Geochemistry and mineralogy of Platinum-group elements in the Ransko gabbro–peridotite massif,Bohemian Massif (Czech Republic)

The Ransko gabbro-peridotite massif in Eastern Bohemia is a strongly differentiated intrusive complex of Lower Cambrian age. The complex hosts low grade Ni-Cu ores mainly developed close to the contact of olivine-rich rocks with gabbros, in troctolites and, to a much lesser extent, in both pyroxene and olivine gabbros and plagioclase-rich peridotites. The ore zone is characterized by strong serpentinization and uralitization. The total Ni + Cu locally reaches up to 4 wt%. Anomalous concentrations of platinum-group elements (PGE's) (maximum 532 ppb Pd, 182 ppb Pt, 53 ppb Rh, 15 ppb Ru, 41 ppb Ir) were detected in samples of Cu-Ni and Ni-Cu ores (maximum 2.63 wt% Ni and 2.31 wt% Cu) from the Jezírka orebody. The main ore paragenesis includes pyrrhotite, pentlandite, chalcopyrite, cubanite, pyrite, magnetite, mackinawite, valleriite, ilmenite and sphalerite. During this work, michenerite, froodite, sperrylite, gold, native bismuth, altaite, tsumoite, hessite, an unnamed Bi-Ni telluride, cobaltite-gersdorffite and galena were newly identified. The host rocks originated through partial melting of a slightly depleted mantle source with noble metals scavenged from this primitive magma prior to the development of these rocks.     

Isotopic age and metamorphic history of the banded gneiss at Danmarkshavn,East Greenland

Along the northern part of the East Greenland coast the Caledonian structures are superimposed on an older fold system called the Carolinidian. Traces of this Carolinidian belt are preserved in a few isolated fragments within the Caledonian fold belt. According to Haller (1970) one of these fragments exhibiting the typical Carolinidian NNW to NW-trending infrastructural folds is the peninsula of Germania Land which is accessible near the Danish weather station Danmarkshavn. The rock sampled there is a banded gneiss of granodioritic composition with steeply inclined, NNW-trending layers. Isotopic age determinations yielded essentially two groups of ages: 1) 3,000±150 m.y. (zircon suite and Rb/Sr whole rock analyses of layers) and 2) 320–380 m.y. (Rb/Sr mineral isochrons, U-Th-Pb on sphene, K/Ar on hornblende and biotite). The egg-shaped zircons support a sedimentary origin of the banded gneiss and in conjunction with the Rb/Sr whole rock ages determine the age of formation of the banded gneiss (or its last high grade metamorphism) some 3,000 m.y. ago. No other Precambrian metamorphism or orogeny is recorded in the rock. The ages between 320–380 m.y. date a thermal event of lower amphibolite facies grade related to a late Caledonian spasm.The new isotopic data reveal the existence of very old rocks in the hinterland — away from the direction of thrusting—of the East Greenland Caledonian belt. With respect to the age of the Carolinidian fold system three geological interpretations are compatible with the results of this study:

Tertiary alkaline Roztoky Intrusive Complex, České středohoří Mts., Czech Republic: petrogenetic characteristics

The ?eské st?edoho?í Mts. is the dominant volcanic center of the Oh?e (Eger) rift zone. It hosts the Roztoky Intrusive Complex (RIC), which is made up of a caldera vent and intrusions of 33–28-Ma-old hypabyssal bodies of essexite–monzodiorite–sodalite syenite series accompanied by a radially oriented 30–25-Ma-old dike swarm comprising about 1,000 dikes. The hypabyssal rocks are mildly alkaline mostly foid-bearing types of mafic to intermediate compositions. The dike swarm consists of chemically mildly alkaline and rare strongly alkaline rocks (tinguaites). The geochemical signatures of the mildly alkaline hypabyssal and associated dike rocks of the RIC are consistent with HIMU mantle sources and contributions from lithospheric mantle. The compositional variations of essexite and monzodiorite can be best explained by fractional crystallization of parent magma without significant contributions of crustal material. On the other hand, the composition of monzosyenite, leuco-monzodiorite and sodalite syenite reflects fractional crystallization coupled with variable degrees of crustal assimilation. It is suggested that the parent magmas in the Oh?e rift were produced by an adiabatic decompression melting of ambient upper mantle in response to lithospheric extension associated with the Alpine Orogeny.     

Refractory Black Carbon Results and a Method Comparison between Solid-state Cutting and Continuous Melting Sampling of a West Antarctic Snow and Firn Core

This work presents the refractory black carbon(rBC)results of a snow and firn core drilled in West Antarctica(79°55'34.6"S,94°21'13.3"W)during the 2014?15 austral summer,collected by Brazilian researchers as part of the First Brazilian West Antarctic Ice Sheet Traverse.The core was drilled to a depth of 20 m,and we present the results of the first 8 m by comparing two subsampling methods—solid-state cutting and continuous melting—both with discrete sampling.The core was analyzed at the Department of Geological Sciences,Central Washington University(CWU),WA,USA,using a single particle soot photometer(SP2)coupled to a CETAC Marin-5 nebulizer.The continuous melting system was recently assembled at CWU and these are its first results.We also present experimental results regarding SP2 reproducibility,indicating that sample concentration has a greater influence than the analysis time on the reproducibility for low rBC concentrations,like those found in the Antarctic core.Dating was carried out using mainly the rBC variation and sulfur,sodium and strontium as secondary parameters,giving the core 17 years(1998?2014).The data show a well-defined seasonality of rBC concentrations for these first meters,with geometric mean summer/fall concentrations of 0.016μg L^?1 and geometric mean winter/spring concentrations of 0.063μg L^?1.The annual rBC concentration geometric mean was 0.029μg L^?1(the lowest of all rBC cores in Antarctica referenced in this work),while the annual rBC flux was 6.1μg m^?2 yr^?1(the lowest flux in West Antarctica records so far).     

Prediction of Resource Volumes at Untested Locations Using Simple Local Prediction Models

This paper shows how local spatial nonparametric prediction models can be applied to estimate volumes of recoverable gas resources at individual undrilled sites, at multiple sites on a regional scale, and to compute confidence bounds for regional volumes based on the distribution of those estimates. An approach that combines cross-validation, the jackknife, and bootstrap procedures is used to accomplish this task. Simulation experiments show that cross-validation can be applied beneficially to select an appropriate prediction model. The cross-validation procedure worked well for a wide range of different states of nature and levels of information. Jackknife procedures are used to compute individual prediction estimation errors at undrilled locations. The jackknife replicates also are used with a bootstrap resampling procedure to compute confidence bounds for the total volume. The method was applied to data (partitioned into a training set and target set) from the Devonian Antrim Shale continuous-type gas play in the Michigan Basin in Otsego County, Michigan. The analysis showed that the model estimate of total recoverable volumes at prediction sites is within 4 percent of the total observed volume. The model predictions also provide frequency distributions of the cell volumes at the production unit scale. Such distributions are the basis for subsequent economic analyses.

Empirical Methods for Detecting Regional Trends and Other Spatial Expressions in Antrim Shale Gas Productivity, with Implications for Improving Resource Projections Using Local Nonparametric Estimation Techniques

The primary objectives of this research were to (1) investigate empirical methods for establishing regional trends in unconventional gas resources as exhibited by historical production data and (2) determine whether or not incorporating additional knowledge of a regional trend in a suite of previously established local nonparametric resource prediction algorithms influences assessment results. Three different trend detection methods were applied to publicly available production data (well EUR aggregated to 80-acre cells) from the Devonian Antrim Shale gas play in the Michigan Basin. This effort led to the identification of a southeast–northwest trend in cell EUR values across the play that, in a very general sense, conforms to the primary fracture and structural orientations of the province. However, including this trend in the resource prediction algorithms did not lead to improved results. Further analysis indicated the existence of clustering among cell EUR values that likely dampens the contribution of the regional trend. The reason for the clustering, a somewhat unexpected result, is not completely understood, although the geological literature provides some possible explanations. With appropriate data, a better understanding of this clustering phenomenon may lead to important information about the factors and their interactions that control Antrim Shale gas production, which may, in turn, help establish a more general protocol for better estimating resources in this and other shale gas plays.     

Dangerous fogs on the territory of Georgia

The statistical structure of dangerous fogs with the visibility of less than 50 m is studied using the observation data of 50 meteorological stations in Georgia for the period of 1961–2006. The contribution of dangerous fogs to the total number of foggy days is estimated. The number of days with dangerous fogs and their duration in different regions of the country are determined and the empirical functions of their distribution, sizes of areas of their expansion, temperature regime, and peculiarities of annual variations are studied.     

5. Einige Beziehungen zwischen Intrusionstektonik und Lagerstättenverteilung

Ohne Zusammenfassung     

Cascading ocean basins: numerical simulations of the circulation and interbasin exchange in the Azov-Black-Marmara-Mediterranean Seas system

In this paper, we use the unstructured grid model SCHISM to simulate the thermohydrodynamics in a chain of baroclinic, interconnected basins. The model shows a good skill in simulating the horizontal circulation and vertical profiles of temperature, salinity, and currents. The magnitude and phases of the seasonal changes of circulation are consistent with earlier observations. Among the mesoscale and subbasin-scale circulation features that are realistically simulated are the anticyclonic coastal eddies, the Sebastopol and Batumi eddies, the Marmara Sea outflow around the southern coast of the Limnos Island, and the pathway of the cold water originating from the shelf. The superiority of the simulations compared to earlier numerical studies is demonstrated with the example of model capabilities to resolve the strait dynamics, gravity currents originating from the straits, high-salinity bottom layer on the shallow shelf, as well as the multiple intrusions from the Bosporus Strait down to 700 m depth. The warm temperature intrusions from the strait produce the warm water mass in the intermediate layers of the Black Sea. One novel result is that the seasonal intensification of circulation affects the interbasin exchange, thus allowing us to formulate the concept of circulation-controlled interbasin exchange. To the best of our knowledge, the present numerical simulations, for the first time, suggest that the sea level in the interior part of the Black Sea can be lower than the sea level in the Marmara Sea and even in some parts of the Aegean Sea. The comparison with observations shows that the timings and magnitude of exchange flows are also realistically simulated, along with the blocking events. The short-term variability of the strait transports is largely controlled by the anomalies of wind. The simulations demonstrate the crucial role of the narrow and shallow strait of Bosporus in separating the two pairs of basins: Aegean-Marmara Seas from one side and Azov-Black Seas from the other side. The straits of Kerch and Dardanelles provide sufficient interbasin connectivity that prevents large phase lags of the sea levels in the neighboring basins. The two-layer flows in the three straits considered here show different dependencies upon the net transport, and the spatial variability of this dependence is also quite pronounced. We show that the blocking of the surface flow can occur at different net transports, thus casting doubt on a previous approach of using simple relationships to prescribe (steady) outflow and inflow. Specific attention is paid to the role of synoptic atmospheric forcing for the basin-wide circulation and redistribution of mass in the Black Sea. An important controlling process is the propagation of coastal waves. One major conclusion from this research is that modeling the individual basins separately could result in large inaccuracies because of the critical importance of the cascading character of these interconnected basins.