Effects of artificial and natural recharge on chemical equilibrium in the Cerro Prieto reservoirs, Baja California, México

Chemical equilibrium modeling studies of two aquifers in the western part of the Cerro Prieto (CP-I) geothermal field were performed to obtain the activities of the main ions and complexes by using the EQQYAC program. The results provided a pH of 6.44 for the deep aquifer, which is slightly higher than the value of 5.5 found for the shallower reservoir. In the northern part of the field, the reservoir pH has decreased up to 1.5 units compared to that modeled for 1990. Variations of pH with respect to time were also found to occur in the southern part of the field. In spite of the large changes in hydrodynamic conditions occurring in the reservoir due to exploitation, the equilibrium between both K- and Na-feldspars and between K-feldspar and K-mica seems to control the chemical composition of the fluids, in both reservoirs.     

Assessing the geochemical reactivity of inorganic phosphorus along estuaries by means of laboratory simulation experiments

Phosphate behaviour in natural estuarine systems can be studied by performing field measurements and by undertaking laboratory simulation experiments. Thus, in this paper we describe the use of a dynamic automated estuarine simulator to characterize the geochemical reactivity of phosphate in varying salinity gradients in order to study possible mechanisms of phosphate removal from the dissolved phase (e.g. formation of some kind of apatite) and how changes in pH and salinity values influence this removal. Six laboratory assays, representing various salinity and pH gradients (average pH values between 7 and 8), were carried out. The geochemical equilibrium model MINTEQA2 was employed to characterize removal of phosphate. Among the minerals from which dissolved phosphate can originate, it seems that hydroxyapatite is by far the mineral that shows the greatest saturation indexes in the experiments. Thus, there is evidence that a type of calcium phosphate (hydroxyapatite) is involved in phosphate removal in the assays. Phosphate removal by Ca²⁺ occurs sharply at salinity values of 1–2, whereas by Fe³⁺ it is relatively gradual, at least until a salinity value of 7. Copyright © 2006 John Wiley & Sons, Ltd.     

MIS 5/4 transition in a mountain environment: herpetofaunal assemblages from Cueva del Camino,central Spain

The Cueva del Camino site (Pinilla del Valle, Madrid, Spain) is located in the upper valley of the Lozoya River in the Sierra de Guadarrama, a mountain range extending NE?SW within the Central Range System. Due to its location within a mountain range on the central Iberian Peninsula at an altitude of 1114 m a.s.l. and the numerical dating of its sediments, the palaeontological site of Cueva del Camino has proved a highly relevant location for studying the ecological changes linked to the climatic fluctuations at the end of Marine Isotope Stage (MIS) 5 and the beginning of MIS 4. Environmental reconstructions suggest a rather open, patchy landscape throughout the succession, with abundant evidence of dry meadows, scrublands and rocky habitats. The climate can be considered as generally warm, reaching mean annual temperatures (MATs) of up to 13.8°C (i.e. higher than today's by up to 2.9°C). Three cooler events can be seen throughout the succession as reflected by the presence of Rana iberica, Anguis fragilis and Coronella austriaca. The first of these events may correlate with MIS 5b; the second in the Central sector may correlate with the Stadial I pollen event occurring at the end of MIS 5a; and the third event, corresponding to the coldest MAT of the entire succession with MATs 0.9°C lower than today's, may correspond to the transition from MIS 5a to MIS 4. The evolution of mean annual precipitation (MAP) is characterized by warm periods, drier and cold periods, as well as wetter periods (up to +356 mm compared to today's MAP values), similar to what occurs today in the high‐elevation areas of the neighbouring mountains. Our study gives new quantitative estimations for the climatic fluctuations in mountain environments of central Spain at the MIS 5/4 transition and their associated ecological changes.     

Linear vertical vibrations of suspension bridges: A review of continuum models and some new results

The classical continuum model for the linear vertical vibrations of a suspension bridge (Bleich et al., 1950 [1]) is re-examined. The primary objective of the study is to extend the definitive analytical and numerical results of Irvine and Caughey (1974) [2], Irvine and Griffin (1976) [3] and Irvine (1980, 1981) [4], [5] for the natural frequencies, mode shapes, and modal participation factors for an extensible suspension cable, which depend on one dimensionless parameter related to the elasticity of the cable, to the case of a stiffened suspension bridge in which the response depends also on a second dimensionless parameter related to the stiffness of the girder. The continuum suspension bridge model is also used to understand the pattern of variation of mode shapes as a function of cable elasticity and girder stiffness, which has been shown by West et al. (1984) [6] to be considerably more complex than that for a suspension cable. Finally, the threshold amplitudes of free vibrations that would result in the incipient slackening of the hangers are determined.     

Addressing uncertainty in reflectivity‐rainfall relations in mountain watersheds during summer convection

The use of precipitation estimates from weather radar reflectivity has become widespread in hydrologic predictions. However, uncertainty remains in the use of the nonlinear reflectivity–rainfall (Z‐R) relation, in particular for mountainous regions where ground validation stations are often lacking, land surface data sets are inaccurate and the spatial variability in many features is high. In this study, we assess the propagation of rainfall errors introduced by different Z‐R relations on distributed hydrologic model performance for four mountain basins in the Colorado Front Range. To do so, we compare spatially integrated and distributed rainfall and runoff metrics at seasonal and event time scales during the warm season when convective storms dominate. Results reveal that the basin simulations are quite sensitive to the uncertainties introduced by the Z‐R relation in terms of streamflow, runoff mechanisms and the water balance components. The propagation of rainfall errors into basin responses follows power law relationships that link streamflow uncertainty to the precipitation errors and streamflow magnitude. Overall, different Z‐R relations preserve the spatial distribution of rainfall relative to a reference case, but not the precipitation magnitude, thus leading to large changes in streamflow amounts and runoff spatial patterns at seasonal and event scales. Furthermore, streamflow errors from the Z‐R relation follow a typical pattern that varies with catchment scale where higher uncertainties exist for intermediate‐sized basins. The relatively high error values introduced by two operational Z‐R relations (WSR‐57 and NEXRAD) in terms of the streamflow response indicate that site‐specific Z‐R relations are desirable in the complex terrain region, particularly in light of other uncertainties in the modelling process, such as model parameter values and initial conditions. Copyright © 2012 John Wiley & Sons, Ltd.     

Determination of the Concentration of Carbonic Species in Natural Waters: Results from a World‐Wide Proficiency Test

The results of an international interlaboratory proficiency test for the determination of carbonic species are presented. Eight laboratories analysed twelve water samples (four synthetic waters, one lake water, four geothermal waters, one seawater and two petroleum waters) by two methods: (a) individual laboratory analytical procedure and (b) acid–base titration curves in tabular form following a standardised protocol. In case (b), the concentrations of carbonic species were calculated by the organiser using the (1) Hydrologists' method, (2) Geochemists' method and/or (3) initial pH and total alkalinity method. For synthetic waters, the averaged % trueness and precision of measurement of the two methods were (trueness = 7.6, precision = 9.4) and (9.0, 3.4) for total alkalinity, and (6.6, 31.0) and (7.8, 6.1) for carbonic alkalinity, respectively. This indicates that the total alkalinity calculation procedure is in general correct in the individual laboratory method, but the carbonic alkalinity calculation procedure has serious problems. The measurements of total alkalinity for lake and seawaters were in agreement in both the methods; however, the individual laboratory measurement method for geothermal and petroleum waters was conceptually incorrect. Thus, the analytical procedures for the determination of carbonic species were reviewed. To apply the Hydrologists' and/or Geochemists' methods, the location of NaHCO₃EP and H₂CO₃EP is necessary, even for samples with pH lower than that of NaHCO₃EP, and a backward titration curve after complete removal of CO₂ must be performed. The initial pH and total alkalinity method is appropriate where a complete analysis of species that contribute to the alkalinity is known.     

中国有壳变形虫Argynnia(Vucetich,1974)属的修订及若干环境重建问题探讨

有壳变形虫是一类具外壳的陆相淡水根足纲(Rhizopoda)原生动物,广泛栖息于湖泊、泥炭、沼泽、土壤等各种淡水潮湿环境,由于其壳体具有很好的抗腐蚀性而在沉积物中保存下来,近年来广泛应用于泥炭和湖泊湿地的古环境重建研究中.大部分有壳变形虫是世界广泛分布的,但是也有一些种类具有一定的地带性分布格局.形态学和分子生物学的研...     

Trade-offs associated with different modeling approaches for assessment of fish and shellfish responses to climate change

Considerable progress has been made in integrating carbon, nutrient, phytoplankton and zooplankton dynamics into global-scale physical climate models. Scientists are exploring ways to extend the resolution of the biosphere within these Earth system models (ESMs) to include impacts on global distribution and abundance of commercially exploited fish and shellfish. This paper compares different methods for modeling fish and shellfish responses to climate change on global and regional scales. Several different modeling approaches are considered including: direct applications of ESM’s, use of ESM output for estimation of shifts in bioclimatic windows, using ESM outputs to force single- and multi-species stock projection models, and using ESM and physical climate model outputs to force regional bio-physical models of varying complexity and mechanistic resolution. We evaluate the utility of each of these modeling approaches in addressing nine key questions relevant to climate change impacts on living marine resources. No single modeling approach was capable of fully addressing each question. A blend of highly mechanistic and less computationally intensive methods is recommended to gain mechanistic insights and to identify model uncertainties.