Role of electrochemical reactions in pressure solution

Using a Surface Forces Apparatus we have measured changes in the electrical potential difference between quartz and mica surfaces that correlate with the changing quartz dissolution rate when surfaces are pressed together at relatively low pressures (2-3 atm) in aqueous electrolyte solutions of 30 mM CaCl₂ at 25 °C. No detectable dissolution or voltage potential difference is measured in symmetrical systems (e.g. mica-mica or quartz-quartz) or between dry surfaces subjected to similar pressures, indicating that the dissolution can not be attributed to a simple pressure effect, slow aging (creep), or plastic deformation of the quartz surface. In quartz-mica systems brought together under pressure or to close proximity in electrolyte solution, the onset of quartz dissolution is marked by a sudden, rapid decrease in the quartz thickness at initial rates in the range from 1 to 4 nm/min, which after several hours settles into a constant rate of approximately 0.01 nm/min (∼5 μm/yr). Concomitantly, the potential drops to a constant value once the dissolution rate has stabilized. The decrease in the decay rate is interpreted as being due to saturation of the confined aqueous film and/or to the buildup of a Stern layer on the quartz surface, and the constant rate as being due to the steady-state chemical dissolution and diffusion of the dissolving silica into the surrounding reservoir. The dissolution is ‘non-uniform’: the surfaces become rough as dissolution proceeds, with the appearance of pits in a manner analogous to corrosion. On occasions, the process of rapid dissolution followed by a gradual transition to steady dissolution repeats itself, suggesting that the pit structure and Stern layer are fragile and subject to collapse and/or expulsion from the gap. Preliminary experiments on the dissolution of multi-faceted milled quartz particles (∼1.0 μm diameter) compressed between two muscovite surfaces suggest an asymmetry in the dissolution rates at different crystallographic planes. The origin of the electrical potential is interpreted as arising from the overlapping of the electric double-layers of two dissimilar surfaces when they are forced into close proximity. This electrical potential difference, for as yet unknown reasons, appears to be the driving force for the dissolution, rather than pressure.     

The Fernow Experimental Forest,West Virginia,USA: Insights,datasets, and opportunities

Long-term experimental watershed studies have significantly influenced our global understanding of hydrological processes. The discovery and characterization of how stream water quantity and quality respond to a changing environment (e.g. land-use change, acidic deposition) has only been possible due to the establishment of catchments devoted to long-term study. One such catchment is the Fernow Experimental Forest (FEF) located in the headwaters of the Appalachian Mountains in West Virginia, a region that provides essential freshwater ecosystem services to eastern and mid-western United States communities. Established in 1934, the FEF is among the earliest experimental watershed studies in the Eastern United States that continues to address emergent challenges to forest ecosystems, including climate change and other threats to forest health. This data note describes available data and presents some findings from more than 50 years of hydrologic research at the FEF. During the first few decades, research at the FEF focused on the relationship between forest management and hydrological processes—especially those related to the overall water balance. Later, research included the examination of interactions between hydrology and soil erosion, biogeochemistry, N-saturation, and acid deposition. Hydro-climatologic and water quality datasets from long-term measurements and data from short-duration studies are publicly available to provide new insights and foster collaborations that will continue to advance our understanding of hydrology in forested headwater catchments. As a result of its rich history of research and abundance of long-term data, the FEF is positioned to continue to advance understanding of forest ecosystems in a time of unprecedented change.     

Climate change influences on pollinator,forest, and farm interactions across a climate gradient

Improved cookstoves have been identified in Mexico as a key opportunity to advance sustainable local development priorities in disadvantaged regions while mitigating climate change. This paper reviews the Patsari Cookstove Project initiated in 2003 by an NGO, Interdisciplinary Group on Appropriate Rural Technology (GIRA). The project applied an interdisciplinary and participative user-centered approach to disseminate improved cookstoves in rural Mexico, with a special focus on indigenous and poor rural communities. To date, GIRA and the Patsari Network have disseminated thousands of stoves using a “training to trainers” model. Benefits from the project include tangible improvements in users’ health, as well as savings in time and money expended on fuelwood procurement and use. The project has also documented substantive environmental benefits from significant mitigation of greenhouse gas (GHG) emissions associated with traditional open fires. To sustain scaling up efforts over the long-term, two networks have been created: The Patsari Network, which includes several organizations promoting Patsari stoves for household users, and the Tsiri Network, which supports local food security and the empowerment of indigenous women through the promotion of institutional cookstoves. Through appropriately designed and implemented local interventions, the project demonstrates that the goals of advancing sustainable local development in rural areas and climate change mitigation may not be contradictory, and may in fact reinforce one another.     

Optimal Processing of Marine High-Resolution Seismic Reflection (Chirp) Data

Chirp frequency-modulated (FM) systems offer deterministic, repeatable source-signatures for high-resolution, normal incidence marine seismic reflection data acquisition. An optimal processing sequence for uncorrelated Chirp data is presented to demonstrate the applicability of some conventional seismic reflection algorithms to high-resolution data sets, and to emphasise the importance of a known source-signature. An improvement of greater than 60dB in the signal- to-noise ratio is realised from correlating the FM reflection data with the transmitted pulse. Interpretability of ringy deconvolved data is enhanced by the calculation of instantaneous amplitudes. The signal-to-noise ratio and lateral reflector continuity are both improved by the application of predictive filters whose effectiveness are aided by the repeatability of the Chirp source.     

Larval life span of the echinoid evechinus chloroticus (val.)

Newly metamorphosed Evechinus chloroticus (Val.) were observed in three larval cultures 36, 30, and 28 days after fertilisation, indicating that the free swimming larval life may last about 1 month.     

从2014年4月1日智利地震认识前震

<正>最近一些大地震如2014年4月1日智利地震之前的地震活动分析结果揭示,一些大地震是有可能被预测的。大地震之前是否有可测量的、明显的前兆异常来警示我们?一直以来,前震被认为是地震预测最有希望的指标。至少一半以上的大地震有前震,但这些前震很难从非前兆地震活动中区分出来。2014年4月1日智利地震及近期其他大地震的前震活动表明,大地震前可能存在可观测的前兆异常。地震相互作用的统计模型表明,当区域     

Closed Circuit Television (CCTV) Earthquake Behaviour Coding Methodology: analysis of Christchurch Public Hospital video data from the 22 February Christchurch earthquake event

Earthquake epidemiological research indicates that the behavioural response influences the nature and severity of injuries sustained. However, there is no observational evidence of the actions individuals engage in during and immediately following earthquake shaking, and the context in which earthquake injuries and deaths are caused. Closed Circuit Television Earthquake Behaviour Coding Methodology has been developed as a tool to classify human behaviour during and immediately following earthquake shaking using real event video data. The coding methodology was applied to security video data captured during the 22 February 2011 M_w6.3 ‘Christchurch’ earthquake event from the Christchurch Public Hospital which experienced shaking intensity of MM9 lasting approximately 12–15 s. We applied this coding methodology to determine: demography, trans-event behavioural responses, post-event behavioural responses, influence of social context on behaviour, and influence of behaviour on injuries. A total of 213 individuals from 31 different camera views were analysed. Sixty-six per cent of the individuals were adult-aged females. The primary trans-event responses were to hold (26%) onto furniture, walls, and/or other people close to them and to look around (30%). No individuals were observed to perform all ‘Drop, Cover, Hold’ actions, the recommended action during strong earthquake shaking in New Zealand. Post-event behaviour included: running, walking, providing assistance, moving towards others, visual communication, and some individuals gave instructions. Social contextual behaviour varied depending on the role of the adult. There were no serious injuries linked to behaviour. The results of this initial study indicate the coding methodology can record the distribution of and variation in human behaviours. Therefore, objective observation of earthquake video data can provide a useful quantitative measure of human behaviour. Significantly, the process will enable researchers to look more closely at behaviours, as well as the social and physical contexts associated with injury risk during and immediately following earthquake shaking.     

Analytical study on vulnerability functions for casualty estimation in the collapse of adobe buildings induced by earthquake

Collapse of adobe buildings during an earthquakes with various earthquake intensities is analyzed using the 3-dimensional distinct element method code developed by the first author. Firstly, we evaluate structural damage with damage index, interior-space damage with w score, and human casualties in the collapsing buildings with three casualty criteria. Secondly, we investigate relationships between the earthquake intensity, the structural damage, the interior-space damage, and the casualties. It is found that the casualties have stronger correlation with the interior-space damage than the structural damage, and three vulnerability functions, namely, structural, interior-space and casualty vulnerability functions, are proposed. Effects of reinforcing methods on these functions are also examined. Finally, a series of analytical procedures to develop vulnerability functions and to estimate casualties using the functions are described.