Evaluation of an automated EA-IRMS method for total carbon analysis of atmospheric aerosol at HEKAL

Comprehensive atmospheric studies have demonstrated that carbonaceous particles are one of the main components of atmospheric aerosols over Europe. The aim of our study was to establish an automated elemental analyser interfaced to a stable isotope mass spectrometer (EA-IRMS) method at the Hertelendi Laboratory of Environmental Studies (HEKAL), as a suitable method of quantification of total carbon mass in individual PM_2.5 aerosol samples. Total carbon (TC) mass and simultaneous stable isotopic ratios were determined for both test standard and genuine aerosol samples. Finally, the results were compared to the ones obtained independently by an alternative sealed tube combustion method developed previously at HEKAL. The TC recovery tests of standard material prepared by the sealed tube method confirmed at least a carbon recovery yield of 92% for a broad range of carbon mass (100–2000 μg). The stable isotopic results confirmed that sealed tube method is reproducible and suitable to be used as a reference to verify our new EA-IRMS method. The EA-IRMS TC measurements of genuine aerosols gave on average 3% higher carbon recovery yield, relative to the uncorrected results of the sealed tube method. The comparison of the stable isotopic results by the two methods for aerosols also showed minimal differences. Consequently, the possibility of simultaneous TC and stable isotopic analyses makes the EA-IRMS method a very attractive alternative for continuous measurement of aerosols, with an accuracy and reliability similar to other commercial devices.     

A hydrogeological type section for the Duna-Tisza Interfluve, Hungary

The Duna-Tisza Interfluve, Hungary has an agricultural economy but is plagued by severe problems of soil and wetland salinization despite 200 years of intensive research. The study’s objective was to determine the origin of salts and the mechanisms of salinity distribution. To this end, flow-patterns and chemistry of groundwater were evaluated in a 100 km?×?65 km area, with emphasis on the Kolon- and Kelemenszék Lakes region. The lakes are located 13 km apart and have chemically contrasting water and soil types. Two groundwater flow-domains were identified: a gravity-drive meteoric fresh water and an over-pressured deeper domain of saline water. The waters are channeled by a highly permeable gravel aquifer to the surface and may merge near Kelemenszék Lake, causing it to be saline. Kolon Lake receives meteoric groundwater only, hence its fresh chemical character. The cross-formational ascent of the deep waters, combined with the gravitational systems’ geometry and the flow-channeling effect of the near-surface rocks, explains the contrasting chemistry between lakes, and the origin and pattern of soil salinization. The scheme is proposed as a generally valid hydrogeological profile for the interfluve, and has been named the Duna-Tisza Interfluve Hydrogeological Type Section.     

Compartmented flow at the Bátaapáti site in Hungary

Integration of hydrogeological and geological data into a conceptual model is critical for site investigation programs, since this model is the basis for hydrogeological modeling and for engineering. In the Hungarian Radioactive Waste Disposal Investigation Program, several methods have been used to characterize the potential host rock (granite) at the Bátaapáti site for a repository for low and intermediate level radioactive waste. Hydrogeological data acquisition revealed some characteristic aspects of the site. One of the most important is the presence of extensive rock deformation zones (faults) with low hydraulic conductivity, which strongly reduce the direct hydraulic communication between adjacent blocks of rock (compartmentalization). This characteristic of the rock mass results in a mosaic-like distribution of rock compartments, each with an almost constant hydraulic head. Within the compartments, hydraulic tests have shown that transmissivity is strongly scale dependent: the larger the scale, the higher the measured transmissivity. The extensive highly transmissive zones cause very low hydraulic gradients within each block, thus the transport processes are strongly influenced by the low or average transmissivity zones and the rock matrix.     

Life in the sublittoral zone of long-lived Lake Pannon: paleontological analysis of the Upper Miocene Szák Formation,Hungary

Life and depositional environments in the sublittoral zone of Lake Pannon, a large, brackish Paratethyan lake from the Late Miocene, were reconstructed from fossils and facies of the Szák Formation. This formation is exposed in several, roughly coeval (9.4–8.9 Ma) outcrops, located along strike of the paleo-shelf-break in northwestern Hungary. The silty argillaceous marl of the formation was deposited below storm wave base, at 20–30 to 80–90 m water depth. The abundance of benthic organisms indicates that the bottom water was usually well oxygenated. Interstitial dysoxia, however, may have occurred immediately below the sediment–water interface, as evidenced by occasional preservation of trace fossils such as Diplocraterion. The fauna comprised endemic mollusks, including brackish cockles of the subfamily Lymnocardiinae, dreissenid mussels (Congeria), and highly adapted, uniquely large-sized deep-water pulmonate snails (planorbids and lymnaeids). Ostracods were dominated by endemic species and, in some cases, endemic genera of candonids, leptocytherids, cypridids, and loxoconchids. Fish remnants include a sciaenid otolith and the oldest skeletal occurrence of Perca in Europe. The phytoplankton comprised exclusively endemic coccolithophorids, mostly endemic dinoflagellates (prevailingly Spiniferites), and cosmopolitan green algae. The Late Miocene fauna and flora of Lake Pannon were in many ways similar to the modern Caspian biota, and in particular cases can be regarded as its precursor.     

A chironomid-based reconstruction of late glacial summer temperatures in the southern Carpathians (Romania)

Late glacial and early Holocene summer temperatures were reconstructed based on fossil chironomid assemblages at Lake Brazi (Retezat Mountains) with a joint Norwegian–Swiss transfer function, providing an important addition to the late glacial quantitative climate reconstructions from Europe. The pattern of the late glacial temperature changes in Lake Brazi show both similarities and some differences from the NGRIP δ¹⁸O record and other European chironomid-based reconstructions. Our reconstruction indicates that at Lake Brazi (1740 m a.s.l.) summer air temperature increased by ~ 2.8°C at the Oldest Dryas/Bølling transition (GS-2/GI-1) and reached 8.1–8.7°C during the late glacial interstade. The onset of the Younger Dryas (GS-1) was characterized by a weak (< 1°C) decrease in chironomid-inferred temperatures. Similarly, at the GS-1/Holocene transition no major changes in summer temperature were recorded. In the early Holocene, summer temperature increased in two steps and reached ~ 12.0–13.3°C during the Preboreal. Two short-term cold events were detected during the early Holocene between 11,480–11,390 and 10,350–10,190 cal yr BP. The first cooling coincides with the Preboreal oscillation and shows a weak (0.7°C) temperature decrease, while the second is characterized by 1°C cooling. Both cold events coincide with cooling events in the Greenland ice core records and other European temperature reconstructions.     

Some expanding and shearing viscous fluid cosmological models in general relativity

Two cylindrically-symmetric cosmological models representing viscous fluid distributions when free-gravitational field of typeD where coefficient of shear viscosity is assumed to be proportional to the rate of expansion, are obtained. The behaviour of the models in the absence of viscosity and other physical properties are also discussed.     

An analysis of surges triggered by a small flare

On 22 October, 1980, near the solar central meridian in the western vicinity of a large spot group, a subflare of the two-ribbon type was observed. Three surges were associated with this flare. Their starting points were situated close to the principal flare patches on both sides of a short filament that was visible for only a few hours. True flow velocities and decelerations along the arch-shaped surge trajectories have been determined for two of the surges. The highest velocities were found at the onset of the surges.The event was studied from a series of H on- and off-band flltergrams taken with the Debrecen coronagraph of 53 cm aperture.     

Thermal stability of extended clusters in dravite: a combined EMP,SREF and FTIR study

A dravite from Yemen of near end-member composition was treated in air and hydrogen atmospheres at 600–900 °C to reveal changes in Mg and Al order over the octahedrally coordinated Y and Z sites, and to explore related changes in the characteristic vibrational bands in the principal (OH)-stretching frequency. Relevant information was obtained using electron microprobe analysis (EMPA), structural refinement (SREF) and polarized infrared (IR) single-crystal spectroscopy. Overall, the EMPA, SREF and IR data show that only minor changes occur during thermal treatment up to at least 800 °C, including variations in structural parameters, Mg–Al order–disorder and (OH)-stretching bands, indicating limited hydrogen loss. Untreated and treated dravite samples have very similar long-range and short-range atomic structures, which may be related to the occurrence of stable Al–Mg extended clusters around the O1 (=W) and O3 (=V) sites: ^W(F)–^Y(MgMgMg)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]; ^W(OH)–^Y(MgMgAl)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]; ^W(O^2–)–^Y(AlAlAl)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]. These extended clusters remain stable to temperatures close to the observed start of decomposition (~900 °C).