Twenty-two hornblendes separated from amphibolites and granulites of the Grenville Orogen of Ontario have been quantitatively analyzed for major and minor elements by electron microprobe, for FeO/Fe
2O
3 by wet chemistry, and for H
2O by manometric measurement as H
2. Hornblende formulae were calculated on the basis of 24O+OH+Cl+F. Most samples are magnesio-hornblendes, ferroan pargasitic hornblendes and ferroan hastingsitic hornblendes, with weight fractions of Fe
3+/(Fe
2++Fe
3+) ranging from 0.15 to 0.50. An oxy-amphibole component of 0–25 mol%, with an average value of 17 mol%, is obtained for these complete analyses. When compared with structural formulae determined solely from microprobe data, normalization based on 13=Si+Ti+Al+Fe+Mn+Mg cations provides the best approximation to hornblende formulae calculated from the complete analyses. Less satisfactory agreement is obtained from a normalization scheme based on 15=Si+Ti+Al+Fe+Mn+Mg+Ca, while worst agreement is obtained from normalization to 23 oxygens assuming all Fe is Fe
2+. No normalization scheme based on microprobe data alone consistently replicates the measured FeO, Fe
2O
3, and H
2O; accurate determination of these values requires complete chemical analysies. Ionic solution models previously have been proposed to evaluate the activity of Ca
2Mg
5Si
8 O
22(OH)
2(
a
Trem) in hornblende for use in equilibria that constrain the activity of H
2O (
a
H
2O) in igneous and metamorphic rocks. Application of ionic models to typical hornblendes produces low
a
Trem (usually<0.01), consequetly yielding extremely low
a
H
2O. If an oxy-amphibole component is present, the calculated
a
Trem and H
2O is further reduced. An oxy-amphibole component of 25% reduces the calculated H
2O activity and that of
any hydroxyl-amphibole component by 50% below that calculated with simplified assumptions regarding
X
OH in the hydroxyl site (i.e.,
X
OH=1, or
X
OH=1–
X
Cl–
X
f). Thus, methods of amphibole normalizations appear to have a substantial effect on calculated amphibole and H
2O activites. Before
quantitative hornblende thermobarometry can be calibrated and applied, the amounts of FeO, Fe
2O
3 and H
2O must be measured in order to fully characterize hornblende solid solutions.Contribution No. 478 from the Mineralogical Laboratory, University of Michigan
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