The Fe/ΣFe ratios of MORB glasses and their implications for mantle melting

The Fe³⁺/ΣFe ratio of 104 MORB glasses from the Pacific, the Atlantic, the Indian, and the Red Sea spreading centers have been determined using wet chemical Fe²⁺ analyses and electron microprobe FeO_total measurements. The data provide a new estimate for the MORB oxygen fugacity (fO₂) of 0.41 ± 0.43 (1sigma, N = 100) log units below the fayalite-magnetite-quartz buffer (FMQ), equivalent to a Fe³⁺/ΣFe = 0.12 ± 0.02 (1sigma, N = 104). This new fO₂ estimate is 0.8 log units more oxidized than the average fO₂ proposed by Christie et al. (1986) (FMQ-1.20 ± 0.44; Fe³⁺/ΣFe = 0.07 ± 0.01; N = 87). This slight difference may be related in part to the 3.5% underestimation of the Fe²⁺ concentration determined by Christie et al. (1986) compared with this study. MORB oxygen fugacity does not display any significant difference between the three main oceanic domains, or between enriched and depleted MORB. Yet, the iron red-ox state ratio shows a broad increase during fractional crystallization. Detailed study of magmatic suites highlights the lack of systematic Fe³⁺/ΣFe ratio fractionation during differentiation. Despite the large variations of inferred partial melting degrees (from 5 to 20%), the present data set does not provide any evidence of Fe³⁺/ΣFe relationships with partial melting proxies such as Na_8.0.Based on the Fe³⁺ systematics during partial melting, it is suggested that the oxidation state of MORB reflects a “buffered mantle melting process” resulting in the apparent compatible behavior of Fe³⁺ during partial melting, and in the relatively constant Fe³⁺/ΣFe ratio irrespective of the extent of melting. This result implies that partial melting processes may be open relative to oxygen. We propose a model where the Fe³⁺/ΣFe ratio in the melt is buffered during partial melting. The MORB Fe₂O₃ systematics can be accounted for by using a fO₂ of FMQ-1 that is equivalent to the average fO₂ reported for abyssal peridotites.     

Magnetostratigraphic dating of the Donggutuo and Maliang Paleolithic sites in the Nihewan Basin, North China

A detailed magnetostratigraphic investigation, coupled with rock-magnetic studies, was carried out on a lacustrine sequence in the eastern Nihewan Basin, Northern China, which contains the Donggutuo and Maliang Paleolithic sites. Magnetite and hematite were identified as the main carriers for the characteristic remanent magnetizations. Magnetostratigraphic results show that the lacustrine sequence recorded the late Matuyama and Brunhes chrons. Furthermore, the Maliang artifact layer occurs just below the Brunhes/Matuyama boundary, and the Donggutuo artifact layer is just below the Jaramillo onset. Therefore, the age of the Maliang and Donggutuo artifact layers can be definitely estimated to be about 0.78 myr and 1.1 myr, respectively. These two paleomagnetic ages, coupled with previously obtained paleomagnetic data of the Majuangou, Xiaochangliang, Banshan, Lantian, and Xihoudu Paleolithic sites, suggest an expansion and lengthy flourishing of human groups from northern to north-central China during the entire Early Pleistocene.     

Effects of dam operation and land use on stream channel morphology and riparian vegetation

Dams are well known for influencing channel and vegetation dynamics downstream, but little work has focused on distinguishing effects of land use and channel responses to the impoundment. In this paper, we examined interacting effects of a dam and land use on downstream changes in channel morphology and riparian vegetation along an agricultural stream system in northern California. Measurements of planform channel morphology, vegetation area, and land use were mapped along multiple stream segments based on a chronological sequence of historical aerial photographs over a 34-yr period prior to operation of the dam in 1983 and over a 17-yr period after dam operation, and compared to a nearby, undammed reference stream. A two-factor analysis of covariance (ANCOVA) was used to examine the effect of the dam on changes in bankfull area, stream length, and riparian vegetation area while accounting for the effect of land use and distance downstream. The dammed stream's bankfull area contracted 94% after dam operation. Prior to dam operation, bankfull area decreased when land use area increased, but not after operation of the dam. Stream length varied 64% less after dam operation as a consequence of less frequent episodic channel migration and entrenchment. The area of riparian vegetation was decreasing during the pre-dam period, but then increased 72% after operation of the dam. Across time periods, decreases in the area of riparian vegetation were also associated with increases in land use area in both the dammed and reference stream. After operation of the dam, reduced peak discharges and sediment reduction likely lead to channel incision and constrained channel migration, which allowed vegetation to increase 50% on less accessible, abandoned banks. Rating curve and hydraulic exponent analyses based on stream gauge measurements corroborate statistical analyses of the mapped changes. In conclusion, we found that operation of the dam and land use patterns together influenced spatial and temporal changes in channel morphology and riparian vegetation. Use of a nearby undammed reference stream in conjunction with multivariable analysis of spatially and temporally replicated observations provided an effective framework for unraveling interacting effects of dams and land use activities on stream channel and vegetation dynamics.     

20th Century sea-level change along the eastern US: Unravelling the contributions from steric changes, Greenland ice sheet mass balance and Late Pleistocene glacial loading

We have considered the influence of ocean temperature and salinity changes, mass changes of the Greenland ice sheet (GIS) and the isostatic response of the solid earth to the most recent glacial cycle on 20th century sea-level change along the US east coast with the intention of better understanding the observed signal as well as determining the potential of the tide gauge data for constraining the recent (past 50–100 yr) mass balance of the GIS and earth viscosity structure. Our results show that the signal due to steric changes is large and displays a complex spatial variation which can account for a significant portion of the observed signal. In contrast, that due to changes in the GIS is relatively small and insensitive to the specific geometry of the mass balance model adopted. As a consequence, the tide gauge data alone are not capable of providing useful constraints on either the magnitude or form of recent GIS mass balance. Our inference of mantle viscosity structure based on the tide gauge data was affected dramatically when the steric effect was accounted for: An earth model with an upper mantle viscosity of 8 × 10¹⁹ Pa s and a lower mantle viscosity of 5 × 10²² Pa s produced the best fit to the steric-corrected data; the optimal fit to the uncorrected data was obtained for upper and lower mantle viscosities of 5 × 10²⁰ Pa s and 10²² Pa s, respectively.     

Carbon Capture and Storage From Fossil Fuels and Biomass – Costs and Potential Role in Stabilizing the Atmosphere

The capture and storage of CO₂ from combustion of fossil fuels is gaining attraction as a means to deal with climate change. CO₂ emissions from biomass conversion processes can also be captured. If that is done, biomass energy with CO₂ capture and storage (BECS) would become a technology that removes CO₂ from the atmosphere and at the same time deliver CO₂-neutral energy carriers (heat, electricity or hydrogen) to society. Here we present estimates of the costs and conversion efficiency of electricity, hydrogen and heat generation from fossil fuels and biomass with CO₂ capture and storage. We then insert these technology characteristics into a global energy and transportation model (GET 5.0), and calculate costs of stabilizing atmospheric CO₂ concentration at 350 and 450 ppm. We find that carbon capture and storage technologies applied to fossil fuels have the potential to reduce the cost of meeting the 350 ppm stabilisation targets by 50% compared to a case where these technologies are not available and by 80% when BECS is allowed. For the 450 ppm scenario, the reduction in costs is 40 and 42%, respectively. Thus, the difference in costs between cases where BECS technologies are allowed and where they are not is marginal for the 450 ppm stabilization target. It is for very low stabilization targets that negative emissions become warranted, and this makes BECS more valuable than in cases with higher stabilization targets. Systematic and stochastic sensitivity analysis is performed. Finally, BECS opens up the possibility to remove CO₂ from the atmosphere. But this option should not be seen as an argument in favour of doing nothing about the climate problem now and then switching on this technology if climate change turns out to be a significant problem. It is not likely that BECS can be initiated sufficiently rapidly at a sufficient scale to follow this path to avoiding abrupt and serious climate changes if that would happen.     

An analytical interpretation of liquid injection induced microseismicity in porous reservoirs

The paper presents a rigorously derived analytical method to describe and interpret the low-magnitude earthquakes caused by injection of the borehole fluids into surrounding porous reservoirs. Microseismicity is induced due to changes in the pore pressure, which, in turn, is influenced mainly by the low-frequency slow Biot (P2) wave. The classical Biot model is used to obtain the distribution of pore pressure in a reservoir. The constructed solution to the Biot system of equations and the spatio-temporal cloud of microseismic events allow one to assess the critical value of the pore pressure, sufficient for the generation of a microearthquake, and the values of hydromechanical parameters (e.g. permeability) of a saturated porous rock.     

Fire Danger Monitoring Using ERS-1 SAR Images in the Case of Northern Boreal Forests

Research was carried out to assess the potential of imaging radar systems formonitoring forest fire danger. In Canada, daily forest fire danger ratings are generated by the Canadian ForestFire Danger Rating System (CFFDRS), based on estimates of fire weather indices (FWI) and measured foliar moisturecontent (FMC). To evaluate the potential of imaging radar, an experiment was conducted using test sitesconsisting of jack pine, black spruce and white spruce stands located in the MacKenzie river basin, NorthwestTerritories, Canada. Radar image intensity values from ERS-1 SAR imagery collected over these stands in 1994 werecompared to FWI indices and FMC data. FWI indices were calculated using data from local weather stations.Seasonal trends in radar backscatter (⁰) were shown to correlate with temperature and precipitation. Significant relationships were found between ⁰ and FWI codes and indices, particularly in thecase of the black spruce stands, with slow-drying fuels, like duff moisture code (DMC), drought code (DC), and build-upindex (BUI). Rates of changes in ⁰were related to rates of changes in FMC, particularly in the case ofthe jack pine stands for old FMC and in the case of white spruce stands for composite FMC.