A case study of land cover change (1950-2003) and runoff in a Mediterranean catchment

Mediterranean environments have been subject to major land cover change since the end of the second world war. Housing, agricultural activities, forests, green spaces and other land uses have shifted due to urbanisation and tourism. These changes influence runoff, and municipal authorities often cannot estimate the net impact of complex land cover transitions. During this period, elected representatives have become increasingly sensitive to the risks of flooding and have implemented a number of channel management strategies. The main objective of this case study was to analyse the impact of land cover change on total storm runoff between 1950 and 2003 in a Mediterranean catchment near St Tropez, France. A secondary objective was to compare these changes to the impacts of channel management on bankfull discharge. Aerial photographs were used to classify land cover in 3 urban categories, vineyards and bare soil, forests, and green spaces. Stream discharge was estimated using a distributed event based total runoff approach. After validating the model for a large winter event (114 mm) for 1982, runoff was calculated for the same event for 1950 and 2003. Land cover changes occurred mainly in the alluvial plain area. Total gauge catchment urban area increased from 30.1 ha to 393.8 between 1950 and 2003 at the expense mainly of agricultural land, but this was compensated in part by an increase in grassed area. Some of the loss in vineyards was replaced by clearing forested land on the first hills close to the plain. Bank stabilisation and channel maintenance since the 1980’s reduced surface roughness and increased channel area, thereby greatly increasing bankfull discharge. While the impact of urbanisation on runoff was small, channel management effects increased bankfull discharge substantially. Flood damage from extreme events was not studied here.     

Laboratory methods for evaluating migrated high molecular weight hydrocarbons in marine sediments at naturally occurring oil seeps

A laboratory study has been conducted to determine the best methods for the detection of C₁₀–C₄₀ hydrocarbons at naturally occurring oil seeps in marine sediments. The results indicate that a commercially available method using n-C₆ to extract sediments and gas chromatography–flame ionization detection (GC–FID) to screen the resulting extract is effective at recognizing the presence of migrated hydrocarbons at concentrations from 50 to 5000 ppm. When non-biodegraded, the amount of oil charge is effectively tracked by the sum of n-alkanes in the gas chromatogram. However, once the charge oil becomes biodegraded, with the loss of n-alkanes and isoprenoids, the amount of oil is tracked by the quantification of the unresolved complex mixture (UCM). Gas chromatography–mass spectrometry (GC–MS) was also found to be very effective for the recognition of petroleum related hydrocarbons and results indicate that GC–MS would be a very effective tool for screening samples at concentrations below 50 ppm oil charge.     

Contour current imprints and contourite drifts in the Bahamian archipelago

New data collected along the slopes of Little and Great Bahama Bank and the abyssal plain of the Bahama Escarpment provides new insights about contour current‐related erosive structures and associated deposits. The Bahamian slope shows abundant evidence of bottom current activity such as furrows, comet‐like structures, sediment waves and drifts. At a seismic scale, large erosion surfaces and main periods of drift growth resulted from current acceleration related to plate tectonic processes and progressive opening and closure of gateways and long‐term palaeoclimate evolution. At present‐day, erosion features and contourite drifts are either related to relatively shallow currents (<1000 m water depth) or to deep currents (>2500 m water depth). It appears that the carbonate nature of the drifts does not impact the drift morphology at the resolution addressed in the present study. Classical drift morphologies defined in siliciclastic environments are found, such as mounded, plastered and separated drifts. In core, contourite sequences show a bi‐gradational trend that resembles classical contourite sequences in siliciclastic deposits showing a direct relationship with a change in current velocity at the sea floor. However, in a carbonate system the peak in grain size is associated with increased winnowing rather than increased sediment supply as in siliciclastic environments. In addition, the carbonate contourite sequence is usually thinner than in siliciclastics because of lower sediment supply rates. Little Bahama Bank and Great Bahama Bank contourites contain open‐ocean input and slope‐derived debris from glacial episodes. Inner platform, platform edge and open ocean pelagic input characterize the classical periplatform ooze during interglacials. In all studied examples, the drift composition depends on the sea floor topography surrounding the drift location and the type of sediment supply. Carbonate particles are derived from either the slope or the platform in slope and toe of slope drifts, very deep contourites have distant siliciclastic sources of sediment supply. The recent discovery of the importance of a large downslope gravitary system along Bahamian slopes suggests frequent interactions between downslope and along‐slope (contour currents) processes. The interlayering of mass flow deposits and contourites at a seismic scale or the presence of surface structures associated with both contour currents and mass flow processes shows that both processes act at the same location. Finally, contour currents have an important impact on the repartition of deep‐water coral mounds. Currents can actively interact with mounds as a nutrient and oxygen supplier or have a passive interaction, with mounds solely being obstacles orienting erosion and deposition.     

Formation of magnesium‐smectite during lacustrine carbonates early diagenesis: Study case of the volcanic crater lake Dziani Dzaha (Mayotte – Indian Ocean)

The volcanic crater lake of Dziani Dzaha in Mayotte is studied to constrain the geochemical settings and the diagenetic processes at the origin of Mg‐phyllosilicates associated with carbonate rocks. The Dziani Dzaha is characterized by intense primary productivity, volcanic gases bubbling in three locations and a volcanic catchment of phonolitic/alkaline composition. The lake water has an alkalinity of ca 0·2 mol l^?1 and pH values of ca 9·3. Cores of the lake sediments reaching up to one metre in length were collected and studied by means of carbon–hydrogen–nitrogen elemental analyzer, X‐ray fluorescence spectrometry and X‐ray powder diffraction. In surface sediments, the content of total organic carbon reaches up to 20 weight %. The mineral content consists of aragonite and hydromagnesite with minor amounts of alkaline feldspar and clinopyroxene from the volcanic catchment. Below 30 cm depth, X‐ray diffraction analyses of the <2 μm clay fraction indicate the presence of a saponite‐like mineral, a Mg‐rich smectite. The saponite‐like mineral accumulates at depth to reach up to ca 30 weight %, concurrent with a decrease of the contents of hydromagnesite and organic matter. Thermodynamic considerations and mineral assemblages suggest that the evolution of the sediment composition resulted from early diagenetic reactions. The formation of the saponite‐like mineral instead of Al‐free Mg‐silicates resulted from high aluminum availability, which is favoured in restricted lacustrine environments hosted in alkaline volcanic terrains commonly emplaced during early stages of continental rifting. Supersaturation of the lake water relative to saponite is especially due to high pH values, themselves derived from high primary productivity. This suggests that a genetic link may exist between saponite and the development of organic‐rich carbonate rocks, which may be fuelled by the input of CO₂‐rich volcanic gases. This provides novel insights into the composition and formation of saponite‐rich deposits under a specific geodynamic context such as the Cretaceous South Atlantic carbonate reservoirs.     

Interactions between Volatile Reduced Sulfur Compounds and Metals in the Seine Estuary (France)

Concentrations of volatile hydrogen sulfide (H₂S), carbonyl sulfide (OCS), methane thiol (MeSH), dimethyl sulfide (DMS), and dimethyl disulfide (DMDS) in the Seine estuary (France) were investigated in spring 2005 using samples collected from the first meter beneath the surface. Levels of dissolved metals (Ag, Cd, Cu, Zn, Ni, Co, Pb), suspended particulate matter, and particular organic carbon were also assessed. Maximum concentrations were 0.80 nM for H₂S, 0.64 nM for OCS, 3.06 nM for MeSH, 11.06 nM for DMS, and 1.18 nM for DMDS, and different features were observed for the five volatile reduced sulfur compounds (VRSCs). Experiments were conducted to determine silver–VRSC conditional stability constants. Major interactions were observed between H₂S and Ag, which may partially account for the absence of volatile H₂S at the lowest salinities. OCS, MeSH, and DMS did not interact with Ag, as revealed by their insignificant K′ values. Variations in concentrations along the salinity gradient may be explained by the influence of phytoplanktonic compounds.