http://www.sciencedirect.com/science/article/pii/S1674987112001041

Large igneous provinces (LIPs) are considered a relevant cause for mass extinctions of marine life throughout Earth’s history. Their flood basalts and associated intrusions can cause significant release of SO₄ and CO₂ and consequently, cause major environmental disruptions. Here, we reconstruct the long-term periodic pattern of LIP emplacement and its impact on ocean chemistry and biodiversity from δ³⁴S_sulfate of the last 520 Ma under particular consideration of the preservation limits of LIP records. A combination of cross-wavelet and other time-series analysis methods has been applied to quantify a potential chain of linkage between LIP emplacement periodicity, geochemical changes and the Phanerozoic marine genera record. We suggest a mantle plume cyclicity represented by LIP volumes (V) of V = ?(350–770) × 10³ km³ sin(2πt/170 Ma) + (300–650) × 10³ km³ sin(2πt/64.5 Ma + 2.3) for t = time in Ma. A shift from the 64.5 Ma to a weaker ～28–35 Ma LIP cyclicity during the Jurassic contributes together with probably independent changes in the marine sulfur cycle to less ocean anoxia, and a general stabilization of ocean chemistry and increasing marine biodiversity throughout the last ～135 Ma. The LIP cycle pattern is coherent with marine biodiversity fluctuations corresponding to a reduction of marine biodiversity of ～120 genera/Ma at ～600 × 10³ km³ LIP eruption volume. The 62–65 Ma LIP cycle pattern as well as excursion in δ³⁴S_sulfate and marine genera reduction suggest a not-yet identified found LIP event at ～440–450 Ma.     

Physical constraints on impact melt properties from Lunar Reconnaissance Orbiter Camera images

Impact melt flows exterior to Copernican-age craters are observed in high spatial resolution (0.5 m/pixel) images acquired by the Lunar Reconnaissance Orbiter Camera (LROC) Narrow Angle Camera (NAC). Impact melt is mapped in detail around 15 craters ranging in diameter from 2.4 to 32.5 km. This survey supports previous observations suggesting melt flows often occur at craters whose shape is influenced by topographic variation at the pre-impact site. Impact melt flows are observed around craters as small as 2.4 km in diameter, and preliminary estimates of melt volume suggest melt production at small craters can significantly exceed model predictions. Digital terrain models produced from targeted NAC stereo images are used to examine the three-dimensional properties of flow features and emplacement setting, enabling physical modeling of flow parameters. Qualitative and quantitative observations are consistent with low-viscosity melts heated above their liquidii (superheated) with limited amounts of entrained solids.     

Detection and Classification of Phytoplankton Deposits Along an Estuarine Gradient

Phytoplankton deposition onto sediments affects trophic structures, sedimentary nutrient fluxes, and dissolved oxygen concentrations in coastal ecosystems. Deposition can occur as distinct events that are highly variable over space and time, necessitating detection methods that have similarly high resolution. We present an assessment of a novel rapid detection method that combines water-column and benthic fluorometry with surficial sediment sampling to identify phytoplankton deposition, as implemented in a 2-year study of a Florida estuary (24?monthly collections at 14 locations). Maximum water-column chlorophyll concentration, average benthic chlorophyll fluorescence, and the proportion of centric vs. pennate diatoms at the sediment?Cwater interface were each fitted to sine functions to represent phytoplankton bloom cycles. The phase offsets among the three fitted sine functions were varied to maximize fit to the 336 observations. The fitted cycles were divided into four classes that separate dominance by benthic microalgae from early, late, and post-phytoplankton depositional states. Best-fitting cycles for the proportion of centric diatoms were consistently offset from water-column chlorophyll cycles, indicating peak deposition occurred after peak phytoplankton blooms. Phytoplankton deposition dominated the upstream region of the studied estuary and was associated with reduced dissolved oxygen concentrations. Benthic algae dominated in downstream regions, particularly during low freshwater flow conditions when light absorption by colored dissolved organic matter was low. This approach produced repeatable and consistent patterns that agreed with expected relationships and was practical for sampling with high spatial and temporal resolution.     

Physical characterization of a suite of Buzzard Coulee H4 chondrite fragments

On November 20, 2008, the Buzzard Coulee H4 chondrite fell to Earth outside of Lloydminster, Alberta, Canada. Eighteen fresh samples obtained by the National Meteorite Collection of Canada, ranging from 8.80 to 109.14 g, were investigated in this study. Physical properties of the samples were first obtained using a suite of nondestructive techniques. The bulk density (Archimedean bead method: 3.48 ± 0.04 g cm^?3; 3‐D laser imaging: 3.46 ± 0.03 g cm^?3; micro‐computed tomography: 3.44 ± 0.03 g cm^?3), porosity (6.2 ± 0.1%), bulk magnetic susceptibility (log χ: 5.364 ± 0.056 × 10^?9 m³ kg^?1 at 825 Hz; 5.329 ± 0.052 × 10^?9 m³ kg^?1 at 19,000 Hz), and other derived magnetic properties (frequency dependence: 8.7 ± 6.2%; degree of anisotropy A%: 22.0 ± 2.0%; ellipsoid shape B%: ?18.7 ± 8.7%) are typical of H chondrites. The coefficient of variation associated with the properties measured directly was low (0.10–1.15%), indicating that the samples are homogenous at the interfragment scale. The study then proceeded with detailed analyses at the intrafragment scale. Visual inspection of micro‐computed tomographic images allowed the identification of an anomalous large clast with low metal content in a fragment. Another fragment exhibited macroscopic shock veins that warranted further examination. These fragments were cut and polished thin sections prepared for petrological analysis by optical and scanning electron microscopy. Based on mineralogical and textural similarities with several chondrules, the large clast was interpreted to be a macrochondrule. In a larger context, this study proposes a protocol for the systematic investigation of extraterrestrial material that can be exported to other new meteorite falls and finds, and specimens from sample return mission.     

Geochemical characteristics of the high- and low-Ti basaltic rocks from the uplifted shoulder of the Ohře (Eger) Rift,Western Bohemia

High-Ti melanephelinite (3.8–5.9 wt% TiO₂), medium-Ti (phono)tephrite (2.7–3.1 wt% TiO₂), and low-Ti olivine melanephelinite/basanite (1.9–2.3 wt.% TiO₂) are subordinate rock types in the central European Cenozoic Volcanic Province. A contrasting melanephelinite to (phono)tephrite series occurs in the Lou?ná–Oberwiesenthal Volcanic Centre (37–28 Ma) and also as satellite volcanic bodies (26–12 Ma) together with olivine melanephelinite/basanite (17–20 Ma) on the southwestern periphery of the Kru?né hory mountains (Erzgebirge). The volcanic rocks intrude the Variscan basement of the uplifted shoulder of the Oh?e/Eger Rift in the Kru?né hory mountains of the Bohemian Massif. Low Mg# (44–59) and Cr, Ni contents and enrichment of LILE, Zr, Hf, Nb, Ta, U, Th and LREE in the high-Ti melanephelinites contrast with the composition of primitive low-Ti olivine melanephelinites/basanites displaying high Mg# (63–74) and high contents of compatible elements. The high-Ti melanephelinites reveal a wide range in initial ⁸⁷Sr/⁸⁶Sr of ca. 0.7034–0.7038 and ε_Nd of 2.4–4.9. The low-Ti melanephelinites show an overlapping range of initial ⁸⁷Sr/⁸⁶Sr of ca. 0.7035–0.7036 and ε_Nd of 4.3–5.5. The large variation in initial ⁸⁷Sr/⁸⁶Sr ratios at similar ε_Nd values in those rock types is interpreted as evidence for melting of metasomatized lithospheric mantle sources comprising K-bearing phases with radiogenic Sr. Modification of the olivine-free alkali basaltic magmas by differentiation or crustal contamination could give rise to the medium-Ti (phono) tephrites. The initial isotope ratios of all samples are consistent with HIMU-mantle sources and contributions from lithospheric mantle. The olivine-free melanephelinitic rocks often contain alkali pyroxenite–ijolite xenoliths with initial ⁸⁷Sr/⁸⁶Sr ratios of ca. 0.7036 and ε_Nd of 3.0. We interpret these xenoliths as samples of an intra-crustal alkali complex derived from similar mantle sources as those for the basaltic volcanic rocks.     

Precise U–Pb baddeleyite ages of mafic dykes and intrusions in southern West Greenland and implications for a possible reconstruction with the Superior craton

The Archaean block of southern Greenland constitutes the core of the North Atlantic craton (NAC) and is host to a large number of Precambrian mafic intrusions and dyke swarms, many of which are regionally extensive but poorly dated. For southern West Greenland, we present a U–Pb zircon age of 2990 ± 13 Ma for the Amikoq mafic–ultramafic layered intrusion (Fiskefjord area) and four baddeleyite U–Pb ages of Precambrian dolerite dykes. Specifically, a dyke located SE of Ameralik Fjord is dated at 2499 ± 2 Ma, similar to a previously reported ⁴⁰Ar/³⁹Ar age of a dyke in the Kangâmiut area. For these and related intrusions of ca. 2.5 Ga age in southern West Greenland, we propose the name Kilaarsarfik dykes. Three WNW-trending dykes of the MD3 swarm yield ages of 2050 ± 2 Ma, 2041 ± 3 Ma and 2029 ± 3 Ma. A similar U–Pb baddeleyite age of 2045 ± 2 Ma is also presented for a SE-trending dolerite (Iglusuataliksuak dyke) in the Nain Province, the rifted western block of the NAC in Labrador. We speculate that the MD3 dykes and age-equivalent NNE-trending Kangâmiut dykes of southern West Greenland, together with the Iglusuataliksuak dyke (after closure of the Labrador Sea) represent components of a single, areally extensive, radiating swarm that signaled the arrival of a mantle plume centred on what is presently the western margin of the North Atlantic craton. Comparison of the magmatic ‘barcodes’ from the Nain and Greenland portions of the North Atlantic craton with the established record from the north-eastern Superior craton shows matches at 2500 Ma, 2214 Ma, 2050–2030 Ma and 1960–1950 Ma. We use these new age constraints, together with orientations of the dyke swarms, to offer a preliminary reconstruction of the North Atlantic craton near the north-eastern margin of the Superior craton during the latest Archaean and early Palaeoproterozoic, possibly with the Core Zone craton of eastern Canada intervening.     

The Vetreny Poyas (Windy Belt) subprovince of southeastern Fennoscandia: An essential component of the ca. 2.5–2.4 Ga Sumian large igneous provinces

Ca. 2.5–2.4 Ga Sumian magmatism is widespread in the Karelia and Kola cratons of Fennoscandia and probably represents at least two intermixed large igneous provinces (LIPs). It is distinct from other Paleoproterozoic LIPs (Jatulian 2.22–2.1 Ga and Ludicovian 2.06–1.96 Ga) elsewhere in the Fennoscandian Shield. A poorly understood portion of Sumian magmatism is the Vetreny Poyas (Windy Belt) subprovince, which covers ∼75,000 km² in southeastern Fennoscandia. This subprovince consists of four genetically related complexes which developed at different levels in the crust: a volcanic complex (komatiitic basaltic lava flows on Golets, Levgora and Myandukha hills, and Victoria lava lake on Levgora hill), a subvolcanic complex (mafic–ultramafic sills and lopoliths including Ruiga, Kirichgora, Kozhozero and Undozero), plutonic complexes (Burakovsky and Vyzhiga) and a dyke complex (gabbronoritic Avdeyevo and Shala dykes and peridotitic Vinela and Koppalozero dykes). Similar patterns are present in other Sumian belts elsewhere in Karelia, for instance in southern Lapland and the Kola Peninsula.     

Geochemical and H-O-Sr-Nd isotope evidence for magmatic processes and meteoric-water interactions in the basal complex of La Gomera, Canary Islands

The plutonic rocks of the Basal Complex of La Gomera, Canary Islands, Spain, were studied by means of major and trace element contents and by H-O-Sr-Nd isotope compositions in order to distinguish primary magmatic characteristics and late-stage alteration products. Deciphering the effects of alteration allowed us to determine primary, plume-related compositions that indicated D- and ¹⁸O-depletion relative to normal upper mantle, supporting the conclusions of earlier studies on the plutonic rocks of Fuerteventura and La Palma. Late-stage alteration took place during the formation of the intrusive series induced by interaction with meteoric water. Inferred isotopic compositions of the meteoric water indicate that the water infiltrated into the rock edifice at a height of about 1500 m above sea level, suggesting the existence of a subaerial volcano which was active during the intrusive activity and that it has been either distroyed or remain buried by later volcanic and landslide events.