Application of a regionalized Clark IUH model with limited hydrologic data availability

To aid prediction of the flow hydrograph in a basin with limited data, a practical approach to determining a regionalized Clark instantaneous unit hydrograph (IUH) model is presented. The proposed model is described in terms of the synthetic time–area concentration curve, the concentration time, and a special regional similarity value that is valid in the whole basin. The latter was estimated from a Monte Carlo testing procedure based on the normal probability distribution of transformed regional similarity values composed of the time of concentration and the storage coefficient in gauged basins. The time–area concentration curve and the concentration time were calculated from a rational equation as in conventional methods. The method of transformation adopted was the Box–Cox power transformation, which is known to make non‐normal values resemble normal data. By introducing the regional similarity value into a Clark IUH, a statistically best estimate of IUH for given data conditions and its quantified degree of uncertainty were realized. The Wi River basin in Korea was used to test the applicability of the regionalized Clark IUH. The performance of the suggested methodology was evaluated by assuming an ungauged sub‐basin at the site. The results showed that the IUH model developed in this work was an effective tool, predicting a reliable hydrograph within the study area even though only limited data were available. Copyright © 2008 John Wiley & Sons, Ltd.     

Reconstruction of the trajectory of the Huygens probe using the Huygens Atmospheric Structure Instrument (HASI)

The Huygens probe returned scientific measurements from the atmosphere and surface of Titan on 14 January 2005. Knowledge of the trajectory of Huygens is necessary for scientific analysis of those measurements. We use measurements from the Huygens Atmospheric Structure Instrument (HASI) to reconstruct the trajectory of Huygens during its mission. The HASI Accelerometer subsystem measured the axial acceleration of the probe with errors of 3E−6 m s⁻², the most accurate measurements ever made by an atmospheric structure instrument on another planetary body. The atmosphere was detected at an altitude of 1498 km. Measurements of the normal acceleration of the probe, which are important for determining the probe's attitude during hypersonic entry, were significantly less accurate and limited by transverse sensitivity of the piezo sensors. Peak acceleration of 121.2 m s⁻² occurred at 234.9 km altitude. The parachute deployment sequence started at 157.1 km and a speed of 342.1 m s⁻¹. Direct measurements of pressure and temperature began shortly afterwards. The measured accelerations and equations of motion have been used to reconstruct the trajectory prior to parachute deployment. Measured pressures and temperatures, together with the equation of hydrostatic equilibrium and the equation of state, have been used to reconstruct the trajectory after parachute deployment. Uncertainties in the entry state of Huygens at the top of the atmosphere are significant, but can be reduced by requiring that the trajectory and atmospheric properties be continuous at parachute deployment.     

Solar Irradiance Models and Measurements: A Comparison in the 220–240?nm wavelength band

Solar irradiance models that assume solar irradiance variations to be due to changes in the solar surface magnetic flux have been successfully used to reconstruct total solar irradiance on rotational as well as cyclical and secular time scales. Modelling spectral solar irradiance is not yet as advanced, and also suffers from a lack of comparison data, in particular on solar cycle time scales. Here, we compare solar irradiance in the 220–240?nm band as modelled with SATIRE-S and measured by different instruments on the UARS and SORCE satellites. We find good agreement between the model and measurements on rotational time scales. The long-term trends, however, show significant differences. Both SORCE instruments, in particular, show a much steeper gradient over the decaying part of cycle 23 than the modelled irradiance or that measured by UARS/SUSIM.     

A Sr,Nd, Hf,and Pb isotope perspective on the genesis and long-term evolution of alkaline magmas from Erebus volcano,Antarctica

We report new Nd, Hf, Sr, and high-precision Pb isotopic data for 44 lava and tephra samples from Erebus volcano. The samples cover the entire compositional range from basanite to phonolite and trachyte, and represent all three phases of the volcanic evolution from 1.3 Ma to the present. Isotopic analyses of 7 samples from Mt. Morning and the Dry Valley Drilling Project (DVDP) are given for comparison. The Erebus volcano samples have radiogenic ²⁰⁶Pb/²⁰⁴Pb, unradiogenic ⁸⁷Sr/⁸⁶Sr, and intermediate ¹⁴³Nd/¹⁴⁴Nd and ¹⁷⁶Hf/¹⁷⁷Hf, and lie along a mixing trajectory between the two end-member mantle components DMM and HIMU. The Erebus time series data show a marked distinction between the early-phase basanites and phonotephrites, whose Nd, Hf, Sr, and Pb isotope compositions are variable (particularly Pb), and the current ‘phase-three’ evolved phonolitic lavas and bombs, whose Nd, Hf, Sr, and Pb isotope compositions are essentially invariant. Magma mixing is inferred to play a fundamental role in establishing the isotopic and compositional uniformity in the evolved phase-three phonolites. In-situ analyses of Pb isotopes in melt inclusions hosted in an anorthoclase crystal from a 1984 Erebus phonolite bomb and in an olivine from a DVDP basanite are uniform and identical to the host lavas within analytical uncertainties. We suggest that, in both cases, the magma was well mixed at the time melt inclusions were incorporated into the different mineral phases.     

A trigger-tube tracer dilution technique for determining Darcy and apparent velocities of groundwater in dug wells: A case study on phreatic aquiferous formation in Bamenda-Cameroon

The need to understand flow within aquiferous formations for a complete evaluation of groundwater resource and quality control prompts the determination of groundwater velocities through well dilution technique. Well dilution techniques utilize tracer solutions after establishing an initial homogenous condition to monitor the flow rate of ambient groundwater into the wells. Application of dilution techniques in wells makes it feasible to determine the velocities of groundwater in the aquiferous formation surrounding the well. In this study, a simple trigger-tube tracer dilution technique was employed to determine the Darcy and apparent velocities of groundwater in the phreatic aquiferous formation in Bamenda, Cameroon. Eighteen(18) hand dug-wells at different locations within Bamenda were sampled by utilizing sodium chloride(NaCl) as the conservative tracer. Field estimates of groundwater flow velocities in the phreatic aquiferous formation in Bamenda reveal Darcy's groundwater velocity in the range of 0.39 m/d at Nacho to 130.64 m/d at Foncha Street and apparent velocity in the range of 0.78 m/d at Nacho to 277.86 m/d at Foncha Street. The immense variations in the velocities of groundwater indicate that the groundwater flows at different rates and directions within the aquiferous formation in Bamenda, possibly due to variations in their hydraulic conductivities. Moreover, the spatial variations in the formation types, facies changes, thickness, and layering of the aquiferous formation also contribute to the variation of velocities. Areas with low groundwater velocities are associated with a lower contaminant transport rate when compared to areas with high groundwater velocities. The findings of this study are important for assessing the rates of pollutant movement in the subsurface, as well as the effectiveness and efficacy of the trigger-tube technique in evaluating the hydraulic properties of aquiferous formations.     

Modeling vertical stratification of CO2 injected into a deep layered aquifer

The vertical stratification of carbon dioxide (CO₂) injected into a deep layered aquifer made up of high-permeability and low-permeability layers, such as Utsira aquifer at Sleipner site in Norway, is investigated with a Buckley–Leverett equation including gravity effects. In a first step, we study both by theory and simulation the application of this equation to the vertical migration of a light phase (CO₂), in a denser phase (water), in 1D vertical columns filled with different types of porous media: homogeneous, piecewise homogeneous, layered periodic and finally heterogeneous. For each case, we solve the associated Riemann problems and propose semi-analytical solutions describing the spatial and temporal evolution of the light phase saturation. These solutions agree well with simulation results. We show that the flux continuity condition at interfaces between high-permeability and low-permeability layers leads to CO₂ saturation discontinuities at these interfaces and, in particular, to a saturation increase beneath low-permeability layers. In a second step, we analyze the vertical migration of a CO₂ plume injected into a 2D layered aquifer. We show that the CO₂ vertical stratification under each low-permeability layer is induced, as in 1D columns, by the flux continuity condition at interfaces. As the injection takes place at the bottom of the aquifer the velocity and the flux function decrease with elevation and this phenomenon is proposed to explain the stratification under each mudstone layer as observed at Sleipner site.     

Long-term monitoring of a large deep-seated landslide (La Clapiere,South-East French Alps): initial study

The large-scale deformation of high mountain slopes finds its origin in many phenomena (inherent parameters, external stresses) with very different time constants (instantaneous to geological scale). Gravitational effect, tectonic forces and water infiltration are generally the principal causes of slope instability. However, it can be very difficult to distinguish which cause is dominant and which are their respective effects. To gain a better understanding of the complex processes taking place during the evolution of an unstable slope and separate the causes responsible of the landslide dynamic, an observational study based on geodetic, meteorological, seismological and electrical data has been performed on the La Clapière rockslide (Southern French Alps). This deep-seated landslide (DSL) is known for many years as one of the largest and fastest rock slide in Europe (60 million m³ of highly weathered metamorphic material, moving at 1 to 3 m year^?1). The set-up of the “Observatoire Multidisciplinaire des Instabilités de Versants” (OMIV, http://omiv.osug.fr) in 2011 has allowed the production and availability of an important and original data set over several years of accurate monitoring. Thus, for the first time, the long-term study of geodetic data permitted us to highlight acceleration phases in the general movement of the landslide that affect its dynamic. These modifications are associated with variations of the velocity by a factor 3 to 6. The characterization of the origin of these variations was possible due to the comparison with meteorological, electrical and seismological data. Based on these various signals, we were able to establish correlations and contributions of meteorological water infiltration in the dynamic evolution of the La Clapière slope. We determine several response times to the meteorological stress for seismic endogenous events (mainly rockfalls), the resistivity of the ground (quasi-instantaneous) and the kinematics of the slope (from 2 weeks to 2.5 months). Moreover, our results strongly suggest the existence of rainfall threshold of 3.5?±?1 mm day^?1 from which the number of seismic endogenous events is highly increased.     

Hydrochemical characteristics of groundwater and surface water for domestic and irrigation purposes in Vea catchment,Northern Ghana

The Vea catchment, mainly underlain by crystalline basement rocks, is located in Northern Ghana. Hydrogeochemical studies were carried out in this area with the objective of identifying the geochemical processes influencing water quality and suitability of surface and groundwater for agricultural and domestic uses. Sixty-one groundwater and four surface water samples were collected from boreholes, dams and rivers and analysed for Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ^?, Cl^?, and SO₄ ^2?, Fe_tot, PO₄ ^3?, Mn_tot, NH₄ ⁺, NO₃ ^?, NO₂ ^?. In addition, pH, total dissolved solids, electrical conductivity, total hardness, turbidity, colour, salinity and dissolved oxygen were analysed. Chloro-alkaline indices 1 and 2, and characterization of weathering processes suggest that the chemistry of groundwater is dominated by the interaction between water and rocks. Cation exchange and silicate weathering are the dominant processes controlling the chemical composition of the groundwater in the area studied. Mineral saturation indices indicate the presence of at least three groups of groundwater in the Vea catchment with respect to residence time. The meteoric genesis index suggests that 86% of the water samples belong to the shallow meteoric water percolation type. The findings further suggest that the groundwater and surface water in the basin studied are mainly Ca–Mg–HCO₃ water type, regardless of the geology. Compared to the water quality guidelines of WHO, the study results on sodium absorption ratio, sodium percentage, magnesium hazard, permeability index and residual sodium carbonate indicate that groundwater and surface water in the Vea catchment are generally suitable for drinking and irrigation purposes.     

Back diffusion of chlorinated solvent contaminants from a natural aquitard to a remediated aquifer under well-controlled field conditions: predictions and measurements

Vertical profiles of tetrachloroethene (or perchloroethylene, PCE) and trichloroethene (TCE) were used to validate a diffusion process in a natural aquitard at Dover Air Force Base, Delaware. PCE and TCE distributions in the aquitard underlying an unconfined aquifer were sampled from core tubes obtained at four times over the course of a 35-month field investigation within "test cells" that were isolated from the surrounding ground water by means of grout-sealed steel sheetpile barriers (Mackay et al. 2000). For the final 23 months of this period, boundary conditions at the aquifer/aquitard interface were such that a "back diffusion" of contaminants from the aquitard was induced. Modeling predictions of concentration changes were made on the basis of the earliest coring results and an assumption of sorption-retarded diffusion and using laboratory information about sorption and diffusion characteristics of the media. The predictive modeling was complicated by the fact that "initial" and "final" PCE and TCE distributions in the aquitard were measured at different (albeit proximate) coring locations, such that results reflect spatial variations in aquitard characteristics. This problem was solved by means of an inverse interpretation that involved spatial "translation" of observed profiles on the basis of the laboratory characterizations and assuming a common aquifer-side contaminant history. Predictions indicated substantial change in PCE and TCE concentrations within the upper aquitard (near the aquifer/aquitard interface) and the development of a back-diffusion profile up into the aquifer. Modeling also predicted comparatively minor profile changes in the deeper aquitard, and especially in the deep layer where sorption was strongest. All of these predicted effects were observed in the coring results. Although not exact, the agreement between predictions and observations was sufficiently good to justify the basic tenets of the diffusion model and to support a conclusion that major processes of advection and/or transformation were unimportant within the 35-month time scale of this work.