Distribution of heavy metals in marine bivalves, fish and coastal sediments in the Gulf and Gulf of Oman

An assessment of marine contamination due to heavy metals was made in the Gulf and Gulf of Oman based on marine biota (fish and various bivalves) and coastal sediment collected in Bahrain, Oman, Qatar, and the United Arab Emirates (UAE) during 2000-2001. Sediment metal loadings were generally not remarkable, although hot spots were noted in Bahrain (Cu, Hg, Pb, Zn) and on the east coast of the UAE (As, Co, Cr, Ni). Concentrations of As and Hg were typically low in sediments and the total Hg levels in top predator fish commonly consumed in the region were < 0.5 microg g(-1) and posed no threat to public health. Very high Cd concentrations (up to 195 microg g(-1)) in the liver of some fish from southern Oman may result from food-chain bioaccumulation of elevated Cd levels brought into the productive surface waters by upwelling in the region. Very high As concentrations (up to 156 microg g(-1)) were measured in certain bivalve species from the region. Although not certain, the As is probably derived from natural origins rather than anthropogenic contamination.     

Estrogen in a karstic aquifer

Adverse impacts on the health of some fish populations, such as skewed sex distributions, have been noted in surface waters and in laboratory experiments with relatively low concentrations (above 25 ng/L) of natural estrogen (17 beta-estradiol--E2). Sources of E2 to surface and ground waters can include avian, human, and mammalian waste products. The Ozark Plateau Aquifer (OPA) is a karstic basin that receives a significant portion of its water through losing reaches of rivers. Thus, there is a direct connection between surface water and ground water. The OPA was targeted for an E2 study to assess the potential for adverse health effects to aquatic organisms living in the system. Eight springs, which drain the aquifer, were sampled quarterly. The concentrations of E2 in the OPA ranged from 13 to 80 ng/L. For any one sampling event, the concentrations of E2 at the spring waters were statistically similar; however, the concentrations of E2 at all springs varied throughout the year. At Maramec Spring, one of the larger springs, the E2 concentration, was correlated with discharge. Based on the correlation between discharge and E2 concentration, aquatic organisms living in the plateau or in its discharged waters, including the threatened southern cavefish T. subterraneus, are exposed to concentration of E2 above 25 ng/L approximately 60% of the time. This implies that organisms living in karst basins throughout the OPA are likely exposed to E2 concentrations that may adversely impact their reproductive success for a significant portion of each year.     

Walrus (Odobenus rosmarus) predation on adult thick-billed murres (Uria lomvia) at Coats Island, Nunavut, Canada

Although the diet of walrus ( Odobenus rosmarus ) is considered varied, records of walrus consuming marine birds are rare in the published literature. In 2001 and 2002 we observed walrus foraging on adult thick-billed murres ( Uria lomvia ) at Coats Island in Nunavut, Canada. Approximately 46% of the attacks on murres were successful, and as many as 67 murres may have been killed in one day in August 2002. All soft parts of the murres were sucked out, with carcasses of only bones, feathers and skin left floating on the water. The extent to which predation on seabirds by walrus occurs across the eastern Arctic is unknown, but it could represent an important source of mortality for murres at some breeding colonies.     

Geodetic measurement of the local elastic response to the changing mass of water in Lago Laja, Chile

A geodetic station (ANTC) built in bedrock in southern Chile is undergoing non-steady vertical motion within a range of nearly 50 mm. These fluctuations are dominated by the earth’s local elastic response to the changing weight of water in a reservoir located about 20 km away. There is also an annual periodic component of motion that is attributed to global and regional patterns of loading, as well as a steady tectonic signal. The local loading response constrains the average elastic structure of the area, and implies a stiffness that falls near the lower end of the range observed in rock samples.     

Modern sediment yield compared to geologic rates of sediment production in a semi‐arid basin,New Mexico: assessing the human impact

An Erratum has been published for this article in Earth Surface Processes and Landforms 29(13) 2004, 1707. In the semi‐arid Arroyo Chavez basin of New Mexico, a 2·28 km² sub‐basin of the Rio Puerco, we contrasted short‐term rates (3 years) of sediment yield measured with sediment traps and dams with long‐term, geologic rates (～10 000 years) of sediment production measured using ¹⁰Be. Examination of erosion rates at different time‐scales provides the opportunity to contrast the human impact on erosion with background or geologic rates of sediment production. Arroyo Chavez is grazed and we were interested in whether differences in erosion rates observed at the two time‐scales are due to grazing. The geologic rate of sediment production, 0·27 kg m^?2 a^?1 is similar to the modern sediment yields measured for geomorphic surfaces including colluvial slopes, gently sloping hillslopes, and the mesa top which ranged from 0·12 to 1·03 kg m^?2 a^?1. The differences between modern sediment yield and geologic rates of sediment production were most noticeable for the alluvial valley ?oor, which had modern sediment yields as high as 3·35 kg m^?2 a^?1. The hydraulic state of the arroyo determines whether the alluvial valley ?oor is aggrading or degrading. Arroyo Chavez is incised and the alluvial valley ?oor is gullied and piped and is a source of sediment. The alluvial valley ?oor is also the portion of the basin most modi?ed by human disturbance including grazing and gas pipeline activity, both of which serve to increase erosion rates. Copyright © 2004 John Wiley & Sons, Ltd.     

The impact of land use change on soil water holding capacity and river flow modelling in the Nakambe River, Burkina-Faso

The annual hydrological regime of the Nakambe River shows substantial changes during the period 1955–1998 with a shift occurring around 1970. From 1970 to the mid-1990s, despite a reduction in rainfall and an increase in the number of dams in the basin, average runoff and maximum daily discharges increased. This paper reviews the hydrological behaviour of the Nakambe River from 1955 to 1998 and examines the potential role of land use change on soil water holding capacity (WHC) in producing the counter-intuitive change in runoff observed after 1970. We compare the results of two monthly hydrological models using different rainfall, potential evapotranspiration and WHC data sets. Model simulations with soil WHC values modified over time based upon historical maps of land use, are compared against simulations with a constant value for WHC. The extent of natural vegetation declined from 43 to 13% of the total basin area between 1965 and 1995, whilst the cultivated areas increased from 53 to 76% and the area of bare soil nearly tripled from 4 to 11%. The total reduction in WHC is estimated to range from 33 to 62% depending on the method used, either considering that the WHC values given by the FAO stand for the environmental situation in 1965 or before. There is a marked improvement in river flow simulation using the time-varying values of soil WHC. The paper ends with a discussion of the role of other factors such as surface runoff processes and groundwater trends in explaining the hydrological behaviour of the Nakambe River.     

Trace elements in streambed sediments of small subtropical streams on O‘ahu, Hawai‘i: Results from the USGS NAWQA program

Data are presented for trace element concentrations determined in the <63 μm fraction of streambed sediment samples collected at 24 sites on the island of O‘ahu, Hawai‘i. Sampling sites were classified as urban, agricultural, mixed (urban/agricultural), or forested based on their dominant land use, although the mixed land use at selected sampling sites consisted of either urban and agricultural or forested and agricultural land uses. Forest dominated sites were used as reference sites for calculating enrichment factors.Trace element concentrations were compared to concentrations from studies conducted in the conterminous United States using identical methods and to aquatic-life guidelines provided by the Canadian Council of Ministers of the Environment. A variety of elements including Pb, Cr, Cu and Zn exceeded the aquatic-life guidelines in selected samples. All of the Cr and Zn values and 16 of 24 Cu values exceeded their respective guidelines. The potential toxicity of elements exceeding guidelines, however, should be considered in the context of strong enrichments of selected trace elements attributable to source rocks in Hawai‘i, as well as in the context of the abundance of fine-grained sediment in the streambed of O‘ahu streams.Statistical methods including cluster analysis, Kruskal–Wallis non-parametric test, correlation analysis, and principal component analysis (PCA) were used to evaluate differences and elucidate relationships between trace elements and sites. Overall, trace element distributions and abundances can be correlated to three principal sources of elements. These include basaltic rocks of the volcanic edifice (Fe, Al, Ni, Co, Cr, V and Cu), carbonate/seawater derived elements (Mg, Ca, Na and Sr), and elements enriched owing to anthropogenic activity (P, Sn, Cd, Sn, Ba and Pb). Anthropogenic enrichment gradients were observed for Ba, Cd, Pb, Sn and Zn in the four streams in which sediments were collected upstream and downstream.The findings of this study are generally similar to but differ slightly from previous work on sediments and suspended particulate matter in streams, from two urban watersheds of O‘ahu, Hawai‘i. Inter-element associations in the latter were often stronger and indicated a mixture of anthropogenic, agricultural and basaltic sources of trace elements. Some elements fell into different statistical categories in the two studies, owing in part to differences in study design and the hydrogeological constraints on the respective study areas.     

Flood Forecasting and Warning at the River Basin and at the European Scale

Application of recent advances in numerical weather prediction (NWP) has the potential of allowing delivery of flood warning to extend well beyond the typical lead times of operational flood warning at the river basin scale. A prototype system, a European Flood Forecasting System (EFFS) developed to deliver such pre-warnings, aiming at providing a pre-warning at lead times of between 5 and 10 days is described. Considerable uncertainty in the weather forecast at these lead times, however, means that resulting forecasts must be treated probabilistically, and although probabilistic forecasts may be easy to disseminate, these are difficult to understand. This paper explores the structure of operational flood warning, and shows that integration in the flood warning process is required if the pre-warning is to fulfil its potential. A simple method of summarising the information in the pre-warning is presented, and the system in hindcast mode is shown to give clear indication of an upcoming major event in the Rhine basin up to 10 days before the actual event. Finally recommendations on the use of data assimilation to embed the EFFS system within an operational environment are given.