to larger sizes than the ones we know from carbonaceous chondrites. Thus, angrites may bear a record of rare and special conditions in some part of the early solar nebula. Here we report trace element contents of D'Orbigny phases. Trace element data were obtained from both the porous and the compact part of this meteorite. We have confronted our results with the popular igneous genetic model. According to this model, if all phases of D'Orbigny crystallized from the same system, as an igneous origin implies, a record of this genesis should be expressed in the distribution of trace elements among early and late phases. Our results show that the trace element distribution of the two contemporaneous phases olivine and plagioclase, which form the backbone of the rock, seem to require liquids of different composition. Abundances of highly incompatible elements in all olivines, including the megacrysts, indicate disequilibrium with the bulk rock and suggest liquids very rich in these elements (>10,000 x CI), which is much richer than any fractional crystallization could possibly produce. In addition, trace element contents of late phases are incompatible with formation from the bulk system's residual melt. These results add additional severe constraints to the many conflicts that existed previously between an igneous model for the origin of angrites and the mineralogical and chemical observations. This new trace element content data, reported here, corroborate our previous results based on the shape, structure, mineralogy, chemical, and isotopic data of the whole meteorite, as well as on a petrographic and chemical composition study of all types of glasses and give strength to a new genetic model that postulates that D'Orbigny (and possibly all angrites) could have formed in the solar nebula under changing redox conditions, more akin to chondritic constituents (e.g., CAIs) than to planetary differentiated rock.     

Response of unconfined turbidity current to normal‐fault topography

Turbidity currents descending the slopes of deep‐water extensional basins or passive continental margins commonly encounter normal‐fault escarpments, but such large‐magnitude phenomena are hydraulically difficult to replicate at small scale in the laboratory. This study uses advanced computational fluid dynamics numerical simulations to monitor the response of large, natural‐scale unconfined turbidity currents (100 m thick and 2000 m wide at the inlet gate) to normal‐fault topography with a maximum relief of nearly 300 m. For comparative purposes, the turbidity current is first released on a non‐faulted pristine slope of 1·5° (simulation model 1). The expanding and waxing flow bypasses the slope without recognizable deposition within the visibility limit of 8 vol.% sand grain packing. Similar flow is then released towards the tip (model 2) and towards the centre (model 3) of a normal‐fault escarpment. In both of these latter models, the sand carried by flow tends to be entrapped in four distinct depozones: an upslope near‐gate zone of flow abrupt expansion and self‐regulation; a flow‐transverse zone at the fault footwall edge; a flow‐transverse zone at the immediate hangingwall; and a similar transverse zone near the crest of the hangingwall counter‐slope, where some of the deposited sand also tends to be reshuffled to the previous zone by a secondary reverse underflow. The near‐bottom reverse flow appears to be generated on a counter‐slope of 1·1°, increased to 2·0° by deposition. The Kelvin–Helmholtz interface instability plays an important role by causing three‐dimensional fluctuations in the flow velocity magnitude and sediment concentration. The thick deposits of large single‐surge flows may thus show hydraulic fluctuations resembling those widely ascribed to hyperpycnal flows. The study indicates further that the turbiditic slope fans formed on such fault topographies are likely to be patchy and hence may differ considerably from the existing slope‐fan conceptual models when it comes to the spatial prediction of main sand depozones.     

Stable carbon isotope distribution of particulate organic matter in the ocean: a model study

The stable carbon isotopic composition of particulate organic matter in the ocean, δ¹³C_POC, shows characteristic spatial variations with high values in low latitudes and low values in high latitudes. The lowest δ¹³C_POC values (−32‰ to −35‰) have been reported in the Southern Ocean, whereas in arctic and subarctic regions δ¹³C_POC values do not drop below −27‰. This interhemispheric asymmetry is still unexplained. Global gradients in δ¹³C_POC are much greater than in δ¹³C_DIC, suggesting that variations in isotopic fractionation during organic matter production are primarily responsible for the observed range in δ¹³C_POC. Understanding the factors that control isotope variability is a prerequisite when applying δ¹³C_POC to the study of marine carbon biogeochemistry. The present model study attempts to reproduce the δ¹³C_POC distribution pattern in the ocean. The three-dimensional (3D) Hamburg Model of the Oceanic Carbon Cycle version 3.1 (HAMOCC3.1) was combined with two different parametrizations of the biological fractionation of stable carbon isotopes. In the first parametrization, it is assumed that the isotopic fractionation between CO₂ in seawater and the organic material produced by algae, _P, is a function of the ambient CO₂ concentration. The two parameters of this function are derived from observations and are not based on an assumption of any specific mechanism. Thus, this parametrization is purely empirical. The second parametrization is based on fractionation models for microalgae. It is supported by several laboratory experiments. Here the fractionation, _P, depends on the CO₂ concentration in seawater and on the (instantaneous) growth rates, μ_i, of the phytoplankton. In the Atlantic Ocean, where most field data are available, both parametrizations reproduce the latitudinal variability of the mean δ¹³C_POC distribution. The interhemispheric asymmetry of δ¹³C_POC can mostly be attributed to the interhemispheric asymmetry of CO₂ concentration in the water. However, the strong seasonal variations of δ¹³C_POC as reported by several authors, can only be explained by a growth rate-dependent fractionation, which reflects variations in the cellular carbon demand.     

近期博斯腾湖水位变化及其原因分析

新疆博斯腾湖1987年以来湖泊水位的变化(上升)与主要补给河流开都河径流量的变化有直接关系, 而这与发源于天山中段降水和高山冰雪融水的河流, 受到气候变化影响很大有关. 全球变化研究结果显示, 中亚干旱区是全球温度上升幅度较大的地区. 当地的气象资料表明, 过去20 a年平均温度明显升高的趋势, 对水资源储量和补给来源影响深远.     

Measurement of the radius of Mercury by radio occultation during the MESSENGER flybys

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft completed three flybys of Mercury in 2008–2009. During the first and third of those flybys, MESSENGER passed behind the planet from the perspective of Earth, occulting the radio-frequency (RF) transmissions. The occultation start and end times, recovered with 0.1 s accuracy or better by fitting edge-diffraction patterns to the RF power history, are used to estimate Mercury's radius at the tangent point of the RF path. To relate the measured radius to the planet shape, we evaluate local topography using images to identify the high-elevation feature that defines the RF path or using altimeter data to quantify surface roughness. Radius measurements are accurate to 150 m, and uncertainty in the average radius of the surrounding terrain, after adjustments are made from the local high at the tangent point of the RF path, is 350 m. The results are consistent with Mercury's equatorial shape as inferred from observations by the Mercury Laser Altimeter and ground-based radar. The three independent estimates of radius from occultation events collectively yield a mean radius for Mercury of 2439.2±0.5 km.     

Evidence of magmatic CO2-rich fluids in peraluminous graphite-bearing leucogranites from Deep Freeze Range (northern Victoria Land,Antarctica)

Fine-grained peraluminous synkinematic leuco-monzogranites (SKG), of Cambro-Ordovician age, occur as veins and sills (up to 20–30 m thick) in the Deep Freeze Range, within the medium to high-grade metamorphics of the Wilson Terrane. Secondary fibrolite + graphite intergrowths occur in feldspars and subordinately in quartz. Four main solid and fluid inclusion populations are observed: primary mixed CO₂+H₂O inclusions + Al₂SiO₅ ± brines in garnet (type 1); early CO₂-rich inclusions (± brines) in quartz (type 2); early CO₂+CH₄ (up to 4 mol%)±H₂O inclusions + graphite + fibrolite in quartz (type 3); late CH₄+CO₂+N₂ inclusions and H₂O inclusions in quartz (type 4). Densities of type 1 inclusions are consistent with the crystallization conditions of SKG (750°C and 3 kbar). The other types are post-magmatic: densities of type 2 and 3 inclusions suggest isobaric cooling at high temperature (700–550°C). Type 4 inclusions were trapped below 500°C. The SKG crystallized from a magma that was at some stage vapour-saturated; fluids were CO₂-rich, possibly with immiscible brines. CO₂-rich fluids (±brines) characterize the transition from magmatic to post-magmatic stages; progressive isobaric cooling (T<670°C) led to a continuous decrease off _{O 2} can entering in the graphite stability field; at the same time, the feldspars reacted with CO₂-rich fluids to give secondary fibrolite + graphite. Decrease ofT andf _{O 2} can explain the progressive variation in the fluid composition from CO₂-rich to CH₄ and water dominated in a closed system (in situ evolution). The presence of N₂ the late stages indicates interaction with external metamorphic fluids.Contribution within the network Hydrothermal/metamorphic water-rock interactions in crystalline rocks: a multidisciplinary approach on paleofluid analysis. CEC program: Human Capital and Mobility     

A 1.78 Ga large igneous province in the North China craton: The Xiong'er Volcanic Province and the North China dyke swarm

The 1.78 Ga Xiong'er Volcanic Province (XVP) and coeval North China giant mafic Dyke Swarm (NCDS) are the most important magmatic events occurring after the amalgamation of the North China craton (NCC). The XVP consists of 3–7 km of extrusive volcanics and some feeder dykes/sills located along the southern margin of the NCC and extending over an area > 0.06 M km². Compositions vary from basalt to rhyolite, but are predominantly intermediate in terms of silica content. There are also minor sedimentary intercalations and pyroclastic units. The sedimentary interlayers indicate an environment changing from continental-facies to oceanic-facies up-section. The XVP is characterized by fractional crystallization from an EM I type mantle source, and both continental arc (Andean-type) and rift environments have been proposed. The NCDS is widespread in the central NCC with an outcrop area > 0.1 M km², and are exposed at variable depths up to 20 km (deepest in the north). Dyke compositions vary from basalt to andesite and dacite, but are dominantly mafic, and comprise two series of magmatism. Previous studies revealed that the NCDS recorded assimilation and fractional crystallization of an EM I type magma source, with a minor DM contribution in the younger magmas. Both syn-collisional and intra-continental anorogenic environments have been proposed. Spatial and petrogenic correlations suggest a cogenetic relationship between the NCDS and XVP, and considered together, they define a Large Igneous Province (LIP) of > 0.1 M km² in area and > 0.1 M km³ in volume, which is also notable for its continuous compositional range from mafic to felsic (with no gap at intermediate compositions). The petrology is explained by a common magma source that undergoes a silica-poor and iron-enriched fractionation trend at depth followed by a silica-rich and iron-poor fractionation trend in shallow-level magma conduits (dykes) and surface lavas. A mantle plume is favored as the cause of this  1.78 Ga North China LIP.     

The Compositions of Six Chinese Ordinary Chondrites and Element Distributions in Their Different Phases

Six Chinese ordinary chondrites (four of them have fallen in recent years and the trace element abundances have not yet been reported for the other two) were examined.The contents of 21 elements (Na,Cr,Mn,Sc,Se,Zn,Br,Ni,Fe,Co,Ir,Cu,Ga,As,Au,Sb,Os,W,Re,Pt,and Ru)in the magnetic fractions and 20 elements (Na,K,Ca,Sc,Cr,Mn,Fe,Co,Ni,Zn,Se,Br,La,Sm,Eu,Yb,Lu,Ir,Au,and As) in the non-magnetic fractions were de-termined by INAA. The results indicate that the 5 H-group chondrites show almost no difference in composition,but they are different from the Zhaodong L-group chondrite in elemental abundance.As a normalized element(relative to CI),the concentrations of Ga in the magnetic fractions can be used to classify ordinary chondrites(H-,L- and LL-group).The bulk composition and modal weight of each component calculated from element concentrations in different phases are in good agreement with the bulk rock analyses presented in the literature.