Stable Fe isotope fractionations produced by aqueous Fe(II)-hematite surface interactions

Stable Fe isotope fractionations were investigated during exposure of hematite to aqueous Fe(II) under conditions of variable Fe(II)/hematite ratios, the presence/absence of dissolved Si, and neutral versus alkaline pH. When Fe(II) undergoes electron transfer to hematite, Fe(II) is initially oxidized to Fe(III), and structural Fe(III) on the hematite surface is reduced to Fe(II). During this redox reaction, the newly formed reactive Fe(III) layer becomes enriched in heavy Fe isotopes and light Fe isotopes partition into aqueous and sorbed Fe(II). Our results indicate that in most cases the reactive Fe(III) that undergoes isotopic exchange accounts for less than one octahedral layer on the hematite surface. With higher Fe(II)/hematite molar ratios, and the presence of dissolved Si at alkaline pH, stable Fe isotope fractionations move away from those expected for equilibrium between aqueous Fe(II) and hematite, towards those expected for aqueous Fe(II) and goethite. These results point to formation of new phases on the hematite surface as a result of distortion of Fe-O bonds and Si polymerization at high pH. Our findings demonstrate how stable Fe isotope fractionations can be used to investigate changes in surface Fe phases during exposure of Fe(III) oxides to aqueous Fe(II) under different environmental conditions. These results confirm the coupled electron and atom exchange mechanism proposed to explain Fe isotope fractionation during dissimilatory iron reduction (DIR). Although abiologic Fe(II)_aq - oxide interaction will produce low δ⁵⁶Fe values for Fe(II)_aq, similar to that produced by Fe(II) oxidation, only small quantities of low-δ⁵⁶Fe Fe(II)_aq are formed by these processes. In contrast, DIR, which continually exposes new surface Fe(III) atoms during reduction, as well as production of Fe(II), remains the most efficient mechanism for generating large quantities of low-δ⁵⁶Fe aqueous Fe(II) in many natural systems.     

Synthetic stellar and SSP libraries as templates for Gaia simulations

ESA’s Gaia mission will collect low resolution spectroscopy in the optical range for ～10⁹ objects. Complete and up-to-date libraries of synthetic stellar spectra are needed to built algorithms aimed to automatically derive the classification and the parametrization of this huge amount of data. In addition, libraries of stellar spectra are one of the main ingredients of stellar population synthesis models, aiming to derive the properties of unresolved stellar populations from their integrated light. We present (a) the newly computed libraries of synthetic spectra built by the Gaia community, covering the whole optical range (300–1100 nm) at medium-high resolution of (0.3 nm) for stars spanning the most different types, from M to O, from A-peculiar to Emission lines to White Dwarfs, and (b) the implementation of those libraries in our SSP code (Tantalo in The Initial Mass Function 50 Years Later, 327:235 2005), exploring different stellar evolution models.     

An improved methodology for filling missing values in spatiotemporal climate data set

In this paper, an improved methodology for the determination of missing values in a spatiotemporal database is presented. This methodology performs denoising projection in order to accurately fill the missing values in the database. The improved methodology is called empirical orthogonal functions (EOF) pruning, and it is based on an original linear projection method called empirical orthogonal functions (EOF). The experiments demonstrate the performance of the improved methodology and present a comparison with the original EOF and with a widely used optimal interpolation method called objective analysis.     

The Effects of Reduced Tidal Flushing on Mangrove Structure and Function Across a Disturbance Gradient

The effects of reduced tidal flushing on post-hurricane mangrove recovery were measured across a gradient of hurricane disturbance (in order of decreasing wind intensity: Captiva, North Sanibel, Central Sanibel, and East Sanibel). Each region consisted of replicate study plots with either reduced tidal exchange (tidally restricted location) or an open tidal connection (tidally unrestricted location). Locations with reduced tidal exchange displayed significantly lower (two-way ANOVA, p ≤ 0.0001) tidal amplitude, decreased seedling densities, and decreased productivity (recruitment, growth, and litter fall) when compared to the tidally unrestricted locations. Results also indicated significant regional variations in measures of mangrove stand structure (seedlings and canopy) and productivity (recruitment, growth, and litter fall) up to 4-years post-hurricane disturbance. These findings suggest that the legacy effects from hurricane disturbance vary with degree of wind intensity, acting both independently and synergistically with the effects of tidal restriction to influence post-hurricane mangrove structure and function.     

Hydrosedimentary records and Holocene environmental dynamics in the Yamé Valley (Mali,Sudano-Sahelian West Africa)

Research conducted in the Yamé Valley (Dogon Country, Mali) provides valuable information about the river systems and their Holocene evolution in Sudano-Sahelian West Africa. Past research in the region has relied primarily on marine and lacustrine records. The new results confirm correlation between palaeoclimatic fluctuations recorded in both the river system and in tropical African lakes. They offer a new continental milestone for understanding of the environmental repercussions of Holocene monsoon oscillations. These studies demonstrate the value of river systems as a palaeoenvironmental record and the role of palaeoclimatic and anthropogenic factors in the Holocene dynamics of Sudano-Sahelian hydrosystems.     

Influence of sediment grain size and mineralogy on testate amoebae test construction

Testate amoebae are increasingly used for environmental monitoring as well as paleoenvironmental reconstructions. Paleoecological interpretations of testate amoebae assemblages depend on the understanding of the ecological processes operating today. We then ask the question of the link between testate structure and its environment. This study analyses both the grain size and mineralogical assemblage of tests of common species belonging to the genus Centropyxis and Difflugia. It is concluded that grain size is a limiting factor for test construction, whereas mineral composition is not. Hence, when analyzing agglutinated testate amoebae for paleoenvironmental reconstructions, it should be taken into account the mean grain size of the sediment. A non-appropriate grain-size probably inhibits the development of a testate amoebae specific assemblage.     

Precipitation extremes and the impacts of climate change on stormwater infrastructure in Washington State

The design of stormwater infrastructure is based on an underlying assumption that the probability distribution of precipitation extremes is statistically stationary. This assumption is called into question by climate change, resulting in uncertainty about the future performance of systems constructed under this paradigm. We therefore examined both historical precipitation records and simulations of future rainfall to evaluate past and prospective changes in the probability distributions of precipitation extremes across Washington State. Our historical analyses were based on hourly precipitation records for the time period 1949–2007 from weather stations in and near the state’s three major metropolitan areas: the Puget Sound region, Vancouver (WA), and Spokane. Changes in future precipitation were evaluated using two runs of the Weather Research and Forecast (WRF) regional climate model (RCM) for the time periods 1970–2000 and 2020–2050, dynamically downscaled from the ECHAM5 and CCSM3 global climate models. Bias-corrected and statistically downscaled hourly precipitation sequences were then used as input to the HSPF hydrologic model to simulate streamflow in two urban watersheds in central Puget Sound. Few statistically significant changes were observed in the historical records, with the possible exception of the Puget Sound region. Although RCM simulations generally predict increases in extreme rainfall magnitudes, the range of these projections is too large at present to provide a basis for engineering design, and can only be narrowed through consideration of a larger sample of simulated climate data. Nonetheless, the evidence suggests that drainage infrastructure designed using mid-20th century rainfall records may be subject to a future rainfall regime that differs from current design standards.     

Navigating the dilemmas of climate policy in Europe: evidence from policy evaluation studies

Climate change is widely recognised as a ‘wicked’ policy problem. Agreeing and implementing governance responses is proving extremely difficult. Policy makers in many jurisdictions now emphasise their ambition to govern using the best available evidence. One obvious source of such evidence is the evaluations of the performance of existing policies. But to what extent do these evaluations provide insights into the difficult dilemmas that governors typically encounter? We address this question by reviewing the content of 262 evaluation studies of European climate policies in the light of six kinds of dilemma found in the governance literature. We are interested in what these studies say about the performance of European climate policies and in their capacity to inform evidence-based policy-making. We find that the evaluations do arrive at common findings: that climate change is framed as a problem of market and/or state failure; that voluntary measures tend to be ineffective; that market-based instruments tend to be regressive; that EU-level policies have driven climate policies in the latecomer EU Member States; and that lack of monitoring and weak enforcement are major obstacles to effective policy implementation. However, we also conclude that the evidence base these studies represent is surprisingly weak for such a high profile area. There is too little systematic climate policy evaluation work in the EU to support systematic evidence-based policy making. This reduces the scope for sound policy making in the short run and is a constraint to policy learning in the longer term.     

High frequency stream bed mobility of a low‐gradient agricultural stream with implications on the hyporheic zone

Little Kickapoo Creek (LKC), a low‐gradient stream, mobilizes its streambed–fundamentally altering its near‐surface hyporheic zone–more frequently than do higher‐gradient mountain and karst streams. LKC streambed mobility was assessed through streambed surveys, sediment sampling, and theoretical calculations comparing basal shear stress (τ_b) with critical shear stress (τ_c). Baseflow τ_b is capable of entraining a d₅₀ particle; bankfull flow could entrain a 51·2 mm particle. No particle that large occurs in the top 30 cm of the substrate, suggesting that the top 30 cm of the substrate is mobilized and redistributed during bankfull events. Bankfull events occur on average every 7·6 months; flows capable of entraining d₅₀ and d₈₅ particles occur on average every 0·85 and 2·1 months, respectively. Streambed surveys verify streambed mobility at conditions below bankfull. While higher gradient streams have higher potential energy than LKC, they achieve streambed‐mobilization thresholds less frequently. Heterogeneous sediment redistribution creates an environment where substrate hydraulic conductivity (K) varies over four orders of magnitude. The frequency and magnitude of the substrate entrainment has implications on hyporheic zone function in fluid, solute and thermal transport models, interpretations of hyporheic zone stability, and understanding of LKC's aquatic ecosystem. Copyright © 2008 John Wiley & Sons, Ltd.