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181.
Alireza Bahadori Emmanuel John M. Carranza Bahman Soleimani 《Journal of Geochemical Exploration》2011,111(3):97-112
In this study, the paleo-sedimentary depositional environment of the Gachsaran Formation and the Asmari reservoir cap rock (i.e., the stratigraphically lowest member of the Gachsaran Formation) was investigated from elemental geochemical data and mineralogical data obtained XRF and SEM analyses, respectively, of anhydrite samples collected from two oil wells in the Zeloi oil field in southwestern Iran. The present data reveal that arid conditions and cycles of transgression–regression of the sea contributed to the formation of evaporite sequences of the Gachsaran Formation in a coastal sabkha-lagoon basin that was partly closed to the sea. This interpretation was based on synthesis of statistical correlation analysis the geochemical data, chemostratigraphic correlation of geochemical ratios, and textural analysis of salts observed in SEM images. 相似文献
182.
Elodie Philippe Florence Habets Emmanuel Ledoux Patrick Goblet Pascal Viennot Bruno Mary 《水文研究》2011,25(5):752-765
For predicting the evolution of solute concentrations in groundwater and testing the impact of remediation policies, a coupling between the agronomical model STICS and the hydrogeological model MODCOU was implemented. When applied to the Seine River basin, this model accurately represents the temporal evolution of average nitrate concentrations in the aquifer, but with large local errors. We propose an improvement to the simple unsaturated zone (UZ) scheme NonsatSW used in STICS–MODCOU. The modifications are based on a comparison with the mechanistic model Metis considered as a reference as it solves Richards' equation. A more realistic saturation profile and a varying percolation rate are integrated in NonsatSW. This new model, named NonsatVG, is assessed by comparing it with NonsatSW and Metis. In an ideal case, NonsatVG generates a solute transfer and a dispersion closer to that of Metis than of NonsatSW. In real cases, without additional calibration, NonsatVG and Metis simulate better the average transfer velocities of the observed nitrate profiles. Furthermore, modifications in NonsatVG give a direct relationship between the depth of the water table and the saturation profile. We obtain, therefore, as in Metis, an evolution of the solute transfer velocity depending on the piezometric level. These dynamics are not simulated in NonsatSW. Despite a modified water transfer through the UZ, NonsatVG is also as valid as NonsatSW in the modelling of water transfer to the saturated zone. Finally, an application to the Seine basin shows that solute transfer velocities are lower with NonsatVG than with NonsatSW, but are in better agreement with literature. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
183.
Walter Finsinger Daniele Colombaroli Jacques‐Louis De Beaulieu Verushka Valsecchi Boris Vannière Elisa Vescovi Emmanuel Chapron André F. Lotter Michel Magny Willy Tinner 《第四纪科学杂志》2010,25(8):1239-1247
Despite the high potential of pollen records for climate reconstruction, pollen–climate relationships may be biased due to past and present human activities on the landscape. We use (i) transfer functions based on modern pollen–climate relationships to infer seasonal temperature and summer precipitation for the period 11 500–4500 cal. a BP and (ii) lake‐level change records based on different sedimentary proxies in multiple cores that are mainly indicative for summer hydrology at Lago dell'Accesa (central Italy). Quantitative reconstructions indicate lowest summer precipitation during two phases (8500–7700 cal. a BP and after 6000 cal. a BP) and a gradual winter temperature increase from 11 500 to ca. 8000 cal. a BP. Lowest summer precipitation was reconstructed during these phases characterised by vegetation shifts from open forests dominated by summergreen oaks (Quercus) to forests dominated by evergreen oaks (Quercus ilex), which are at present most abundant where summer drought is stronger. Similarly, the lake‐level record indicates two long‐lasting low summer precipitation phases (8800–7700 and 6400–4400 cal. a BP) that were interrupted by short‐term high summer precipitation events. Based on the broad agreement between the pollen‐inferred summer precipitation and the low‐frequency lake‐level changes, we suggest that the duration of the high summer precipitation events may have been too short to maintain drought‐sensitive trees, which may have been affected by high mortality rates when summer dry conditions returned. Although past and modern pollen–climate relationships may very likely have been affected by human activities since the Neolithic (i.e. when exploitation of the landscape started), we reject the hypothesis of a significant anthropogenic bias in the pollen‐based climate reconstruction. In addition, we suggest that pollen‐based and lake‐level reconstructions may have different inherent abilities of capturing high‐ and low‐frequency precipitation signals. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
184.
185.
Brian A. Bergamaschi Jacob A. Fleck Bryan D. Downing Emmanuel Boss Brian A. Pellerin Neil K. Ganju David H. Schoellhamer Amy A. Byington Wesley A. Heim Mark Stephenson Roger Fujii 《Estuaries and Coasts》2012,35(4):1036-1048
We used high-resolution in situ measurements of turbidity and fluorescent dissolved organic matter (FDOM) to quantitatively estimate the tidally driven exchange of mercury (Hg) between the waters of the San Francisco estuary and Browns Island, a tidal wetland. Turbidity and FDOM??representative of particle-associated and filter-passing Hg, respectively??together predicted 94?% of the observed variability in measured total mercury concentration in unfiltered water samples (UTHg) collected during a single tidal cycle in spring, fall, and winter, 2005?C2006. Continuous in situ turbidity and FDOM data spanning at least a full spring-neap period were used to generate UTHg concentration time series using this relationship, and then combined with water discharge measurements to calculate Hg fluxes in each season. Wetlands are generally considered to be sinks for sediment and associated mercury. However, during the three periods of monitoring, Browns Island wetland did not appreciably accumulate Hg. Instead, gradual tidally driven export of UTHg from the wetland offset the large episodic on-island fluxes associated with high wind events. Exports were highest during large spring tides, when ebbing waters relatively enriched in FDOM, dissolved organic carbon (DOC), and filter-passing mercury drained from the marsh into the open waters of the estuary. On-island flux of UTHg, which was largely particle-associated, was highest during strong winds coincident with flood tides. Our results demonstrate that processes driving UTHg fluxes in tidal wetlands encompass both the dissolved and particulate phases and multiple timescales, necessitating longer term monitoring to adequately quantify fluxes. 相似文献
186.
Saibal Ghosh Cees J. van Westen Emmanuel John M. Carranza Victor G. Jetten 《Landslides》2012,9(3):371-384
Landslide risk assessment is based on spatially integrating landslide hazard with exposed elements-at-risk to determine their vulnerability and to express the expected direct and indirect losses. There are three components that are relevant for expressing landslide hazard: spatial, temporal, and magnitude probabilities. At a medium-scale analysis, this is often done by first deriving a landslide susceptibility map, and to determine the three types of probabilities on the basis of landslide inventories linked to particular triggering events. The determination of spatial, temporal, and magnitude probabilities depend mainly on the availability of sufficiently complete historical records of past landslides, which in general are rare in most countries (e.g., India, etc.). In this paper, we presented an approach to use available historical information on landslide inventories for landslide hazard and risk analysis on a medium scale (1:25,000) in a perennially typical data-scarce environment in Darjeeling Himalayas (India). We demonstrate how the incompleteness in the resulting landslide database influences the various components in the calculation of specific risk of elements-at-risk (e.g., buildings, population, roads, etc.). We incorporate the uncertainties involved in the risk estimation and illustrate the range of expected losses in the form of maximum and minimum loss curves. The study demonstrates that even in data-scarce environments, quantitative landslide risk assessment is a viable option, as long as the uncertainties involved are expressed. 相似文献
187.
Understanding the assemblage of basic grains is essential for predicting many soil properties. X-ray synchrotron microtomography with a high resolution was used for visualisation and quantification of the assemblage of silt grains with a clay phase containing 20% of clays. The 3D computed image was analysed after appropriate segmentation by using: (i) autocorrelation functions which enables anisotropy discussion of the assemblage; (ii) chord distribution which gives information on the size distribution of the void and solid phases; and (iii) the Hoshen-Kopelman algorithm (6-connectivity) in order to label each void with a unique number and thus enabling discussion of the connectivity. Our results show that X-ray synchrotron microtomography enables a more accurate analysis of the assemblage of silt grains with a clay phase than with conventional methods. Thus, it showed the isotropy of the silt-clay assemblage in the studied soil material. The void and solid phase volumes were smaller than 80 and 120 μm in all directions, respectively. The mean distance between two interfaces was 6.9 and 13.4 μm for the void and solid phase, respectively. X-ray synchrotron microtomography of the soil material studied also showed that the voids resulting from the assemblage of the silt grains with the clay phase can be considered as fully connected in the studied dried materials. 相似文献
188.
Raphaelle Escoube Olivier J. Rouxel Béatrice Luais Emmanuel Ponzevera Olivier F.X. Donard 《Geostandards and Geoanalytical Research》2012,36(2):149-159
Recent analytical developments in germanium stable isotope determination by multicollector ICP‐MS have provided new perspectives for the use of Ge isotopes as geochemical tracers. Here, we report the germanium isotope composition of the NIST SRM 3120a elemental reference solution that has been calibrated relative to internal isotopic standard solutions used in the previous studies. We also intercalibrate several geological reference materials as well as geological and meteoritic samples using different techniques, including online hydride generation and a spray chamber for sample introduction to MC‐ICP‐MS, and different approaches for mass bias corrections such as sample–calibrator bracketing, external mass bias correction using Ga isotopes and double‐spike normalisation. All methods yielded relatively similar precisions at around 0.1‰ (2s) for δ74/70Ge values. Using igneous and mantle‐derived rocks, the bulk silicate Earth (BSE) δ74/70Ge value was re‐evaluated to be 0.59 ± 0.18‰ (2s) relative to NIST SRM 3120a. Several sulfide samples were also analysed and yielded very negative values, down to ?4.3‰, consistent with recent theoretical study of Ge isotope fractionation. The strong heavy isotope depletion in ore deposits also contrasts with the generally positive Ge isotope values found in many modern and ancient marine sediments. 相似文献
189.
Beno?t Joseph Mbassa Emmanuel Njonfang Mathieu Benoit Pierre Kamgang Michel Grégoire Stephanie Duchene Pierre Brunet Bekoa Ateba Félix M. Tchoua 《Mineralogy and Petrology》2012,106(3-4):217-242
The Mbengwi recent magmatic formations consist of volcanics and syenites belonging to the same magmatic episode. Lavas form a bimodal basanite-rhyolite alkaline series with a gap between 50 and 62?wt.% SiO2. Mafic lavas (basanite-hawaiite) are sodic while felsic rocks (trachyte-rhyolite-syenites) are sodi-potassic, slightly metaluminous to peralkaline. The geochemical and isotopic characteristics (0.7031?<?(87Sr/86Sr)initial?<?0.7043; 1.03?<?εNdi?<?5.17) of these rocks are similar to those of other rocks from the CVL. The main differentiation process is fractional crystallization with two trends of fractionation. Their Rb/Sr isochron age of 28.2?Ma, almost similar to 27.40?±?0.6?Ma?K/Ar age obtained in a trachyte from neighboring Bamenda Mountains system, precludes any local age migration of an hypothetic hotspot. Mafic lavas have OIB features displaying an isotopic signature similar to that of HIMU mantle source different from FOZO known as source of most parental magmas along the CVL. 相似文献
190.
John R. Spencer Emmanuel Lellouch Miguel A. López-Valverde Thomas K. Greathouse Jean-Marie Flaud 《Icarus》2005,176(2):283-304
We have observed about 16 absorption lines of the ν2 SO2 vibrational band on Io, in disk-integrated 19-μm spectra taken with the TEXES high spectral resolution mid-infrared spectrograph at the NASA Infrared Telescope Facility in November 2001, December 2002, and January 2004. These are the first ground-based infrared observations of Io's sunlit atmosphere, and provide a new window on the atmosphere that allows better longitudinal and temporal monitoring than previous techniques. Dramatic variations in band strength with longitude are seen that are stable over at least a 2 year period. The depth of the strongest feature, a blend of lines centered at 530.42 cm−1, varies from about 7% near longitude 180° to about 1% near longitude 315° W, as measured at a spectral resolution of 57,000. Interpretation of the spectra requires modeling of surface temperatures and atmospheric density across Io's disk, and the variation in non-LTE ν2 vibrational temperature with altitude, and depends on the assumed atmospheric and surface temperature structure. About half of Io's 19-μm radiation comes from the Sun-heated surface, and half from volcanic hot spots with temperatures primarily between 150 and 200 K, which occupy about 8% of the surface. The observations are thus weighted towards the atmosphere over these low-temperature hot spots. If we assume that the atmosphere over the hot spots is representative of the atmosphere elsewhere, and that the atmospheric density is a function of latitude, the most plausible interpretation of the data is that the equatorial atmospheric column density varies from about 1.5×1017 cm−2 near longitude 180° W to about 1.5×1016 cm−2 near longitude 300° W, roughly consistent with HST UV spectroscopy and Lyman-α imaging. The inferred atmospheric kinetic temperature is less than about 150 K, at least on the anti-Jupiter hemisphere where the bands are strongest, somewhat colder than inferred from HST UV spectroscopy and millimeter-wavelength spectroscopy. This longitudinal variability in atmospheric density correlates with the longitudinal variability in the abundance of optically thick, near-UV bright SO2 frost. However it is not clear whether the correlation results from volcanic control (regions of large frost abundance result from greater condensation of atmospheric gases supported by more vigorous volcanic activity in these regions) or sublimation control (regions of large frost abundance produce a more extensive atmosphere due to more extensive sublimation). Comparison of data taken in 2001, 2002, and 2004 shows that with the possible exception of longitudes near 180° W between 2001 and 2002, Io's atmospheric density does not appear to decrease as Io recedes from the Sun, as would be expected if the atmosphere were supported by the sublimation of surface frost, suggesting that the atmosphere is dominantly supported by direct volcanic supply rather than by frost sublimation. However, other evidence such as the smooth variation in atmospheric abundance with latitude, and atmospheric changes during eclipse, suggest that sublimation support is more important than volcanic support, leaving the question of the dominant atmospheric support mechanism still unresolved. 相似文献