Geomorphic controls of perched groundwater interaction with natural ridge-top depressional wetlands

Geographically isolated wetlands (GIWs) are commonly reported as having hardpan or low hydraulic conductivity units underneath that produce perched groundwater, which can sustain surface water levels independently of regional aquifer fluctuations. Despite the potential of GIW-perched aquifer systems to provide important hydrological and ecological functions such as groundwater storage and native amphibian habitat, little research has studied the hydrologic controls and dynamics of these systems. We compared several ridge-top depressional GIW-perched groundwater systems to investigate the role of watershed morphology on hydroregime and groundwater-surface water interaction. Ridge-top depressional wetlands in the Daniel Boone National Forest, Kentucky were chosen because they offer natural controls such as lack of apparent connection to surface water bodies, similar climate, and similar soils. Three wetlands with different topographic slopes and hillslope structures were mapped to distinguish key geomorphic parameters and monitored to characterize groundwater-surface water interaction. Wetlands with soil hummocks and low upland slopes transitioned from infiltration to groundwater discharge conditions in the spring and during storm events. The magnitude and duration of this transition fell along a continuum, where higher topographic slopes and steeper uplands produced comparably smaller and shorter head reversals. This demonstrates that ridge-top GIW-perched groundwater systems are largely sensitive to the runoff-recharge relationship in the upland area which can produce significant groundwater storage on a small-scale.     

Organic and inorganic matter in Louisiana coastal waters: Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi regions

Chromophoric dissolved organic matter (CDOM) spectral absorption, dissolved organic carbon (DOC) concentration, and the particulate fraction of inorganic (PIM) and organic matter (POM) were measured in Louisiana coastal waters at Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi River locations, in 2007-2008. The range of CDOM was 0.092 m⁻¹ at Barataria in June 2008 to 11.225 m⁻¹ at Mississippi in February 2008. An indicator of organic matter quality was predicted by the spectral slope of absorption coefficients from 350 to 412 nm which was between 0.0087 m⁻¹ at Mississippi in May 2008 and 0.0261 m⁻¹ at Barataria in June 2008. CDOM was the dominant component of light attenuation at Terrebonne and Barataria. Detritus and CDOM were the primary components of light attenuation at Vermilion, Atchafalaya, and Mississippi. DOC ranged between 65 and 1235 μM. PIM ranged between 1.1 and 426.3 mg L⁻¹ and POM was between 0.3 and 49.6 mg L⁻¹.     

Biomarker responses in pelagic and benthic fish over 1 year following the Hebei Spirit oil spill (Taean, Korea)

After the Hebei Spirit oil spill incident (7th December, 2007) in the west coast of Korea, contamination of biliary PAH metabolite and hepatic biomarkers in a pelagic and a benthic fish was monitored for 1 year. Concentrations of 16 PAHs and alkylated PAHs in fish muscle were highest (22.0 ng/g d.w. for 16 PAHs and 284 ng/g d.w. for alkylated PAHs) at 5 days after the spill and then decreased rapidly to background levels at 11 months after the spill. Fish from the oiled site had elevated biliary PAH metabolite concentrations immediately after the spill; these declined steadily in both species, but were still above reference site concentrations 2 months after the spill. Oiled-site fish showed hepatic CYP 1A induction whose trend closely followed those of biliary PAH metabolite concentrations, implying continuous exposure to PAHs. Brain acetylcholinesterase activity was not related to oil exposure.     

Archaeol as a methanogen biomarker in ombrotrophic bogs

In order to develop new tools in the reconstruction of microbiological processes in ancient continental settings, we determined the concentration of archaeol and sn-2-hydroxyarchaeol in four Holocene ombrotrophic peatlands, spanning a range of European climate zones. Neither ether lipid was present in the aerobic acrotelm peat, consistent with an origin from anaerobic archaea, presumably methanogens. At the depth of the maximum seasonal water table, archaeol and sn-2-hydroxyarchaeol concentration markedly increased at all four sites, again consistent with an anaerobic source, but differed strongly among sites. The differences apparently reflect a combination of vegetation - ericaceous and graminoid plants as opposed to Sphagnum spp. and other mosses lacking root systems - and temperature influence on methanogenesis. In particular, low ether lipid concentrations in Finland probably reflect the lack of vascular vegetation possessing well-developed root systems, together with low mean annual temperature. Similarly low concentrations of archaeol and sn-2-hydroxyarchaeol in a German bog likely result from winter temperatures below 0 °C and a relatively shorter growing season. The occurrence of sn-2-hydroxyarchaeol is limited to a narrow and shallow depth range, indicating that it is poorly preserved, but archaeol persists throughout the cores. Decoupling the concentration of archaeol and the more labile sn-2-hydroxyarchaeol below ca. 50 cm suggests that the former records fossil biomass rather than living biomass. If so, then downcore variation in archaeol concentration likely reflects past changes in methane cycling, and archaeol, pending further developmental research, could serve as a new tool for reconstruction of past peatland biogeochemistry.     

Pyrolysis GC-MS as a rapid screening tool for determination of peat-forming plant composition in cores from ombrotrophic peat

Peat cores provide decadal to centennial records of climatic and environmental change, including evidence for human/environment interaction. Existing palaeoenvironmental proxies (macrofossils, pollen, humification, testate amoebae, lipid composition) require multiple laboratory preparation steps and may be subject to differential preservation that can limit production of a continuous time series. The potential for pyrolysis gas-chromatography-mass-spectrometry (Py-GC-MS) to be applied to bulk peat samples is investigated here. The only preparatory step required was freeze drying. Analysis of a range of important peat-forming plants demonstrates that Sphagnum moss species are unique in containing the pyrolysis product of sphagnum acid, 4-isopropenylphenol. In contrast, non-Sphagnum species are rich in lignin pyrolysis products, which are absent from Sphagnum. The presence of these pyrolysis markers is reflected in bulk peat composition and tested here using archives from Bolton Fell Moss and Butterburn Flow (UK), Kontolanrahka (Finland) and Bissendorfer Moor (Germany). A ratio between 4-isopropenylphenol and two lignin pyrolysis products is proposed as a proxy for total Sphagnum input to peat archives and shows potential for use as a rapid screening tool for characterising bulk peat composition before more intensive analysis.     

Palynology of organic beds below Devensian glacigenic sediments at Pen-y-bryn,Gwynedd, North Wales

Pollen diagrams from organic facies overlain by glacigenic sediments at Pen-y-bryn, North Wales (53°7′N, 4°16′W), suggest that it is the first locality in the British Isles to provide evidence for several Devensian interstadials prior to Devensian stadial glaciation(s). The evidence is not, however, unequivocal. At least two main episodes of organic sedimentation are indicated, separated by an interval of uncertain duration. One eposide records a Pinus-Picea-Betula forest. A second, possibly later, event, with tree pollen less than 10% of total land pollen (TLP), suggests a cool, largely unforested environment. A third episode, with tree pollen up to 25% of TLP, may be related to the latter or be of intermediate age, whereas a fourth and later episode of organic accumulation may be of reworked material. Radiocarbon dating of organic deposits and of a wood macrofossil enclosed in basal till is inconclusive, as is preliminary uranium-series dating. The principal biogenic episodes may correlate with Oxygen Isotope Substages 5c and 5a, but as the pollen records reflect facies floras, the correlation remains tentative; it is also possible that other temperate periods are recorded. Further resolution of the chronostratigraphy is required to help clarify the problematic correlation of interstadial and stadial events in northwest Europe and to correlate more accurately the biogenic and glacigenic facies at Pen-y-bryn with their Pleistocene equivalents elsewhere.     

Mineralogy,microtexture, and composition of shock‐induced melt pockets in thi Los Angeles basaltic shergottite

Abstract— Analytical electron microscopy of shock features in the basaltic shergottite Los Angeles (stone 1) reveals: 1) shock recorded in the bulk sample; and 2) localized pressure and temperature excursions that have generated melt pockets up to 4 mm in diameter. Bulk shock effects include microfaulting (offsets 1–200 μm), mosaicism, deformed exsolution lamellae and planar fracturing in pyroxene, undulose extinction in whitlockite, mechanical twinning in titanomagnetite and ilmenite, and the transformation of plagioclase to maskelynite (≤4% remnant reduced birefringence). The pressure estimates for bulk shock are 35–40 GPa. Localized shock excursions have generated three types of discrete melt zones (0.07 times 1.3 mm to 3.0 times 3.5 mm apparent diameter) possessing glassy to microcrystalline groundmasses. These melt pockets are differentiated on the basis of size, clast volume, and degree of crystallization and vesiculation. Melt veins and melt dikelets emanate from the melt pockets up to 3 mm into the host rock but do not necessarily connect with other melt pockets. The melt pockets were generated by pressure‐temperature excursions of 60–80 GPa and 1600–2000°C, resulting in discrete melting of adjacent host rock minerals at grain boundary margins. Concentric zoning in the margins of clinopyroxenes coincides with a progressive reduction in birefringence as melt pockets are approached. This suggests that the shock excursions were focused as point sources in the wake of the shock front that induced bulk damage.     

Estimated supply of RED credits 2011–2035

Previous attempts to estimate the supply of greenhouse gas emission reductions from reduced emissions from deforestation (RED) have generally failed to incorporate policy developments, country-specific abilities and political willingness to supply offsets for developed countries’ emissions. To address this, we estimate policy-appropriate projections of creditable emission reductions from RED. Two global forest carbon models are used to examine major assumptions affecting the generation of credits. The results show that the estimated feasible supply of RED credits is significantly below the biophysical mitigation potential from deforestation. A literature review identified an annual RED emission reduction potential between 1.6 and 4.3 Gt CO₂e. Feasible RED supply estimates applying the OSIRIS model were 1.74 Gt CO₂e annually between 2011 and 2020, with a cumulative supply of 17.4 Gt CO₂e under an ‘own-efforts’ scenario. Estimates from the Forest Carbon Index were very low at $5/t CO₂e with 8 million tonne CO₂e annually, rising to 1.8 Gt CO₂e at $20/t CO₂e. Cumulative abatement between 2011 and 2020 was 9 billion Gt CO₂e ($20/t CO₂e). These volumes were lower, sometimes dramatically, at prices of $5/t CO₂e suggesting a non-linear supply of credits in relation to price at a low payment level. For policy makers, the results suggest that inclusion of RED in a climate framework increases abatement potential, although significant constraints are imposed by political and technical issues.