Parameter studies on the rheology of limestone slurries

The influences of solids concentration, molecular weight of dispersant, particle size and distribution, and temperature on the rheological behaviour of limestone slurries have been investigated. The results reveal that when the solids concentration of a limestone slurry (< 100 μm) is increased from 60 wt.% (35.71 vol.%) to 78.5 wt.% (57.49 vol.%), the rheological behaviour of the slurry is transformed from a weakly dilatant characteristic to a pseudoplastic one with a yield stress, which is in combination with a thixotropic property at a higher solids concentration (i.e., ≥ 75 wt.% or 52.63 vol.%). At a certain shear rate, the apparent viscosity and the relative viscosity of the slurry increase exponentially with solids concentration. The extrapolated Bingham yield stress increases rather sharply in a power-law form with increasing solids concentration when the solids concentration of the slurry is larger than 70 wt.% (i.e., 46.36 vol.%). An attainable maximum packing solids fraction (?_m) is predicted as ?_m = 64.6 vol.% at the certain limestone–water suspension system. A polymeric dispersant named Dispersant S40 with a molecular weight of 5500 appears most effective for the reduction of the apparent viscosity of limestone slurry due to its good electrosteric stabilization and effective avoidance of depletion flocculation. The smaller the particle size and the narrower the size distribution, the more evident the pseudoplastic property of limestone slurry is with a larger yield stress and a larger apparent viscosity at a given shear rate in the range of 12 to 1200 s^− 1. Also, a statistic model describes a relationship between the particle size and distribution and the apparent viscosity of the slurries at a given solids concentration (i.e., 70 wt.% or 46.36 vol.%). However, a sufficient additive dosage of Dispersant S40 (i.e., ≥ 0.1 wt.%) significantly decreases or even eliminates the rheological differences of limestone slurries (apparent viscosities and extrapolated yield stresses) resulting from the difference in particle size and distribution. Besides, the apparent viscosity of limestone slurries decreases with increasing temperature in the range of 13 to 55 °C, regardless of the absence or the presence of Dispersant S40.     

Comparison of reduced-order, sequential and variational data assimilation methods in the tropical Pacific Ocean

This paper presents a comparison of two reduced-order, sequential, and variational data assimilation methods: the singular evolutive extended Kalman filter (SEEK) and the reduced 4D-Var (R-4D-Var). A hybridization of the two, combining the variational framework and the sequential evolution of covariance matrices, is also preliminarily investigated and assessed in the same experimental conditions. The comparison is performed using the twin-experiment approach on a model of the tropical Pacific domain. The assimilated data are simulated temperature profiles at the locations of the TAO/TRITON array moorings. It is shown that, in a quasilinear regime, both methods produce similarly good results. However, the hybrid approach provides slightly better results and thus appears as potentially fruitful. In a more nonlinear regime, when tropical instability waves develop, the global nature of the variational approach helps control model dynamics better than the sequential approach of the SEEK filter. This aspect is probably enhanced by the context of the experiments in that there is a limited amount of assimilated data and no model error.     

P-wave velocity structure under the Changbaishan volcanic region, NE China, from wide-angle reflection and refraction data

We present velocity models determined by inverting refracted and reflected arrivals along two active source lines in the Changbaishan volcanic region, NE China. We resolve a prominent low-velocity zone (LVZ) in the crust, with velocities as low as 5.4 km/s. Away from the LVZ, the velocity gradients in the crust are relatively smooth, with average P-wave velocities of about 6.0–6.5 km/s. The Moho is at about 35 km depth, thickening to about 40 km under the Tianchi volcano, and thinning to about 30 km under the LVZ. The LVZ is located about 30–60 km to the north of the summit of the Tianchi volcano (the most recently active volcano in the region), is about 30–75 km in north–south extent, is at most 35 km in east–west extent, and is in the depth range of about 10–25 km below the surface. We use these results to constrain receiver function inversions, and show that the receiver functions in the region are compatible with our findings. With these data alone, the significance of the LVZ in non-unique, although we do not see any evidence to support the presence of partial melt in the crust, and favor the interpretation that the LVZ indicates a residual crustal magma chamber.     

The Spatial Structure of Land Use from 1970–2000 in the Phoenix,Arizona, Metropolitan Area

This article explores the dimensions of rapid urbanization in the Phoenix Standard Metropolitan Statistical Area (SMSA) over the past thirty years with respect to land use change. We devote primary attention to developing an understanding of what land transformations took place, the extent to which they occurred, and where they occurred. Our findings indicate that 32 percent of the Phoenix SMSA changed between 1970 and 2000. More than half of the overall change was from agriculture to some form of urban land use, and although a large percentage of the region remains open desert the parcels of desert are increasingly fragmented. This has significant implications for urban ecology and biodiversity. The growth indicates that rather than a pattern that reflects the agglomeration effects of a polycentric metropolis, the central business district of the City of Phoenix dominates the region. This has implications with respect to employment patterns, traffic congestion, and urban air quality and climate.     

Prograde and retrograde history of the Junction School eclogite,California, and an evaluation of garnet–phengite–clinopyroxene thermobarometry

Quantitative thermobarometry of inclusions in zoned garnet from a Franciscan eclogite block record a counter-clockwise P–T path from blueschist to eclogite and back. Garnet retains prograde zoning from inclusion-rich Alm₅₂Grs₃₀Pyp₆Sps₁₂ cores to inclusion-poor Alm₆₂Grs₂₅Pyp₁₂Sps₁ mantles, with overgrowths of highly variable composition. Barometry using the Waters–Martin version of the garnet–phengite–omphacite thermobarometer yields conditions of 7–15 kbar, 400–500°C (garnet cores), 18–22 kbar, ∼550°C (mantles), and 10–14 kbar, 350–450°C (overgrowths), in agreement with clinozoisite–sphene–rutile–garnet–quartz barometry. These pressures are ∼10–15 kbar less than those obtained using more recent, fully thermodynamic calibrations of the phengite–omphacite–garnet thermobarometer. Low early temperatures suggest that the block was subducted in a thermally mature subduction zone and not at the inception of subduction when prograde temperature is expected to be higher. Franciscan high-grade blocks likely represent crust subducted throughout the history of this convergent margin, rather than only at the inception of the subduction zone.     

Influence of the turbulence closure scheme on the finite-element simulation of the upwelling in the wake of a shallow-water island

A three-dimensional finite-element model is used to investigate the tidal flow around Rattray Island, Great Barrier Reef, Australia. Field measurements and visual observations show both stable eddies developing at rising and falling tide in the wake of the island. The water turbidity suggests intense upwelling able to carry bed sediments upwards. Based on previous numerical studies, it remains unclear at this point whether the most intense upwelling occurs near the centre of the eddies or off the island's tips, closer to the island. All these studies resorted to a very simple turbulence closure, with a zero-equation model whereby the coefficient of vertical viscosity is computed via an algebraic expression. In this work, we aim at studying the influence of the turbulence closure on model results, with emphasis on the prediction of vertical motions. The Mellor and Yamada level 2.5 closure scheme is used and an increase in the intensity of vertical transport is observed. This increase is partly explained by the fact that the Mellor and Yamada model takes into account the hysteresis effect in the time variation of turbulence variables. The influence of the advection of turbulence variables is estimated to be negligible. By a better representation of transient coastal phenomena, the Mellor and Yamada level 2.5 turbulence closure improves the model to a significant degree.