The Proterozoic,albitite-hosted,Valhalla uranium deposit,Queensland, Australia: a description of the alteration assemblage associated with uranium mineralisation in diamond drill hole V39

The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite, (uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the assemblage of Rodinia. The oldest ages of the brannerite overlap with ⁴⁰Ar/³⁹Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr, P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and reibeckite within the ore zone suggests that F⁻ and were important ore-transporting complexes. δ¹⁸O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a fluid having δ¹⁸O_fluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δD_fluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ¹⁸O_fluid and δD_fluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small pegmatite dykes that intruded during the Isan Orogeny.     

Evaluation of effective management plan for an agricultural watershed using AVSWAT model,remote sensing and GIS

In the present investigation, an effort has been made to identify the critical sub-watersheds for the development of best management plan for a small watershed of Eastern India using a hydrological model, namely, AVSWAT2000. A total of 180 combinations of various management treatments including crops (rice, maize ground nut and soybean), tillage (zero, conservation, field cultivator, mould board plough and conventional practices) and fertilizer levels (existing half of recommended and recommended) have been evaluated. The investigation reveled that rice cannot be replaced by other crops such as groundnut, maize, mungbean, sorghum and soybean since comparatively these crops resulted in higher sediment yield. The tillage practices with disk plough have been found to have more impact on sediment yield and nutrient losses than conventional tillage practices for the existing level of fertilizer. Sediment yield decreased in the case of zero tillage, conservation tillage, field cultivator, moldboard plough, and conservation tillage as compare to conventional tillage. Lowest NO₃–N loss was observed in zero tillage in all the fertilizer treatments, whereas field cultivator, moldboard plough and disk plough resulted in increase of NO³–N loss. As compared to conventional tillage, the losses of soluble phosphorus were increased in moldboard plough. The losses of organic nitrogen were also increased as fertilizer dose increased. After zero tillage the conservation tillage preformed better in all the fertilizer treatments as per loss of organic nitrogen and organic phosphorus is concerned. It can be concluded that the sediment yield was found to be the highest in the case of disk plough followed by moldboard plough, field cultivator, conventional tillage, field cultivator and least in zero tillage practices. The nutrient losses were found to be in different order with tillage practices, resulted highest in disk plough tillage practices. In view of sediment yield and nutrient losses, the conservation tillage practice was found to be the best as the sediment yield is less than the average soil loss whereas nutrient loss is within the permissible limit.     

Global change and the biogeochemistry of the North Sea: the possible role of phytoplankton and phytoplankton grazing

Phytoplankton plays a dominant role in shelf biogeochemistry by producing the major part of organic matter. Part of the organic matter will reach the sediment where diagenetic processes like denitrification, apatite formation or burial will remove nutrients from the biogeochemical cycle. In this article current knowledge on the decadal plankton variability in the North Sea is summarized and possible implications of these changes for the biogeochemistry of the North Sea are discussed. Most of the observed interdecadal dynamics seem to be linked to large-scale oceanographic and atmospheric processes. Prominent changes in the North Sea ecosystem have taken place around 1979 and 1988. In general, the phytoplankton color (CPRS indicator of phytoplankton biomass) reached minimum values during the end of the 1970s and has increased especially since the mid 1980s. Changes with a similar timing have been identified in many time series from the North Sea through the entire ecosystem and are sometimes referred to as regime shifts. It is suggested that the impact of global change on the local biogeochemistry is largely driven by the phyto- and zooplankton dynamics during spring and early summer. At that time the extent of zooplankton–phytoplankton interaction either allows that a large part of the new production is settling to the sediment, or that a significant part of the new production including the fixed nutrients is kept within the pelagic system. The origin of the extent of the phytoplankton–zooplankton interaction in spring is probably set in the previous autumn and winter. In coastal areas, both large-scale atmospheric and oceanographic changes as well as anthropogenic factors influence the long-term dynamics. Due to eutrophication, local primary production nowadays still is up to five times higher than during pre-industrial conditions, despite a decreasing trend. Recently, introduced species have strengthened the filter feeder component of coastal ecosystems. Especially in shallow coastal seas like the Wadden Sea, this will enhance particle retention, shift organic matter degradation to the benthic compartment and enhance nutrient removal from the biogeochemical cycle by denitrification or apatite formation.     

Geochemical constraints on the origin of the late Jurassic proto-Caribbean oceanic crust in Hispaniola

The nature of the oceanic crust produced through rifting and oceanic spreading between North and South America during the Late Jurassic is a key element for the Caribbean plate tectonic model reconstruction. Located in the Cordillera Central of Hispaniola, the Loma La Monja volcano-plutonic assemblage (LMA) is composed of gabbros, dolerites, basalts, and oceanic sediments, as well as metamorphic equivalents, which represent a dismembered fragment of this proto-Caribbean oceanic crust. Petrologic and geochemical data show that the LMA have a relatively broad diversity in composition, which represent the crystallization products of a typical low-pressure tholeiitic fractionation of mid-ocean ridge basalts (MORB)-type parental magmas, ranging from N- to E-MORB. Three geochemical groups have been distinguished in the volcanic sequence: LREE-flat to slightly LREE-enriched basalts of groups II and III occur interlayered in the lower stratigraphic levels; and LREE-depleted basalts of group I in the upper levels. Mantle melt modeling suggests that group III magmas are consistent by mixing within a mantle melt column of low-degree (<1%) melts of a deep garnet lherzolite source and high-degree (>15%) melts of a shallow spinel source, and groups II and I magmas are explained with moderate to high (14–18%) and very high (>20%) fractional melting degrees of a shallower spinel mantle source, respectively. Thus, upward in the volcanic sequence of the LMA, the magmas represent progressively more extensive melting of shallower sources, in a plume-influenced spreading ridge of the proto-Caribbean oceanic crust. Nb/Y versus Zr/Y systematics combined with recent plate tectonic model reconstructions reveal that Caribbean Colombian oceanic plateau fragments in Hispaniola formed through melting of heterogeneous mantle source regions related with distinct plumes during at least from Aptian–Albian (>96 Ma) to Late Campanian.     

Empty marine container logistics: facts,issues and management strategies

With the global container population exceeding 25 million TEU (Twenty-foot Equivalent Unit) and the annual production of new boxes exceeding 3 million TEU it is estimated that around 1.5 million TEU of empty containers are sitting in yards and depots around the world waiting for use. Although utilization rates have improved since 2004, container utilization depends on the very dynamic nature of container transportation, and the container building and leasing industries. Owing primarily to the chronic trend of increasing trade imbalances across the oceans, and despite recent trends along some trade routes, the empty container management problem has become a major issue for the container shipping industry during the last decade. This paper examines and analyzes empty container logistics at a global, interregional, regional and local level. Special consideration is given to key factors affecting the empty container logistics management and strategies implemented by ocean carriers and other stakeholders to better manage empty containers.

Geochemical distribution and removal of As,Fe, Mn and Al in a surface water system affected by acid mine drainage at a coalfield in Southwestern China

The chemical characteristics, formation and natural attenuation of pollutants in the coal acid mine drainage (AMD) at Xingren coalfield, Southwest China, are discussed in this paper based on the results of a geochemical investigation as well as geological and hydrogeological background information. The chemical composition of the AMD is controlled by the dissolution of sulfide minerals in the coal seam, the initial composition of the groundwater and the water–rock interaction. The AMD is characterized by high sulfate concentrations, high levels of dissolved metals (Fe, Al, Mn, etc.) and low pH values. Ca²⁺ and SO₄ ²⁻ are the dominant cation and anion in the AMD, respectively, while Ca²⁺ and HCO₃ ⁻ are present at significant levels in background water and surface water after the drainage leaves the mine site. The pH and alkalinity increase asymptotically with the distance along the flow path, while concentrations of sulfate, ferrous iron, aluminum and manganese are typically controlled by the deposition of secondary minerals. Low concentrations of As and other pollutants in the surface waters of the Xingren coalfield could be due to relatively low quantities being released from coal seams, to adsorption and coprecipitation on secondary minerals in stream sediments, and to dilution by unpolluted surface recharge. Although As is not the most serious water quality problem in the Xingren region at present, it is still a potential environmental problem. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Viscosity effect on consolidation of poroelastic soil due to groundwater table depression

In this study, the viscosity effect on consolidation of poroelastic soil due to groundwater table depression is examined. A viscoelastic consolidation numerical model is developed to conduct this examination. By nondimensionalizing the governing equations the viscosity number that depends on hydraulic conductivity, viscous moduli, and thickness of soil is obtained to represent the viscosity effect on consolidation of poroelastic soil. The case of clay stratum sandwiched between sandy strata subjected to sudden and gradual groundwater table depressions is used to investigate the importance of viscosity effect to poroelastic consolidation. The results show that the displacement and pore water pressure of clay stratum are strongly related to the viscosity effect. The overestimation of soil displacement will occur if the viscosity effect is neglected. Hence, the viscosity effect needs to be considered in modeling consolidation of poroelastic soil under groundwater table depression.     

DECOVALEX Project: from 1992 to 2007

The DECOVALEX project is a unique international research collaboration, initiated in 1992, for advancing the understanding and mathematical modelling of coupled thermo-hydro-mechanical (THM) and thermo-hydro-mechanical-chemical (THMC) processes in geological systems—subjects of importance for performance assessment of radioactive waste repositories in geological formations. From 1992 up to 2007, the project has made important progress and played a key role in the development of numerical modelling of coupled processes in fractured rocks and buffer/backfill materials. The project has been conducted by research teams supported by a large number of radioactive-waste-management organizations and regulatory authorities, including those of Canada, China, Finland, France, Japan, Germany, Spain, Sweden, UK, and the USA. Through this project, in-depth knowledge has been gained of coupled THM and THMC processes associated with nuclear waste repositories, as well as numerical simulation models for their quantitative analysis. The knowledge accumulated from this project, in the form of a large number of research reports and international journal and conference papers in the open literature, has been applied effectively in the implementation and review of national radioactive-waste-management programmes in the participating countries. This paper presents an overview of the project.     

Granulometric analysis of glacial sediments,Schirmacher Oasis,East Antarctica

Granulometric analysis of nineteen sediment samples has been carried out for their statistical and textural parameters. The samples are collected from the northern and southern margins of Schirmacher Oasis extending below the polar ice sheet and grading to coastal area respectively and main rocky land of Schirmacher including lakes. The analysis shows that most of the sediments are of medium grain size and fall in poor to very poor sorted category. An attempt has been made to interpret the depositional set-up by plotting the scatter patterns between various textural parameters, including C-M plot and arithmetic log-probability curves. The influence of physical parameters viz. low to high velocity winds, ice and meltwater on sediment characteristics has been discussed.     

Robustness of the holistic seismic risk evaluation in urban centers using the USRi

The Urban Seismic Risk index (USRi) published in a previous article (Carreño et al., Nat Hazards 40:137–172, 2007) is a composite indicator that measures risk from an integrated perspective and guides decision-making for identifying the main interdisciplinary factors of vulnerability to be reduced or intervened. The first step of the method is the evaluation of the potential physical damage (hard approach) as a result of the convolution of the seismic hazard with the physical vulnerability of buildings and infrastructure. Subsequently, a set of social context conditions that aggravate the physical effects is also considered (soft approach). According to this procedure, the physical risk index is evaluated for each unit of analysis from existing loss scenarios, whereas the total risk index is obtained by multiplying the former index by an impact factor using an aggravating coefficient, based on variables associated with the socio-economic conditions of each unit of analysis. The USRi has been developed using the underlying holistic and multi-hazard approach of the Urban Risk Index framework proposed for the evaluation of disaster risk in different megacities worldwide. This article presents the sensitivity analysis of the index to different parameters such as input data, weights and transformation functions used for the scaling or normalization of variables. This analysis has been performed using the Monte Carlo simulation to validate the robustness of this composite indicator, understanding as robustness how the cities maintain the ranking as well as predefined risk level ranges, when compared with the deterministic results of risk. Results are shown for different cities of the world.