Aliphatic hydrocarbons in metasomatized gabbroic xenoliths from Hyblean diatremes (Sicily): Genesis in a serpentinite hydrothermal system

Many tholeiite gabbro xenoliths from the Hyblean tuff-breccia deposits (Sicily, southern Italy) present mineralogical and geochemical evidence for hydrothermal alteration at different temperatures and water/rock ratios. In some cases, the primary mineral assemblage has been entirely replaced by Na-rich alkali feldspar, chlorite/smectite interlayers, zeolites, aegirine–augite, titanite, zircon etc. Hence the chemical composition of such metasomatic rocks displays larger amounts of volatiles, alkalis, Zr, Hf, U, Th and lower Ca, Mg, Fe with respect to the original gabbro. Five hydrothermally altered gabbroic xenoliths were selected for thermal decrepitation and bulk gas analyses by quadrupole mass spectrometry. All the samples analyzed display the same Electron Impact-Direct Pyrolysis Mass spectra (EI-DPMS). These show a series of peaks differing by 14 mass units due to loss of methylene groups (–CH₂), by a fragmentation process typical of saturated aliphatic and aliphatic–aromatic hydrocarbons. In addition, Fourier Transform Infrared (FT-IR) spectra of the samples present several bands typical of vibration frequencies of aliphatic hydrocarbons. The high-molecular-weight hydrocarbons observed probably originated from Fischer–Tropsch-type (FT-t) synthesis in the high temperature section of a serpentinite-hosted hydrothermal system. This suggestion may lend support to the recent hypothesis regarding the original oceanic nature of the Hyblean lithospheric basement.     

Global and regional ocean carbon uptake and climate change: sensitivity to a substantial mitigation scenario

Under future scenarios of business-as-usual emissions, the ocean storage of anthropogenic carbon is anticipated to decrease because of ocean chemistry constraints and positive feedbacks in the carbon-climate dynamics, whereas it is still unknown how the oceanic carbon cycle will respond to more substantial mitigation scenarios. To evaluate the natural system response to prescribed atmospheric ??target?? concentrations and assess the response of the ocean carbon pool to these values, 2 centennial projection simulations have been performed with an Earth System Model that includes a fully coupled carbon cycle, forced in one case with a mitigation scenario and the other with the SRES A1B scenario. End of century ocean uptake with the mitigation scenario is projected to return to the same magnitude of carbon fluxes as simulated in 1960 in the Pacific Ocean and to lower values in the Atlantic. With A1B, the major ocean basins are instead projected to decrease the capacity for carbon uptake globally as found with simpler carbon cycle models, while at the regional level the response is contrasting. The model indicates that the equatorial Pacific may increase the carbon uptake rates in both scenarios, owing to enhancement of the biological carbon pump evidenced by an increase in Net Community Production (NCP) following changes in the subsurface equatorial circulation and enhanced iron availability from extratropical regions. NCP is a proxy of the bulk organic carbon made available to the higher trophic levels and potentially exportable from the surface layers. The model results indicate that, besides the localized increase in the equatorial Pacific, the NCP of lower trophic levels in the northern Pacific and Atlantic oceans is projected to be halved with respect to the current climate under a substantial mitigation scenario at the end of the twenty-first century. It is thus suggested that changes due to cumulative carbon emissions up to present and the projected concentration pathways of aerosol in the next decades control the evolution of surface ocean biogeochemistry in the second half of this century more than the specific pathways of atmospheric CO₂ concentrations.     

Asymptotic giant branch stars in the Phoenix dwarf galaxy

JHK _s near-infrared photometry of stars in the Phoenix dwarf galaxy is presented and discussed. Combining these data with the optical photometry of Massey et al. allows a rather clean separation of field stars from Phoenix members. The discovery of a Mira variable ( P = 425 d), which is almost certainly a carbon star, leads to an estimate of the distance modulus of 23.10 ± 0.18 that is consistent with other estimates and indicates the existence of a significant population of age ∼2 Gyr. The two carbon stars of Da Costa have   M _bol=−3.8  and are consistent with belonging to a population of similar age; some other possible members of such a population are identified. A Da Costa non-carbon star is  Δ K _s∼ 0.3  mag brighter than these two carbon stars. It may be an asymptotic giant branch star of the dominant old population. The nature of other stars lying close to it in the   K _s, ( J − K _s)  diagram needs studying.     

Turbulence in the Stable Boundary Layer at Higher Richardson Numbers

We present some algebraic and numerical simulations of the stable boundary layer. We also discuss the problem of the existence of a critical Richardson number (Ri), beyond which the turbulence is suppressed. We compare the results of a second-order algebraic model with those of a third-order numerical model and, to this purpose, numerical simulations of a wind-tunnel flow, which is characterized by various Richardson numbers, were performed. As far as the second-order model is concerned, solutions, for the Richardson number greater than any critical value, can be obtained by modifying the time scales of the second-order equation pressure correlation terms in order to account for a buoyancy damping factor. We show that using a third-order model allows the same results (no critical Richardson number) to be obtained without modifications to the time scales. It is suggested that the non-locality, accounted for by the third-order moments, could allow the turbulence to persist also for Ri > 1.     

Seismic characterization of rigid sites in the ITACA database by ambient vibration monitoring and geological surveys

The problem of seismic characterization of rock-mass or stiff-soil outcrops by the use of passive seismic prospecting techniques is discussed. Difficulties in the application of this kind of procedure in the presence of rugged morphology, high surface wave velocities and low ambient vibration powers, typical of stiff-soil/rock-mass sites are examined. A methodology to face these problems is here proposed, which is based on the strict synergy of detailed geologic surveys and application of robust seismic prospecting techniques, jointly considering single-station and multi-station tools. The application of this approach for the characterization of a number of sites belonging to the Italian Accelerometric Network is described, focusing on two representative case histories.     

A full-scale study of Darcy-Weisbach friction factor for channels vegetated by riparian species

In this article, an open channel flow resistance equation, deduced applying dimensional analysis and incomplete self-similarity condition for the flow velocity distribution, was tested using measurements carried out in a full-scale channel equipped with three types of riparian plants (Salix alba L., Salix caprea L. and Alnus glutinosa L.). In the experimental channel, having banks lined with boulders, the vegetation branches were anchored in a concrete bottom. For each species, the measurements were carried out with plants having different amounts of leaves, different plant density and plant area index. The relationship between the scale factor Γ of the velocity profile and the Froude number was separately calibrated by measurements carried out without and with vegetation. The component of Darcy-Weisbach friction factor corresponding to the riparian vegetation f_v was calculated as the difference between the measured friction factor value (channel grain roughness + vegetation) and that calculated for the channel without vegetation in the same hydraulic conditions. Using these f_v values, the relationship between the scale factor Γ and the Froude number was calibrated. In this last relationship, a scaling coefficient a varying with the investigated vegetation type was introduced. This coefficient, as expected, gives the highest friction factor values for vegetation having branches with leaves. The theoretical flow resistance law, coupled with the relationship for estimating the Γ function having a scaling coefficient different for each investigated vegetation type, allowed an accurate estimate of the Darcy-Weisbach friction factor (errors less than or equal to 20% for 82.6% of the investigated cases). Finally, for the investigated vegetation species that are characterized by a condition with few leaves or leafless, the scaling coefficient a resulted strongly related to the bending stiffness. This analysis demonstrated that the highest Darcy-Weisbach friction factors correspond to vegetation species characterized by the highest values of bending stiffness. The friction factor values calculated for this last condition are characterized by errors that were less than or equal to ±20% for 90.6% of cases.     

黄龙与黄石钙华微生物沉积作用比较研究

本文通过调查黄龙风景区水体的环境地质特征与微生物群落结构及多样性,并与黄石公园对比分析,探讨了两种特殊地理环境下的微生物群落结构和多样性及其对钙华沉积的影响。结果表明：黄龙沟泉水属于地下冷泉,且景区内覆盖着大量植被,水体中有大量藻类和细菌;黄石公园猛犸象温泉区泉水属于地下热泉,植被覆盖率很低,泉水中微生物多为嗜热菌,藻类较少。黄龙与黄石钙华主要由方解石组成并且微生物参与了钙华的形成过程。微生物对钙华沉积的作用,主要分为模板作用、产物诱导作用和代谢调控作用,对比探讨了特殊地质环境下的微生物对钙华沉积的贡献,指出微生物沉积作用在钙华沉积过程中的重要性,可为黄龙钙华“黑化”防治提供理论依据。     

Risk analysis for remediation of contaminated sites: the geostatistical approach

The assessment of the risks associated with contamination by elevated levels of pollutants is a major issue in most parts of the world. The risk arises from the presence of a pollutant and from the uncertainty associated with estimating its concentration, extent and trajectory. The uncertainty in the assessment comes from the difficulty of measuring the pollutant concentration values accurately at any given location and the impossibility of measuring it at all locations within a study zone. Estimations tend to give smoothed versions of reality, with the smoothing effect being inversely proportional to the amount of data. If risk is a measure of the probability of pollutant concentrations exceeding specified thresholds, then the variability is the key feature in risk assessment and risk analysis. For this reason, geostatistical simulations provide an appropriate way of quantifying risk by simulating possible “realities” and determining how many of these realities exceed the contamination thresholds, and, finally, provides a means of visualizing risk and the geological causes of risk. This study concerns multivariate simulations of organic and inorganic pollutants measured in terrain samples to assess the uncertainty for the risk analysis of a contaminated site, an industrial site in northern Italy that has to be remediated. The main geostatistical tools are used to model the local uncertainty of pollutant concentrations, which prevail at any unsampled site, in particular by means of stochastic simulation. These models of uncertainty have been used in the decision-making processes to identify the areas targeted for remediation.     

Influence of FPS bearing properties on the seismic performance of base‐isolated structures

The paper analyzes the influence of friction pendulum system (FPS) isolator properties on the seismic performance of base‐isolated building frames. The behavior of these systems is analyzed by employing a two‐degree‐of‐freedom model accounting for the superstructure flexibility, whereas the FPS isolator behavior is described by adopting a widespread model that considers the variation of the friction coefficient with the velocity. The uncertainty in the seismic input is taken into account by considering a set of natural records with different characteristics scaled to increasing intensity levels. The variation of the statistics of the response parameters relevant to the seismic performance is investigated through the nondimensionalization of the motion equation and an extensive parametric study carried out for different isolator and system properties. The proposed approach allows to explore a wide range of situations while limiting the required nonlinear response history analyses. Two case studies consisting of base‐isolated building frames described as shear‐type systems are finally investigated in order to demonstrate the capabilities of the proposed simplified model in unveiling the essential characteristics of the performance of buildings isolated with FPS bearings. Copyright © 2015 John Wiley & Sons, Ltd.     

Flexural uplift of a lithospheric slab near the Vema transform (Central Atlantic): Timing and mechanisms

The Vema Transverse Ridge (VTR) is a prominent, long and narrow topographic anomaly that runs for over 300 km along a sea floor spreading flow line south of the Vema transform at 11° N in the Atlantic. It rises abruptly about 140 km from the axis of the Mid-Atlantic Ridge (MAR) in 10 Myr old crust and runs continuously up to 25 Myr old crust. It reaches over 3 km above the predicted lithospheric thermal contraction level. It is absent in crust younger than 10 Myr; thus, the uplift of the VTR must have ended roughly 10 Ma. The VTR is interpreted as the exposed edge of a flexured and uplifted slab of oceanic lithosphere that was generated at an 80 km long MAR segment. Based on satellite gravimetry imagery this MAR segment was born roughly 50 Ma and increased its length at an average rate of 1.6 mm/yr. Multibeam data show that the MAR-parallel sea floor fabric south of the VTR shifts its orientation by 5° to 10° clockwise in 11–12 Myr old crust, indicating a change at that time of the orientation of the MAR axis and of the position of the Euler rotation pole. This change caused extension normal to the transform, followed between 12 and 10 Ma by flexure of the edge of the lithospheric slab, uplift of the VTR at a rate of 2 to 4 mm/yr, and exposure of a lithospheric section (Vema Lithospheric Section or VLS) at the northern edge of the slab, parallel to the Vema transform. Ages of pelagic carbonates encrusting ultramafic rocks sampled at the base of the VLS at different distances from the MAR axis suggest that the entire VTR rose vertically as a single block within the active transform offset. A 50 km long portion of the crest of the VTR rose above sea level, subsided, was truncated at sea level and covered by a carbonate platform. Subaerial and submarine erosion has gradually removed material from the top of the VTR and has modified its slopes. Spreading half rate of the crust south of the transform decreased from 17.2 mm/yr between 26 and 19 Ma to 16.9 mm/yr between 19 and 10 Ma, to 13.6 mm/yr from 10 Ma to present. The slowing down of spreading occurred close in time to the change in ridge/transform geometry, suggesting that the two events are related. A numerical model relates lithospheric flexure to extension normal to the transform, suggesting that the extent of the uplift depends on the thickness of the brittle layer, consistent with the observed greater uplift of the older lithosphere along the VTR.