Fractionation of Ni,Cr and Cu from Soil by Sequential Extraction Procedure and Determination by Inductively Coupled Plasma Optical Emission Spectrometry

Five‐step sequential extractions were employed to fractionation of Ni, Cr and Cu in soil polluted by anthropogenic activities and determine the mobility of the metals. Twelve samples were collected on an agricultural area that was located near an airport and intercity roads in Elazig‐Turkey. Exchangeable, organically bounded, carbonate bounded, adsorbed species on Fe and Mn oxides and residual species (except silicates) of Ni, Cr and Cu were extracted into solution by using CaCl₂, Na₄P₂O₇, Na₂EDTA, NH₂OH–HCl and HNO₃–H₂O₂, respectively. Mobile metal concentrations in fractions and total recoverable in soils were determined by using inductively coupled plasma‐optical emission spectrometry (ICP‐OES). Total recoverable Ni, Cr and Cu concentrations were in the range of 40–119, 45–126 and 23–72 mg kg^?1, respectively. It was observed that total concentrations of metals in some of the samples were higher than the permitted values. The sum of the mobile percentages of metals was found to be lower than 50%. The Ni, Cr and Cu percentages for exchangeable species are in the ranges of 0.18–1.64, 0.03–0.59 and 0.42–2.53%, respectively.     

Assessing seismic response of a 2D roller-compacted concrete dam under variable reservoir lengths

Finite element method (FEM) is effectively used for evaluating roller-compacted concrete (RCC) dams, especially in high seismicity zones. The aim of this study is to investigate the effect of various reservoir lengths on the seismic response of a selected RCC dam under strong ground motion effects. Six different reservoir lengths, the lengths varies from h/2 to 10h (h, the height of dam), are used within finite element models. The hydrodynamic pressure of the reservoir water is modelled with the 2D fluid finite elements based on the Lagrangian approach. The horizontal and vertical components of the 1989 Mw 6.9 Loma Prieta earthquake are utilized in numerical analyses. The non-linear time-history analyses of those six models are investigated by using Drucker-Prager material model. According to the numerical analysis, it is obvious that the seismic behavior of the RCC dams is considerably dependent on the reservoir length. By increasing the length, we have obtained higher displacement values, which exist until the reservoir length reaches the 3h; at increased lengths, the values remain stable. This result proposes that 3h reservoir length is adequate to assess the seismic response of RCC dams. The principal tensile stresses are relatively lower in non-linear analysis compared to linear analyses. However, the principal compression stresses are close to each other in linear and non-linear analyses. The results imply that the non-linear response is influential on the total seismic response of a dam, which cannot be neglected in numerical analysis.     

Changes in algal, coral and fish assemblages along water quality gradients on the inshore Great Barrier Reef

Macroalgae, hard corals, octocorals, and fish were surveyed on 10 to 13 inshore coral reefs of the Great Barrier Reef, along a water quality gradient in two regions with contrasting agricultural land use. A water quality index was calculated for each reef based on available data of particulate and dissolved nutrients, chlorophyll and suspended solids. Strong gradients in ecological attributes occurred along the water quality gradient. Macroalgae of the divisions Rhodophyta and Chlorophyta increased with increasing nutrients, while Phaeophyta remained similar. Octocoral richness and abundances of many hard coral and octocoral taxa decreased, and none of the hundreds of species increased. At reefs in higher nutrient environments, hard coral and octocoral assemblages were composed of subsets of the many species found in lower nutrient environments, whereas fish and macroalgal assemblages consisted of contrasting suites of species. The study identifies species groups that are likely to increase or decrease in abundance with changing water quality.     

Use of interactive multisensor snow and ice mapping system snow cover maps (IMS) and artificial neural networks for simulating river discharges in Eastern Turkey

Basins located in Eastern Turkey are largely fed by snowmelt runoff during spring and early summer seasons. This study investigates the efficiency of artificial neural networks (ANNs) in snowmelt runoff generation. Although ANNs have been used for streamflow simulating/forecasting in the last two decades, using satellite-based snow-covered area (SCA) maps and meteorological observations as inputs to ANN provides a novel basis for estimating streamflow. The proposed methodology is implemented over Upper Euphrates River Basin in Eastern Turkey. SCA data was acquired from Interactive Multisensor Snow and Ice Mapping System (IMS) for an 8-year period from February 2004 to September 2011. Meteorological observations including daily cumulative precipitation and daily average air temperatures were obtained from Turkish State Meteorological Services. The simulation results are promising with coefficient of correlation varying from 0.67 to 0.98 among proposed models. Past days discharge was found to substantially improve the forecast accuracy. The paper presents the expected basin discharge for 2011 water year based on meteorological observations and SCA input.     

DEM modeling of a monowire cutting system

Monowire block cutting machines can be used for natural stone block squaring and slab cutting operations. The plants where the cutting operations are performed demand high product quality with minimum operational costs. The major parameters affecting the economy of the operation are the energy consumed and the wear induced on the diamond beads during the cutting operation. An efficient cutting operation can only be maintained by selecting proper cutting parameters. Therefore, cutting parameters should be clearly understood. Experimental studies and numerical modeling methods are significant in terms of identifying the energy consumption occurring during natural stone cutting with monowire. Experimental studies and numerical modeling using discrete element method were performed on Afyon White Marble. Experimental studies have been performed by using a specially designed, fully automatic monowire cutting machine, and numerical analyses were carried out by commercially available software called three-dimensional particle flow code (PFC3D). A discrete element model for the cutting operation was developed, and various numerical models were performed for different peripheral speeds and cutting speeds, while, at the same time, the actual cutting operations were being carried out in the laboratory. Finally, the data obtained from the experimental works were compared with the data from numerical modeling. A comparison indicates that the frictional energy values obtained by means of numerical modeling are in good agreement with the results of the laboratory measurements. This study clearly put forward the influences of effective parameters on monowire cutting operations in natural stone industry. Furthermore, it filled an important space in the literature about the use of monowire block squaring machines.     

Magnetic susceptibility and VLF-R investigations for determining geothermal blowout contaminated area: a case study from Alaşehir (Manisa/Turkey)

Western Turkey is one of the most spectacular regions of widespread, active continental extension in the world. The most prominent structures of this region are E–W trending Gediz and Büyük Menderes Grabens. Geothermal activity around city of Manisa in Gediz Graben has been investigated by many researchers and many geothermal boreholes were drilled in order to produce electricity. In the middle of May 2012, a geothermal blowout occurred 150 m away from the deep drilling (depth 1,100 m), in Alkan village of Ala?ehir resort in city of Manisa. After that, four big blowouts took place at the same area and thermal water had been diverted to Alkan stream for almost 4 months. The boron (B) and Fe levels of thermal water are 87 and 11.2 ppm where the background B and Fe values of topsoil vary between 0.2–1.5 ppm and 3.08–5.63 ppm, respectively. The objective of this study was to utilize joint magnetic susceptibility and VLF-R investigations to determine possibly contaminated area with B, related to high Fe level on the topsoil and thermal water in the subterranean layers. It is observed that magnetic susceptibility values vary between 500 and 790 cgs (×10^?6) in the vicinity of blowouts and 150–340 cgs (×10^?6) at a distance of 50 m around, where the background average value is 20 cgs (×10^?6), by using the data collected at 346 stations. Besides, the VLF-R studies were carried out along 18 profiles at three different frequencies. Laterally constrained two-layer inversion was applied to each station; in addition to the inversion of all profiles for each frequency, all lines were stacked, 2-D resistivity maps were obtained, and the contaminated area was determined approximately as 35,000 m². The results show not only satisfactory agreement between magnetic susceptibility and VLF-R data, but also provide fast and valued interpretation of geochemical and geophysical properties of the geothermal contaminated area.     

Validation of the Meteosat Second Generation (MSG) fire monitoring product using ground observations over Turkey

Validation of the active fire monitoring (FIR) product from Spinning Enhanced Visible and Infrared Imager sensor of Meteosat Second Generation satellite is performed over Turkey. Ground truth data from the Ministry of Environment and Forestry for the years 2007, 2008, and 2009 is used by taking the active fire months of April–September into consideration. The contingency tables are obtained on a monthly basis and categorical statistics of probability of detection (POD) and false alarm rate (FAR) are derived. The results are introduced for each subclass, namely probable, possible, and combined cases. The highest POD amounts of 8.5, 1.93, and 9.4 % are obtained for the possible, probable, and combined cases, respectively, with the lowest FAR amounts of 70.9, 4.5, and 86.1 % for the same categories. FIR product validation with respect to predefined burnt area thresholds is introduced in the second part of the study in order to investigate burnt area effect in active fire detection. Increasing POD values with respect to burnt area amount is obtained with relatively higher values in probable than possible type. On the other hand, FAR variation is observed to be not correlated with the burnt area amount.     

Seismic failure probability of concrete slab on CFR dams with welded and friction contacts by response surface method

In this study, failure probability of the concrete slab on concrete-faced rockfill (CFR) dams with welded and friction contact is investigated under earthquake effects by reliability analysis. For this purpose, Torul CFR dam is selected as an example and numerical solutions are performed by considering combination of reliability analysis–finite element method. 1992 Erzincan earthquake acceleration record is used in the finite element analysis considering deconvolved-base rock input model. In this model, the ground motion to be applied to the foundation base rock is obtained by deconvolution of the free-field surface record. In the materially nonlinear analysis, Drucker–Prager model is used for concrete slab and multi-linear kinematic hardening model is utilized for rockfill. Geometrically nonlinearity is also taken into account. Viscous boundary conditions are defined in the finite element model for both foundation soil and reservoir water. The hydrodynamic pressure of the reservoir water is considered using 2D fluid finite elements based on the Lagrangian approach. Both welded contact and friction contact based on the Coulomb’s friction law are defined in the structural connections. Improved Rackwitz–Fiessler method is used with response surface method in the reliability analysis. The tensile and compression strengths of the concrete slab are utilized in the implicit limit state functions considering various thicknesses. The probability of failure of the most critical points in the concrete slab is obtained. According to this study, the probabilities of failure obtained from the CFR dam including friction contact are lower. When the welded contact is considered in joints, the probability of failure of the concrete slab is 1 due to tensile stress limit state and compression stress limit state only if concrete slab is linear. The most critical probability of failure of the concrete slab appears in the case that the concrete slab is linear and rockfill is materially nonlinear. The probability of failure of the concrete slab decreases if the nonlinearity of the concrete is considered. Also, hydrodynamic pressure decreases the reliability of the concrete slab.