Enhancement and Mapping of Weak Multivariate Stream Sediment Geochemical Anomalies in Ahar Area,NW Iran

In this study, stream sediment geochemical data have been subjected to robust principal components analysis (RPCA) and singularity mapping (SM) to enhance and map significant multivariate geochemical anomalies (i.e., mineralization-related) in Ahar area, NW Iran. The RPCA was applied to (a) account for the compositional nature of stream sediment geochemical data using suitable log-ratio transformation, (b) modulate the effect of outliers in component estimation and (c) derive a multivariate geochemical footprint of mineralization. The SM was applied to extract anomalous patterns of the multivariate geochemical footprint of mineralization. The exploration targets were then delineated using Student’s t-statistics analysis. The correlations of mapped exploration targets with the known mineral occurrences and mineralization-related patterns were further evaluated using normalized density index and overall accuracy analyses.     

Volume diffusion of Ytterbium in YAG: thin-film experiments and combined TEM–RBS analysis

In this study, we address volume diffusion of ytterbium in yttrium aluminum garnet (YAG) using thin-film single crystal diffusion couples. We employ analytical transmission electron microscopy (ATEM) as a tool for combined microstructural and microchemical analysis and compare the results to Rutherford backscattering (RBS) analysis. Given the high spatial resolution of the method, we focus on microstructural changes of the thin-film diffusant source during the diffusion anneal. We evaluate the potential influence of the associated changes in its transport properties on the evolution of concentration profiles in the single crystal substrate. This approach allows us to test the reliability of determination of volume diffusion coefficients from thin-film diffusion experiments. We found that for the chosen experimental setting, the influence of thin-film re-crystallization is small when compared with the experimental uncertainty and good estimates for the volume diffusion coefficients of Yb in YAG can be obtained using standard assumptions. Both Yb-concentration profiles analyzed with ATEM and with RBS give similar results. At 1,450°C and 1 bar, we infer log D _Yb (m²/s) values of −19.37 ± 0.07 (TEM) and −19.84 ± 0.02 (RBS). Although the change in thin-film transport properties associated with successive crystallization during the diffusion anneal does not play a major role for our experimental setup, this effect cannot generally be ignored.     

Application of a semi-spectral cloud water parameterization to cooling tower plumes simulations

In order to simulate the plume produced by large natural draft cooling towers, a semi-spectral warm cloud parameterization has been implemented in an anelastic and non-hydrostatic 3D micro-scale meteorological code. The model results are compared to observations from a detailed field experiment carried out in 1980 at Bugey (location of an electrical nuclear power plant in the Rhône valley in East Central France) including airborne dynamical and microphysical measurements. Although we observe a slight overestimation of the liquid-water content, the results are satisfactory for all the 15 different cases simulated, which include different meteorological conditions ranging from low wind speed and convective conditions in clear sky to high wind and very cloudy. Such parameterization, which includes semi-spectral determination for droplet spectra, seems to be promising to describe plume interaction with atmosphere especially for aerosols and cloud droplets.     

Selection of Less Biased Threshold Angles for SAM Classification Using the Real Value–Area Fractal Technique

The accuracy of classification of the Spectral Angle Mapping (SAM) is warranted by choosing the appropriate threshold angles, which are normally defined by the user. Trial‐and‐error and statistical methods are commonly applied to determine threshold angles. In this paper, we discuss a real value–area (RV–A) technique based on the established concentration–area (C–A) fractal model to determine less biased threshold angles for SAM classification of multispectral images. Short wave infrared (SWIR) bands of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images were used over and around the Sar Cheshmeh porphyry Cu deposit and Seridune porphyry Cu prospect. Reference spectra from the known hydrothermal alteration zones in each study area were chosen for producing respective rule images. Segmentation of each rule image resulted in a RV–A curve. Hydrothermal alteration mapping based on threshold values of each RV–A curve showed that the first break in each curve is practical for selection of optimum threshold angles. The hydrothermal alteration maps of the study areas were evaluated by field and laboratory studies including X–ray diffraction analysis, spectral analysis, and thin section study of rock samples. The accuracy of the SAM classification was evaluated by using an error matrix. Overall accuracies of 80.62% and 75.45% were acquired in the Sar Cheshmeh and Seridune areas, respectively. We also used different threshold angles obtained by some statistical techniques to evaluate the efficiency of the proposed RV–A technique. Threshold angles provided by statistical techniques could not enhance the hydrothermal alteration zones around the known deposits, as good as threshold angles obtained by the RV–A technique. Since no arbitrary parameter is defined by the user in the application of the RV‐A technique, its application prevents introduction of human bias to the selection of optimum threshold angle for SAM classification.     

Spectroscopic anatomy of a meteor trail cross section with the European Southern Observatory Very Large Telescope

Abstract— A meteor spectrum was recorded serendipitously at the European Southern Obrervatory (ESO) Very Large Telescope (VLT) during a long exposure in long‐slit spectroscopic mode with FORS1. The ?8 magnitude fireball crossed the narrow 1Î × 7î slit during the observation of a high z supernova in normal service mode operation on May 12, 2002. The spectrum covered the range of 637–1050 nm, where the meteor's air plasma emissions from N₂, N, and O dominate. Carbon atom emission was not detected in the relatively unexplored wavelength range above 900 nm, but the observed upper limit was only 3 sigma less than expected from the dissociation of atmospheric CO₂. The meteor trail was resolved along the slit, and the emission had a Gaussian distribution with a dimension of FWHM = 7.0 (±0.4) * sin(α) * H (km)/90 m, where α is the unknown angle between the orientation of the meteor path and slit and H the assumed altitude of the meteor in km. To our knowledge, this is the first observation of a spatially resolved spectrum across a meteor trail. Unlike model predictions, the plasma excitation temperature varied only from about 4,300 to 4,365 K across the trail, based on the ratio of atomic and molecular nitrogen emissions. Unfortunately, we conclude that this was because the meteor at 100 km altitude was out of focus.     

An evaluation of the genesis and suitability of groundwater for irrigation in the Volta Region,Ghana

Stable isotope data and concentrations of the major cations and anions of groundwater from the northern part of the Volta Region, Ghana, were used to determine the source of recharge and the suitability of groundwater in the area for irrigation. This study finds that the delta deuterium (δD) and delta Oxygen-18 (δ¹⁸O) data from the area fall along the global meteoric water line (GMWL). An equation of regression derived for the relationship between δD and δ¹⁸O bears very close semblance to the equation which describes the GMWL. On the basis of this, groundwater in the study area is probably meteoric and fresh. The apparently low salinities and sodicities of the groundwater seem to support this interpretation. The suitability of groundwater for domestic and irrigation purposes is related to its source, which determines its constitution. A plot of the sodium adsorption ratio (SAR) and electrical conductivity (EC) data on a semilog axis, suggests that groundwater serves good irrigation quality in the area. Sixty percent (60%), 20% and 20% of the 67 data points used in this study fall within the medium salinity–low sodicity (C2–S1), low salinity–low sodicity (C1–S1) and high salinity–low sodicity (C3–S1) fields, which ascribe good irrigation quality to groundwater from this area. Salinities range from 28.1 to 1,956 μS/cm, whilst SAR values fall within the range 0–3. Extremely low sodicity waters of this kind, with salinities lower than 600 μS/cm, have the tendency to affect the dispersive properties of irrigation soils when used for irrigation. About 50% of the groundwater in the study area fall within this category and need prior treatment before usage.     

Glacier mass balance of tropical Zongo glacier, Bolivia, comparing hydrological and glaciological methods

A glaciological program has been undertaken since 1991 on Zongo glacier in Bolivia (6000–4850 m asl, 2.4 km², 16°S). This program involves mass balance measurements, hydrological studies and energy balance investigations. On outer-tropical glaciers, melting and snow accumulation are both maximum in the wet season (austral summer), whereas the dry season (winter) is a period of low ablation. Errors on each term of the glaciological (stakes, snow-pits and integration method of the measurements) and hydrological (precipitation, discharge and runoff coefficient of free ice areas) methods are investigated to estimate the overall accuracy of the mass balance measurements. The hydrological budget is less than the glaciological one (mean difference: 60 cm w.e. per year), but both methods reproduce similar inter-annual variations. Errors in assessment of evaporation or water storage inside the glacier cannot explain the discrepancy. Errors using the glaciological method are large (around ± 40 cm w.e. per year), but no bias can explain the departure from the hydrological balance. Errors on discharge measurements are small and the uncertainty on the runoff coefficient has a minor effect on the mass balance. We concluded that hydrological budgets are too low due to the catch deficiency of rain gauges and absence of precipitation measurements at high altitudes, emphasizing the difficulty to assess snowfall distribution in high mountainous basins.     

Climatic and structural controls on Late-glacial and Holocene rockfall occurrence in high-elevated rock walls of the Mont Blanc massif (Western Alps)

In the Mont Blanc massif (European Western Alps), rockfalls are one of the main natural hazards for alpinists and infrastructure. Rockfall activity after the Little Ice Age is well documented. An increase in frequency during the last three decades is related to permafrost degradation caused by rising air temperatures. In order to understand whether climate exerts a long-term control on rockfall occurrence, a selection of paleo-rockfall scars was dated in the Glacier du Géant basin [>3200 m above sea level (a.s.l.)] using terrestrial cosmogenic nuclides. Rockfall occurrence was compared to different climatic and glacial proxies. This study presents 55 new samples (including replicates) and 25 previously-published ages from nine sampling sites. In total, 62 dated rockfall events display ages ranging from 0.03 ± 0.02 ka to 88.40 ± 7.60 ka. Holocene ages and their uncertainties were used to perform a Kernel density function into a continuous dataset displaying rockfall probability per 100 years. Results highlight four Holocene periods of enhanced rockfall occurrence: (i) c. 7–5.7 ka, related to the Holocene Warm Periods; (ii) c. 4.5–4 ka, related to the Sub-boreal Warm Period; (iii) c. 2.3–1.6 ka, related to the Roman Warm Period; and (iv) c. 0.9–0.3 ka, related to the Medieval Warm Period and beginning of the Little Ice Age. Laser and photogrammetric three-dimensional (3D) models of the rock walls were produced to reconstruct the detached volumes from the best-preserved rockfall scars (≤0.91 ± 0.12 ka). A structural study was carried out at the scale of the Glacier du Géant basin using aerial photographs, and at the scale of four selected rock walls using the 3D models. Two main vertical and one horizontal fracture sets were identified. They correspond respectively to alpine shear zones and veins opened-up during long-term exhumation of the Mont Blanc massif. Our study confirms that climate primarily controls rockfall occurrence, and that structural settings, coincident at both the massif and the rock wall scales, control the rock-wall shapes as well as the geometry and volume of the rockfall events. © 2020 John Wiley & Sons, Ltd.