Lake Neor reveals how mountain vegetation responded to 7000 years of hydroclimate variability in northwestern Iran

Palynological and geochemical analyses provide valuable information about modern and past climatic regimes and vegetation. The impact of climate and humans on past vegetation in the semi-arid areas of northwestern Iran has received increased interest in the wake of warming temperatures in the Middle East. Palynological and down-core XRF elemental abundances from a peat core from Lake Neor enabled a reconstruction of vegetational changes of the past 7000 years over the highlands of northwestern Iran. Periods of increased arboreal pollen (AP) types and high (Artemisia + Poaceae)/Chenopodiaceae ratios along with low titanium abundances, high percentages of total organic carbon, more negative δD values, and higher carbon accumulation rates suggest a relatively wet climate. These conditions have persisted during the periods 6700–6200, 5200–4450 and 3200–2200 cal a bp. The overall low AP values, substantial rise of Chenopodiaceae, high Ti abundances and low values of palaeo-redox proxies, are all evidences of a drier climate, as has been reconstructed for the periods 6200–5200 and 4030–3150 cal a bp and the last 2200 years. An important feature of the last centuries is the increase of anthropogenic and pastoral indicator pollen types. Our results may provide basic data to predict future trends in vegetation dynamics under future climate change in western Asia.     

Mineralogy and geochemical behaviour during weathering of greenstone belt under tropical dry conditions in the extreme North Cameroon (Central Africa)

Mineralogy, major, trace and rare earth elements of a weathering profile developed on tertiary greenstone belt in the extreme North Cameroon are reported. The aim of which was to investigate mineralogical evolution and element mobilization and redistribution during weathering under dry tropical climate. The weathering profile consists of four main horizons: (1) a spheroidal weathering zone constituted by a corestone–shell complex, (2) a C horizon, (3) a Bw horizon and an Ah horizon. The results indicate that nontronite, a Fe-rich smectite, is the exclusive clay mineral formed in the exfoliated shells and the C horizon. It is associated with kaolinite in the upper horizons. The coexistence of these two clay minerals induced a decrease of CEC and pH which becomes neutral. The weathering index (WI) values reveal that weathering becomes more and more intensive from the corestone up to Bw horizon, which is the most weathered horizon in the weathering profile. Mass balance calculations, using Th as immobile element, indicate that Ti is quite mobile and that Al and Fe are relatively enriched at the bottom and strongly leached at the top of the profile. Alkalis and alkaline earth elements are strong leached through out the profile, except Ca which displays similar trend as Al and Fe. The same goes for LILE (Cs, Sr), TTE (Cr, Co, Ni) and HSFE (Y, Nb, Hf). In opposite, REE are depleted at the bottom and enriched in the upper horizons, with more enrichment for LREE than for HREE. It appears that weathering of greenstone belt causes a fractionation of HREE and induces a concentration of LREEs. Ce and Eu anomalies display opposite behaviour.     

Groundwater potential assessment in a sedimentary terrain,southwestern Nigeria

Geoelectrical resistivity techniques are increasingly being applied in addressing a wide range of hydrological, environmental, and geotechnical problems. This is due to their effectiveness in near-surface characterization. In the present study, a suite of vertical electrical soundings (VESs) was integrated with 2D geoelectrical resistivity and time-domain induced polarization (IP) imaging to characterize the near-surface and delineate the underlying aquifer in a sedimentary terrain. The geophysical survey was conducted as part of preliminary studies to evaluate the potential of groundwater resource in Iyana-Iyesi and Canaan Land area of Ota, southwestern Nigeria. A high-yield confined sandy aquifer overlain by a low-yield aquitard was delineated; overlying the aquitard is a very resistive and thick layer that is predominantly composed of kaolinitic swelling clay intercalated with phosphate mineral.     

Factors Affecting Macrobenthic Fauna in a Tropical Hypersaline Coastal Lagoon in Ghana,West Africa

The macrobenthic fauna in the large, hypersaline, shallow Keta lagoon in Ghana was sampled at 20 stations in the wet (September 2002) and dry seasons (March 2003) to elucidate the effects of abiotic factors on community patterns. The macrobenthic fauna was low in density and species diversity and numerically dominated by bivalves and capitellid polychaetes. These organisms appear able to withstand physical disturbance (when lagoon water levels become extremely low) and osmotic stress (when salinities are extremely high) and tend to redistribute along environmental gradients. Parallel seasonal differences in several environmental variables and the macrobenthic fauna indicate a highly dynamic system. Species richness and diversity were higher in the wet season than the dry season. Salinity, percent clay, pH, and turbidity in that order were the major significant variables structuring the macrobenthic faunal assemblage in Keta lagoon. The strong effect of seasonal salinity changes on macrobenthic faunal assemblages may have trophic consequences for higher organisms of commercial importance, such as fishes and shorebirds, in the Keta lagoon.     

Characteristics of electron and high-energy proton flares

High-energy proton (E _p > 55 MeV) and electron (E _e > 50 keV) events were observed by University of Iowa experiments on the satellites Explorer 33 and 35. The solar X-ray (2–12 Å) flares associated with the energetic proton events were found to have in general higher peak fluxes, considerably longer decay times (t) and smaller rise to decay time ratios (r) than the X-ray flares associated with the electron events. The most common decay times and rise to decay time ratios are: 80 t 100 min, 0.1 r 0.2 for the proton X-ray flares and t 20 min, 0.3 r 0.7 for the electron ones.     

From whom Bells tolls: Reclassifying Bells among CR chondrites and implications for the formation conditions of CR parent bodies

The ungrouped carbonaceous chondrite (CC) Bells has long been considered petrographically similar to CM chondrites based on its matrix abundance and degree of aqueous alteration, but also shows significant isotopic affinities to CR chondrites. Its taxonomic status is thus important for clarifying the relationship of the CRHB (formerly “CR”) clan with other CCs. In this study, we measured the oxygen isotopic compositions of olivines in type I chondrules and isolated olivine grains in Bells. Bells olivines mostly have ∆¹⁷O > −4‰, similar to CR chondrites but unlike other CCs that are rich in refractory inclusions, in which chondrules are generally richer in ¹⁶O. Therefore, Bells is a CR chondrite (albeit an anomalous one), most similar to the rare, matrix-rich CRs like Al Rais. These chondrites (i) may not necessarily derive from the same primary parent body as mainstream CRs, (ii) bear witness to significant variations of the matrix/chondrule ratio within the CRHB clan, and (iii) may be a good analog for samples retrieved by the space mission OSIRIS-REx.     

Spatially-Weighted Factor Analysis for Extraction of Source-Oriented Mineralization Feature in 3D Coordinates of Surface Geochemical Signal

Natural Resources Research - This contribution proposes a spatially weighted factor analysis (SWFA) to recognize effectively the underlying mineralization-related feature(s) in geochemical signals....     

Mercury speciation in surface and deep waters of the Mediterranean Sea

Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg⁰, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.     

Preliminary spectral characterization of snow in a high altitude tropical glacier and potential effects of impurities in snow on albedo of tropical glaciers

This paper presents some preliminary measurements of snow spectral reflectance on the tropical Bolivian Zongo glacier. Measurements show a correct agreement with theoretical spectral albedo of pure snow in the near infrared region, but lower values in the visible region (by 10–20%) probably due to aerosols contained in snow. Impurity contents ranged from 10 to 100 ppmw in one‐week‐old snow collected from the Zongo glacier, but measurements are scarce. Large amounts of snowfall partly compensate the proximity of dust sources in mid‐latitude glaciers, whereas on outer‐tropical glaciers precipitations are not abundant and are very seasonal, and sources of aerosols are proximate. Copyright © 2007 John Wiley & Sons, Ltd.     

Latitudinal variations of CO and OCS in the lower atmosphere of Venus from near-infrared nightside spectro-imaging

Spectro-imaging of Venus' nightside in the 2.3-μm window provides a powerful means of probing the lower atmosphere in the 25-40 km altitude range. We present observations recorded at the NASA/IRTF in February 2003 and August 2004, using the SpeX spectro-imager in the 2.1-2.5-μm region. Abundances of CO and OCS have been derived as a function of latitude for different longitudes. The CO abundance increases by about 15% between the equatorial region and higher latitudes (±40°). No longitudinal or temporal variations are observed. The OCS abundance shows the opposite variation in observational sets with sufficient S/N. These variations and anticorrelation are consistent with upwelling motions in the equatorial region and downwelling at higher latitudes.