A geochemical approach to model periodically replenished magma chambers: Does oscillatory supply account for the magmatic evolution of EPR 17-19°S?

We propose a new approach to model the geochemical evolution of continuously replenished and tapped steady-state magma chambers. We use a sinusoidal function to model cyclic magma supply. The temporal evolution of a reservoir is described using differential equations, in which the amount of refilling magma does not depend on the size of the chamber. These equations can be used to calculate incompatible trace element concentrations and magma quantities. We examine the geochemical consequences of episodic injections, noises and wall-rock assimilation. We also explore possible variations in crystallization rate. To show its potential, the theoretical treatment has been applied to the EPR 17-19°S, a site with a strong magma budget which has been the subject of several geological/geophysical studies. The practical application requires geological parameters to be constrained, as well as the extreme values of the lava concentration range. A first step specifies the incompatible trace element composition of the replenishing melt, which corresponds in the EPR case to a magnesian liquid (MgO = 9.5 wt%). It is then possible to determine other parameters such as cycle period (∼750 years), magma residence time (∼300 years), and reservoir size (from 4.1 to 8.6 km³ per 20 km segment). Lastly, variations in crystallization rate do not significantly alter the results.     

The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.     

A field evaluation of enhanced reductive dechlorination of chlorinated solvents in groundwater,New York Metropolitan Area

An initial assessment of an old manufacturing site with groundwater impacted by trichloroethene (TCE) contamination in the metropolitan New York area showed that the TCE was being removed naturally by reductive dechlorination. However, complete dechlorination was not expected at the site because the process was progressing too slowly under transitional to aerobic conditions at a degradation constant of –0.0013 and a TCE half life of 533 days. A pilot test was conducted at the site in which a carbohydrate substrate (molasses) was injected into the groundwater to create an In-Situ Reactive Zone (IRZ). Post-pilot test groundwater sampling and analysis indicated that an IRZ was created successfully as the total organic carbon (TOC) content and conductivity increased significantly while oxidation-reduction (REDOX) potential and dissolved oxygen (DO) decreased. The created IRZ caused enhanced reductive dechlorination of TCE at the site, found to proceed with a degradation constant of –0.0158 and a TCE half life of 44 days.     

A New Appraisal of Sri Lankan BB Zircon as a Reference Material for LA‐ICP‐MS U‐Pb Geochronology and Lu‐Hf Isotope Tracing

A potential zircon reference material (BB zircon) for laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U‐Pb geochronology and Hf isotope geochemistry is described. A batch of twenty zircon megacrysts (0.5–1.5 cm³) from Sri Lanka was studied. Within‐grain rare earth element (REE) compositions are largely homogeneous, albeit with some variation seen between fractured and homogeneous domains. Excluding fractured cathodoluminescence bright domains, the variation in U content for all analysed crystals ranged from 227 to 368 μg g^?1 and the average Th/U ratios were between 0.20 and 0.47. The Hf isotope composition (0.56–0.84 g/100 g Hf) is homogeneous within and between the grains – mean ¹⁷⁶Hf/¹⁷⁷Hf of 0.281674 ± 0.000018 (2s). The calculated alpha dose of 0.59 × 10¹⁸ g^?1 for a number of BB grains falls within the trend of previously studied, untreated zircon samples from Sri Lanka. Aliquots of the same crystal (analysed by ID‐TIMS in four different laboratories) gave consistent U‐Pb ages with excellent measurement reproducibility (0.1–0.4% RSD). Interlaboratory assessment (by LA‐ICP‐MS) from individual crystals returned results that are within uncertainty equivalent to the TIMS ages. Finally, we report on within‐ and between‐grain homogeneity of the oxygen isotope systematic of four BB crystals (13.16‰ VSMOW).     

Fault-controlled dolomitization at Swan Hills Simonette oil field (Devonian), deep basin west-central Alberta, Canada

The partly dolomitized Swan Hills Formation (Middle‐Upper Devonian) in the Simonette oil field of west‐central Alberta underwent a complex diagenetic history, which occurred in environments ranging from near surface to deep (>2500 m) burial. Five petrographically and geochemically distinct dolomites that include both cementing and replacive varieties post‐date stylolites in limestones (depths >500 m). These include early planar varieties and later saddle dolomites. Fluid inclusion data from saddle dolomite cements (T_h=137–190 °C) suggest that some precipitated at burial temperatures higher than the temperatures indicated by reflectance data (T_peak=160 °C). Thus, at least some dolomitizing fluids were ‘hydrothermal’. Fluorescence microscopy identified three populations of primary hydrocarbon‐bearing fluid inclusions and confirms that saddle dolomitization overlapped with Upper Cretaceous oil migration. The source of early dolomitizing fluids probably was Devonian or Mississippian seawater that was mixed with a more ⁸⁷Sr‐rich fluid. Fabric‐destructive and fabric‐preserving dolostones are over 35 m thick in the Swan Hills buildup and basal platform adjacent to faults, thinning to less than 10 cm thick in the buildup between 5 and 8 km away from the faults. This ‘plume‐like’ geometry suggests that early and late dolomitization events were fault controlled. Late diagenetic fluids were, in part, derived from the crystalline basement or Palaeozoic siliciclastic aquifers, based on ⁸⁷Sr/⁸⁶Sr values up to 0·7370 from saddle dolomite, calcite and sphalerite cements, and ²⁰⁶Pb/²⁰⁴Pb of 22·86 from galena samples. Flow of dolomitizing and mineralizing fluids occurred during burial greater than 500 m, both vertically along reactivated faults and laterally in the buildup along units that retained primary and/or secondary porosity.     

The geologic history of the Nicoya Ophiolite Complex, Costa Rica, and its geotectonic significance

Costa Rica forms part of an intra-oceanic arc between the Pacific and Caribbean oceans; the Nicoya Ophiolite Complex is located along its Pacific border. In this study, evidence is given that the Nicoya Complex is composed of ridge-formed oceanic crust that suffered a strong compressional stress during Late Santonian times. As a result of this, isoclinal folding and large-scale nappe emplacement occurred at a shallow crustal depth. The principal component of this compressional stress was E-W-directed. It is also demonstrated that, from this time, the complex was situated between a subducting plate and a volcanic arc. From that Campanian until the Middle Eocene the zone was undulated, and generally at a great depth below sea level. During the Eocene—Oligocene epoch a new tectonic stress affected the area. It produced open folding with upthrusting in the ophiolite complex and overthrust folding of the overlying rock series. As a result of crustal thickening during this tectonic phase, the area was uplifted. From Miocene times, the zone was shaped into a dome and a synform. These undulations are attributed to compression of the subducting Coco Plate, west of the area.The Upper Santonian tectonic phase demonstrates how compressional stress produced the break-up of the Caribo-Pacific plate west of the study area, as a result of which, a Caribbean plate without an associated oceanic ridge and a Pacific plate originated. The compressional stress in question was presumably generated by the opposed spreading directions of the new Mid-Atlantic Ridge and an older ridge to the west of the study area.Furthermore, it is argued that the Cretaceous obduction of the ophiolite belt along the Pacific coast of the American continents, was produced by the directional change of these continents during the birth of the Mid-Atlantic Ridge. This created intra-plate compressional stress and converted originally passive continental margins into active zones, where thrusting of oceanic crust on to a continental margin (obduction) could occur. When the Mid-Atlantic Ridge started spreading, the obduction phase ended due to subduction of the oceanic plate below the leading edge of the continent.     

Geomorphological and historical changes on the Argentina delta,Ligurian coast,Italy

A preliminary investigation of the geomorphological evolution of the small delta of the Argentina river (Riviera di Ponente, Italy) shows that it has largely been affected by anthropic processes. Erosion is undermining land and structural developments not only in the delta, but also along the nearby shores and a thorough knowledge of them seems necessary prior to management applications. In fact, processes affecting the evolution of the investigated area could well be regarded as a good example of the evolution of many other deltaic areas in the Northern Mediterranean.     

Estimating longitudinal dispersion in rivers using Acoustic Doppler Current Profilers

The longitudinal dispersion coefficient (D) is an important parameter needed to describe the transport of solutes in rivers and streams. The dispersion coefficient is generally estimated from tracer studies but the method can be expensive and time consuming, especially for large rivers. A number of empirical relations are available to estimate the dispersion coefficient; however, these relations are known to produce estimates within an order of magnitude of the tracer value. The focus of this paper is on using the shear-flow dispersion theory to directly estimate the dispersion coefficient from velocity measurements obtained using an Acoustic Doppler Current Profiler (ADCP). Using tracer and hydrodynamic data collected within the same river reaches, we examined conditions under which the ADCP and tracer methods produced similar results. Since dead zones / transient storage (TS) are known to influence the dispersion coefficient, we assessed the relative importance of dead zones in different stream reaches using two tracer-based approaches: (1) TS modeling which explicitly accounts for dead zones and (2) the advection–dispersion equation (ADE) which does not have separate terms for dead zones. Dispersion coefficients based on the ADE tend to be relatively high as they describe some of the effects of dead zones as well. Results based on the ADCP method were found to be in good agreement with the ADE estimates indicating that storage zones play an important role in the estimated dispersion coefficients, especially at high flows. For the river sites examined in this paper, the tracer estimates of dispersion were close to the median values of the ADCP estimates obtained from multiple datasets within a reach. The ADCP method appears to be an excellent alternative to the traditional tracer-based method if care is taken to avoid spurious data and multiple datasets are used to compute a distance-weighted average or other appropriate measure that represents reach-averaged conditions.     

Phosphate in Angra dos Reis: Structure and composition of the Ca3(PO4)2 minerals

Extraterrestrial calcium phosphates (“whitlockites”) have the anhydrous β-Ca₃(PO₄)₂ structure, which is different from that of hydrous terrestrial whitlockite. This has been confirmed by X-ray refinement of the structure of a phosphate from the achondrite Angra dos Reis. In the β-Ca₃(PO₄)₂ structure, there is one crystallographic site, Ca(IIA), which is half-occupied by calcium, and which seems to have an energetically unfavorable configuration; natural phosphates with this configuration (including Angra dos Reis) have composition Ca₁₉(Mg,Fe)₂(PO₄)₁₄. Stability of the structure is probably increased by substitution of Na for Ca in Ca(IIA) giving composition Ca₁₈ (Mg,Fe)₂Na₂(PO₄)₁₄, which occurs in chondrites; by vacancy of Ca(IIA), with rare earths and yttrium substituting for calcium in other sites for charge balance, giving composition Ca₁₆(Y,RE)₂(Mg,Fe)₂(PO₄)₁₄, found in lunar rocks; or by replacing Ca with hydrogen, giving composition Ca₁₈(Mg,Fe)₂H₂(PO₄)₁₄, which is terrestrial whitlockite. Lack of the favorable substitutions of Na, (Y, RE) or H in Angra dos Reis phosphate implies that these elements were relatively scarce in its environment of formation.