Experience of produced water treatment in the North Sea

This paper describes the experience of the Elf company regarding produced water treatment and disposal in the North Sea. It focuses on three fields where difficulties were faced: it evaluates the various treatment techniques used (plate separators, hydrocyclones, vapour stripping units, injection into a disposal well), the reasons for the problems encountered during the life of these fields and the efforts made to obtain a satisfactory quality of the produced water discharged. The contribution of recent or new technologies put on the market is discussed. It shows that, because of the nature of the effluents to be treated, and the fact that produced water characteristics depend largely on upstream treatment and processes, it is still very difficult to anticipate the correct design of an installation or to extrapolate from laboratory tests. For these reasons and others, the improvement of performance requires extensive effort by operators, process and design engineers in order to improve the quality of effluent discharged. Finally, it expounds the limits of the efforts made by industry to reduce the quantity of hydrocarbons released into the sea or to comply with present regulations. It emphasizes that not only costs are to be taken into account but also the adverse consequences of a further reduction of the limit for discharges, if this should happen. Such a measure would to the use of techniques which, in many cases, would increase the total impact of the produced water treatment and the human risk.     

The effects of vegetative ash on infiltration capacity, sediment transport, and the generation of progressively bulked debris flows

Through the alteration of the physical characteristics of a landscape, such as the destruction of vegetation and the formation of a hydrophobic layer, a fire can dramatically amplify erosion rates. On the basis of field observations, it has been proposed that the deposition of a layer of ash on the ground surface can enhance the erosion of mountainous terrain by surface runoff and might even be a necessary condition for the generation of progressively bulked debris flows. In this study, a flume was constructed to investigate the role of ash in increasing both the volume and the transport capacity of runoff. The experiments demonstrated that the presence of ash on the soil surface reduces the ability of flowing water to infiltrate; this effect is even greater when the ash has been pre-wetted. In addition, the ability of ash slurries to infiltrate decreases with increasing ash concentration. The results also indicate that the transport capacity of runoff is enhanced by the incorporation of ash into the flow because of the increased fluid density. However, the addition of ash reduces the boundary Reynolds number such that, at high ash concentrations and with fine-grained sediment, sediment transport declines as the flow becomes hydraulically smooth. The experimental results were also used to evaluate the ability of steep flow fronts, a common characteristic of debris flows and flash floods, to increase sediment transport rates. Finally, it is proposed that ash slurries may evolve into progressively bulked debris flows through a positive feedback between fluid density, transport capacity, and erosivity.     

A 17,900-year multi-proxy lacustrine record of Lago Puyehue (Chilean Lake District): introduction

This paper introduces the background and main results of a research project aimed at unravelling the paleolimnological and paleoclimatological history of Lago Puyehue (40° S, Lake District, Chile) since the Last Glacial Maximum (LGM), based on the study of several sediment cores from the lake and on extensive fieldwork in the lake catchment. The longest record was obtained in an 11-m-long piston core. An age-depth model was established by AMS ¹⁴C dating, ²¹⁰Pb and ²³⁷Cs measurements, identification of event-deposits, and varve-counting for the past 600 years. The core extends back to 17,915 cal. yr. BP, and the seismic data indicate that an open-lake sedimentary environment already existed several thousands of years before that. The core was submitted to a multi-proxy analysis, including sedimentology, mineralogy, grain-size, major geochemistry and organic geochemistry (C/N ratio, δ¹³C), loss-on-ignition, magnetic susceptibility, diatom analysis and palynology. Along-core variations in sediment composition reveal that the area of Lago Puyehue was characterized since the LGM by a series of rapid climate fluctuations superimposed on a long-term warming trend. Identified climate fluctuations confirm a.o. the existence of a Late-Glacial cold reversal predating the northern-hemisphere Younger Dryas cold period by 500–1,000 years, as well as the existence of an early southern-hemisphere Holocene climatic optimum. Varve-thickness analyses over the past 600 years reveal periodicities similar to those associated with the El Niño Southern Oscillation and the Pacific Decadal Oscillation, as well as intervals with increased precipitation, related to an intensification of the El Niño impact during the southern-hemisphere equivalent of the Little Ice Age.     

Giant submarine collapse of a carbonate platform at the Turonian–Coniacian transition: The Ayabacas Formation, southern Peru

The Ayabacas Formation of southern Peru is an impressive unit formed by the giant submarine collapse of the mid‐Cretaceous carbonate platform of the western Peru back‐arc basin (WPBAB), near the Turonian–Coniacian transition (～90–89 Ma). It extends along the southwestern edge of the Cordillera Oriental and throughout the Altiplano and Cordillera Occidental over >80 000 km² in map view, and represents a volume of displaced sediments of >10 000 km³. The collapse occurred down the basin slope, i.e. toward the SW. Six zones are characterised on the basis of deformational facies, and a seventh corresponds to the northeastern ‘stable’ area (Zone 0). Zones 1–3 display increasing fragmentation from NE to SW, and are composed of limestone rafts and sheets embedded in a matrix of mainly red, partly calcareous and locally sandy, mudstones to siltstones. In contrast, in Zones 4 and 5 the unit consists only of displaced and stacked limestone masses forming a ‘sedimentary thrust and fold system’, with sizes increasing to the southwest. In Zone 6, the upper part of the limestone succession consists of rafts and sheets stacked over the regularly bedded lower part. The triggering of this extremely large mass wasting clearly ensued from slope creation, oversteepening and seismicity produced by extensional tectonic activity, as demonstrated by the observation of synsedimentary normal faults and related thickness variations. Other factors, such as pore pressure increases or lithification contrasts probably facilitated sliding. The key role of tectonics is strengthened by the specific relationships between the basin and collapse histories and two major fault systems that cross the study area. The Ayabacas collapse occurred at a turning point in the Central Andean evolution. Before the event, the back‐arc basin had been essentially marine and deepened to the west, with little volcanic activity taking place at the arc. After the event, the back‐arc was occupied by continental to near‐continental environments, and was bounded to the southwest by a massive volcanic arc shedding debris and tuffs into the basin.     

Mineral Paragenesis and Ore‐Forming Processes of the Dongping Gold Deposit,Hebei Province,China

The Dongping gold deposit is located near the center of the northern margin of the North China Craton. It is hosted in the Shuiquangou syenite and characterized by large amounts of tellurides. Numerous studies have addressed this deposit; the mineral paragenesis and ore‐forming processes, however, are still poorly studied. In this contribution, a new mineral paragenesis has been evaluated to further understand ore formation, including sulfides (pyrite, chalcopyrite, galena, sphalerite, molybdenite, and bornite), tellurides (altaite, calaverite, hessite, muthmannite, petzite, rucklidgeite, sylvanite, tellurobismuthite, tetradymite, and volynskite), and native elements (tellurium and gold). Molybdenite, muthmannite, rucklidgeite, and volynskite are reported for the first time in this deposit. We consider the Dongping gold deposit mainly formed in the Devonian, and the ore‐forming processes and the physicochemical conditions for ore formation can be reconstructed based on our newly identified ore paragenesis, that is, iron oxides → (CO₂ effervescence) → sulfides → (fTe₂/fS₂ ratio increase) → Pb‐Bi‐tellurides → (condensation of H₂Te vapor) → Au‐Ag‐tellurides → (mixing with oxidizing water) → carbonate and microporous gold → secondary minerals → secondary minerals. The logfO₂ values increase from the early to late stages, while the fH₂S and logfS₂ values increase initially and then decrease. CO₂ effervescence is the main mechanism of sulfides precipitation; this sulfidation and condensation of H₂Te vapor lead to deposition of tellurides. The development of microporous gold indicates that the deposit might experience overprint after mineralization. The Dongping gold deposit has a close genetic relationship with the Shuiquangou syenite, and tellurium likely originated from Shuiquangou alkaline magmatic degassing.     

Is the connectivity function a good indicator of soil infiltrability distribution and runoff flow dimension?

Among the studies on runoff connectivity of soils with heterogeneous properties, the need to understand the relationships between soil heterogeneity and the associated runoff organization and amount is frequently mentioned. In this study, we simulate the stationary runoff–runon process on bi‐dimensional (2D) flat slopes for five infiltrability distributions, one of them correlated, as a function of rainfall intensity and flow dimension. We define flow dimension by 1 + ε, where ε is the outflow fraction transferred from one pixel to each of the two lateral downslope pixels. Our aim is to assess the effect of ε and soil heterogeneity on the connectivity function compared to the mean runoff flow rate, the wet area and the number of runoff patterns. The analysis of connectivity is carried within the percolation framework. The results show that the integral connectivity scale is more sensitive to the flow dimension and soil heterogeneity compared to the other variables. The wet area fraction does not depend on ε. Unlike previous studies, we find that increased runoff production is not necessarily related to increased connectivity. The use of the connectivity function within the percolation framework appears to be a valuable method for assessing the impact of soil heterogeneity and flow dimension on the runoff organization during a rainfall event. Copyright © 2014 John Wiley & Sons, Ltd.     

Analytical model for the in‐plane seismic performance of cold‐formed steel‐framed gypsum partition walls

This paper proposes an experimentally verified procedure to analytically model cold‐formed steel‐framed gypsum nonstructural partition walls considering all the critical components. In this model, the nonlinear behaviors of the connections are represented by hysteretic load‐deformation springs, which have been calibrated using the component‐level experimental data. The studs and tracks are modeled adopting beam elements with their section properties accounting for nonlinear behavior. The gypsum boards are simulated by linear four‐node shell elements. The proposed procedure is implemented to generate the analytical models of three full‐scale partition wall specimens in the OpenSees platform. The specimens were tested as a part of the NEESR‐GC Project on Simulation of the Seismic Performance of Nonstructural Systems. Force‐displacement responses, cumulative dissipated energy, and damage mechanisms from the analytical simulation are compared to the experimental results. The comparison shows that the analytical model accurately predicts the trend of the response as well as the possible damage mechanisms. The procedure proposed here can be adopted in future studies by researchers and also engineers to assess the seismic performance of partition walls with various dimensions and construction details, especially where test data are not available. Copyright © 2015 John Wiley & Sons, Ltd.     

Upscaling of CO2 vertical migration through a periodic layered porous medium: The capillary-free and capillary-dominant cases

We present an upscaled model for the vertical migration of a CO₂ plume through a vertical column filled with a periodic layered porous medium. This model may describe the vertical migration of a CO₂ plume in a perfectly layered horizontal aquifer. Capillarity and buoyancy are taken into account and semi-explicit upscaled flux functions are proposed in the two following cases: (i) capillarity is the main driving force and (ii) buoyancy is the only driving force. In both cases, we show that the upscaled buoyant flux is a bell-shaped function of the saturation, as in the case of a homogeneous porous medium. In the capillary-dominant case, we show that the upscaled buoyant flux is the harmonic mean of the buoyant fluxes in each layer. The upscaled saturation is governed by the continuity of the capillary pressure at the interface between layers. In the capillary-free case, the upscaled buoyant flux and upscaled saturation are determined by the flux continuity condition at the interface. As the flux is not continuous over the entire range of saturation, the upscaled saturation is only defined where continuity is verified, i.e. in two saturation domains. As a consequence, the upscaled buoyant flux is described by a piecewise continuous function. Two analytical approximations of this flux are proposed and this capillary-free upscaled model is validated for two cases of heterogeneity. Upscaled and cell averaged saturations are in good agreement. Furthermore, the proposed analytical upscaled fluxes provide satisfactory approximations as long as the saturation set at the inlet of the column is in a range where analytical and numerical upscaled fluxes are close.     

ERORUN-STAFOR: A collaborative observatory for the multidisciplinary study of the critical zone processes in a tropical volcanic watershed including a Tropical Montane Cloud Forest

Tropical volcanic islands are biodiversity hotspots where the Critical Zone (CZ) still remains poorly studied. In such steep topographic environments associated with extreme climatic events (cyclones), deployment and maintenance of monitoring equipment is highly challenging. While a few Critical Zone Observatories (CZOS) are located in tropical volcanic regions, none of them includes a Tropical Montane Cloud Forest (TMCF) at the watershed scale. We present here the dataset of the first observatory from the French network of critical zone observatories (OZCAR) located in an insular tropical and volcanic context, integrating a ‘Tropical Montane Cloud Forest’: The ERORUN-STAFOR observatory. This collaborative observatory is located in the northern part of La Réunion island (Indian Ocean) within the 45.0 km² watershed of Rivière des Pluies (i.e., Rainfall river) which hosts the TMCF of Plaines des Fougères, one of the best preserved natural habitats in La Réunion Island. Since 2014, the ERORUN-STAFOR monitoring in collaboration with local partners collected a multidisciplinary dataset with a constant improvement of the instrumentation over time. At the watershed scale and in its vicinity, the ERORUN-STAFOR observatory includes 10 measurement stations covering the upstream, midstream and downstream part of the watershed. The stations record a total of 48 different variables through continuous (sensors) or periodic (sampling) monitoring. The dataset consists of continuous time series variables related to (i) meteorology, including precipitation, air temperature, relative humidity, wind speed and direction, net radiation, atmospheric pressure, cloud water flux, irradiance, leaf wetness and soil temperature, (ii) hydrology, including water level and temperature, discharge and electrical conductivity (EC) of stream, (iii) hydrogeology, including (ground)water level, water temperature and EC in two piezometers and one horizontally drilled groundwater gallery completed by soil moisture measurements under the canopy. The dataset is completed by periodic time series variables related to (iv) hydrogeochemistry, including field parameters and water analysis results. The periodic sampling survey provides chemical and isotopic compositions of rainfall, groundwater, and stream water at different locations of this watershed. The ERORUN-STAFOR monitoring dataset extends from 2014 to 2022 with an acquisition frequency from 10 min to hourly for the sensor variables and from weekly to monthly frequency for the sampling. Despite the frequent maintenance of the monitoring sites, several data gaps exist due to the remote location of some sites and instrument destruction by cyclones. Preliminary results show that the Rivière des Pluies watershed is characterized by high annual precipitation (>3000 mm y⁻¹) and a fast hydrologic response to precipitation (≈2 h basin lag time). The long-term evolution of the deep groundwater recharge is mainly driven by the occurrence of cyclone events with a seasonal groundwater response. The water chemical results support existing hydrogeological conceptual models suggesting a deep infiltration of the upstream infiltrated rainfall. The TMCF of Plaine des Fougères shows a high water storage capacity (>2000% for the Bryophytes) that makes this one a significant input of water to groundwater recharge which still needs to be quantified. This observatory is a unique research site in an insular volcanic tropical environment offering three windows of observation for the study of critical zone processes through upstream-midstream-downstream measurements sites. This high-resolution dataset is valuable to assess the response of volcanic tropical watersheds and aquifers at both event and long-term scales (i.e., global change). It will also provide insights in the hydrogeological conceptual model of volcanic islands, including the significant role of the TMCFs in the recharge processes as well as the watershed hydrosedimentary responses to extreme climatic events and their respective evolution under changing climatic conditions. All data sets are available at https://doi.org/10.5281/zenodo.7983138 .     

Rotation of the Semail ophiolite (Oman): Additional Paleomagnetic data from the volcanic sequence

Thirty-two flows (247 cores) were sampled in the V1 (Geotimes) and V2 (Lasail) volcanic units of the Semail ophiolite, Oman (Aswad, Fizh, Hilti, Sarami, Wuqbah, and Tayin massifs). Paleomagnetic analysis of the samples was complicated by a large overlap of the two components of magnetization carried by the rocks: a crystalline remanent magnetization (CRM) acquired in the present day field, probably during weathering, and an older CRM probably produced by oxidation of the original titanomagnetites during hydrothermal event(s). If the magnetization carried by the V1 samples was acquired during the hydrothermal event related to the emplacement of these lava, e.g., during and/or shortly after cooling, the tectonic unity of the northern domain has to be questioned and a differential rotation considered between the Aswad and Hilti-Sarami massifs but, by the time of emplacement of the V2 series, this northern area seems to behave as one large unit. As only one set of data is available for the southern Tayin-Sumail massif, it is premature but a possible relative rotation on the order of 90° can be suspected between the Hilti-Sarami and Tayin-Sumail massifs, rotation which would have occurred after emplacement of the V2 series.