Selective chemical extraction of heavy metals in tailings and soils contaminated by mining activity: Environmental implications

Total concentrations of chemical elements in soils may not be enough to understand the mobility and bioavailability of the elements. It is important to characterise the degree of association of chemical elements in different physical and chemical phases of soil. Another geochemical characterisation methodology is to apply sequential selective chemical extraction techniques. A seven-step sequential extraction procedure was used to investigate the mobility and retention behaviour of Al, Fe, Mn, Cu, Zn, Pb, Cr, Co, Ni, Mo, Cd, Bi, Sn, W, Ag, As and U in specific physical–chemical and mineral phases in mine tailings and soils in the surroundings of the abandoned Ervedosa mine. The soil geochemical data show anomalies associated with mineralised veins or influenced by mining. Beyond the tailings, the highest recorded concentrations for most elements are in soils situated in mineralised areas or under the influence of tailings. The application of principal components analysis allowed recognition of (a) element associations according to their geochemical behaviour and (b) distinction between samples representing local geochemical background and samples representing contamination. Some metal cations (Mn, Cd, Cu, Zn, Co, Cr, Ni) showed important enrichment in the most mobilisable and bioavailable (i.e., water-soluble and exchangeable) fractions due likely to the acidic conditions in the area. In contrast, oxy-anions such as Mo and As showed lower mobility because of adsorption to Fe oxy-hydroxides. The residual fraction comprised largest proportions of Sn and Al and to a lesser extent Zn, Pb, Ni, Cr, Bi, W, and Ag, which are also present at low concentrations in the bioavailable fractions. The elements in secondary mineral phases (mainly Fe, Mn, Cu, Zn, Cd, Pb, W, Bi, Mo, Cr, Ni, Co, As and U) as well as in organic matter and sulphides are temporarily withheld, suggesting that they may be released to the environment by changes in physico-chemical conditions.     

Regional stresses along the Eurasia-Africa plate boundary derived from focal mechanisms of large earthquakes

The focal mechanism solutions of 83 European earthquakes withM>6, selected from a total of 140, have been used to derive the directions of the principal axes of stress along the plate boundary between Eurasia and Africa from the Azores islands to the Caucasus mountains. Along most of the region, the horizontalP-axes are at an angle of 45° to 90° with the trend of the plate boundary. HorizontalT-axes are concentrated in central Italy and northern Greece in association with normal faulting. Large strike-slip motion of right-lateral character takes place at the center of the Azores-Gibraltar fault and the North Anatolian fault. From Gibraltar to the Caucasus the boundary is complicated by the presence of secondary blocks and zones of extended deformations with earthquakes spread over wide areas. Intermediate and deep earthquakes are present at four areas with arc-like structure, namely, Gibraltar, Sicily-Calabria, Hellenic arc and Carpathians.     

Volcanic evolution of the island of Tenerife (Canary Islands) in the light of new K-Ar data

New age determinations from Tenerife, together with those previously published (93 in all), provide a fairly comprehensive picture of the volcanic evolution of the island. The oldest volcanic series, with ages starting in the late Miocene, are formed mainly by basalts with some trachytes and phonolites which appear in Anaga, Teno and Roque del Conde massifs. In Anaga (NE), three volcanic cycles occurred: one older than 6.5 Ma, a second one between 6.5 and 4.5 Ma, with a possible gap between 5.4 and 4.8 Ma, and a late cycle around 3.6 Ma. In Teno (NW), after some undated units, the activity took place between 6.7 and 4.5 Ma, with two main series separated by a possible pause between 6.2 and 5.6 Ma. In the zone of Roque del Conde (S), the ages are scattered between 11.6 and 3.5 Ma. Between 3.3 and 1.9 Ma, the whole island underwent a period of volcanic quiescence and erosion.The large Cañadas volcano, made up of basalts, trachytes and phonolites, was built essentially between 1.9 and 0.2 Ma. To the NE of this central volcano, linking it with Anaga, is a chain of basaltic emission centers, with a peak of activity around 0.8 Ma. The Cañadas Caldera had several collapse phases, associated with large ignimbrite emissions. There were, at least, an older phase more than 1 Ma old, on the western part of the volcano, and a younger one, less than 0.6 Ma old, in the eastern side. The two large “valleys” of Guimar and la Orotava were formed by large landslides less than 0.8 Ma ago, and probably before 0.6 Ma ago. The present Cañadas caldera was formed by another landslide, less than 0.2 Ma ago. This caldera was later filled by the huge Teide volcano, which has been active even in historic times. During the same period a series of small volcanoes erupted at scattered locations throughout the island.The average eruptive rate in Tenerife was 0.3 km³/ka, with relatively small variations for the different eruptive periods. This island and La Gomera represent a model of growth by discontinuous pulses of volcanic activity, separated by gaps often coinciding with episodes of destruction of the edifices and sometimes extended for several million years. The neighbouring Gran Canaria, on the other hand, had an initial, rapid “shield-building phase” during which more than 90% of the island was built, and a series of smaller pulses at a much later period.A comparison between these three central islands indicates that the previously postulated westward displacement in time of a gap in the volcanic activity is valid only as a first approximation. Several gaps are present on each island, overlapping in time and not clearly supporting either of the models proposed to explain the evolution of the Canaries.     

Improving precipitation simulation from updated surface characteristics in South America

Land use and land cover maps and their physical-chemical and biological properties are important variables in the numerical modeling of Earth systems. In this context, the main objective of this study is to analyze the improvements resulting from the land use and land cover map update in numerical simulations performed using the Regional Climate Model system version 4 (RegCM4), as well as the seasonal variations of physical parameters used by the Biosphere Atmosphere Transfer Scheme (BATS). In general, the update of the South America 2007 land use and land cover map, used by the BATS, improved the simulation of precipitation by 10 %, increasing the mean temporal correlation coefficient, compared to observed data, from 0.84 to 0.92 (significant at p < 0.05, Student’s t test). Correspondingly, the simulations performed with adjustments in maximum fractional vegetation cover, in visible and shortwave infrared reflectance, and in the leaf area index, showed a good agreement for maximum and minimum temperature, with values closer to observed data. The changes in physical parameters and land use updating in BATS/RegCM4 reduced overestimation of simulated precipitation from 19 to 7 % (significant at p < 0.05, Student’s t test). Regarding evapotranspiration and precipitation, the most significant differences due to land use updating were located (1) in the Amazon deforestation arc; (2) around the Brazil-Bolivia border (in the Brazilian Pantanal wetlands); (3) in the Northeast region of Brazil; (4) in northwestern Paraguay; and (5) in the River Plate Basin, in Argentina. Moreover, the main precipitation differences between sensitivity and control experiments occurred during the rainy months in central-north South America (October to March). These were associated with a displacement in the South Atlantic convergence zone (SACZ) positioning, presenting a spatial pattern of alternated areas with higher and lower precipitation rates. These important differences occur due to the replacement of tropical rainforest for pasture and agriculture and the replacement of agricultural areas for pasture, scrubland, and deciduous forest.

     

Probabilistic seismic hazard assessment of Italy using kernel estimation methods

A representation of seismic hazard is proposed for Italy based on the zone-free approach developed by Woo (BSSA 86(2):353–362, 1996a), which is based on a kernel estimation method governed by concepts of fractal geometry and self-organized seismicity, not requiring the definition of seismogenic zoning. The purpose is to assess the influence of seismogenic zoning on the results obtained for the probabilistic seismic hazard analysis (PSHA) of Italy using the standard Cornell’s method. The hazard has been estimated for outcropping rock site conditions in terms of maps and uniform hazard spectra for a selected site, with 10 % probability of exceedance in 50 years. Both spectral acceleration and spectral displacement have been considered as ground motion parameters. Differences in the results of PSHA between the two methods are compared and discussed. The analysis shows that, in areas such as Italy, characterized by a reliable earthquake catalog and in which faults are generally not easily identifiable, a zone-free approach can be considered a valuable tool to address epistemic uncertainty within a logic tree framework.     

Gender and local soil knowledge: Linking farmers' perceptions with soil fertility in two villages in the Philippines

Scientists often turn to farmers to understand soil management. This process reveals differences and overlaps between local and scientific soil knowledge but rarely considers women and gender issues. This paper examines men's and women's local knowledge of soils in upland, smallholder farms in two villages in Mindanao, the Philippines, using focus group discussions, semi‐structured household interviews, field visits, GIS and soil testing. Farmers' field areas were calculated and delineated based on their perceptions of the different types of soils on their land. Men and women chose the same plots for what they considered their best soil but differed on what they felt were their worst. The fertility of the soils that women considered to be the best and worst was not significantly different from that of the men's respective choices. There was a difference in fertility, however, between the best and worst soils regardless of gender. Although soil fertility analyses showed that the women's chosen soils were similar to men's, analyses of qualitative data showed that their knowledge of soils was different and was based in part on a gendered division of labour. A multidisciplinary approach helped bridge the gap between sociocultural and physical research.     

The Oyambre coastal terrace: a detailed sedimentary record of the Last Interglacial Stage in northern Iberia (Cantabrian coast,Spain)

A detailed study is presented of a 15.3-m-thick Pleistocene coastal terrace located on the Cantabrian coast (northern Spain). Stratigraphic, sedimentological, topographic and micropalaeontological information is combined with a chronology based on luminescence dating to characterize the deposits. The sedimentary succession records: (i) a basal transgressive system, consisting of a wave-cut surface covered by a lower layer of beach gravels and upper beach pebbly sands; and (ii) a thicker upper highstand system (aggrading), comprising medium to very fine aeolian sands interbedded with thin palustrine muds. Luminescence dating involved a detailed sampling strategy (36 samples and two modern analogues) and the use of both quartz optically stimulated luminescence (OSL) and feldspar post-infrared infrared stimulated luminescence single aliquot regeneration protocols; feldspar results were used to confirm the completeness of bleaching of the quartz OSL signal. The quartz OSL luminescence age–depth relationship shows significant dispersion, but nevertheless two rapid phases of deposition can be clearly identified: one at ~130 ka [Marine Oxygen Isotope Stage (MIS) 5] and one at ~100 ka (MIS 5c). The top of the succession is dated to ~70 ka. The MIS 5e marine maximum flooding surface is identified at an elevation of 6.85 m above mean seal level. This elevation provides evidence of a regional sea-level highstand for this sector of the Cantabrian coast.     

Benthic Fluxes of Dissolved Inorganic Nitrogen in a Coastal Lagoon of the Northern Adriatic Sea: an Interpretation of Spatial Variability Based on Sediment Features and Infauna Activity

Abstract. Dark respiration rates, dissolved inorganic nitrogen (DIN) fluxes and nitrification rates were measured at two sites in the microtidal Sacca di Goro lagoon in September 2000. DIN fluxes correlated with the biomass of the dominant macrofauna species (the amphipod Corophium spp. at station Giralda and the polychaete Neanthes spp. at station Faro). Respiration (> 6 mmol O₂ m⁻²h⁻¹) and ammonium fluxes (> 80μmol N m⁻²h⁻¹) were higher at station Giralda despite the lower organic matter content (4.5 %) and lower macrofauna biomass (4 g AFDW m⁻²). At both sites ammonium fluxes were significantly correlated with the biomass of the benthic infauna, but Corophium stimulated ammonium NH₄⁺ fluxes 3-fold compared to Neanthes. The amphipod also enhanced nitrification rates (> 300 μmol N m⁻²h⁻¹) due to the high density of its burrows, the higher NH₄⁺ regeneration rates and the enhanced oxygen supply to the bacteria.     

Tidal frequency dynamics of a Southern Brazil coastal lagoon: Choking and short period forced oscillations

The Patos Lagoon is a choked, microtidal coastal laggon situated in southern Brazil between 30°S and 32°S. The response of the lagoon to tidal oscillations is studied through data analysis and numerical modeling experiments. Two types of high frequency oscillations are observed in the tidal frequency band: mixed tides, predominantly diurnal; and forced oscillations having a period of 24 h occurring in the inner lagoon. In the southern portion of the lagoon, tides are selectively filtered by the entrance channel. The main diurnal constituent O₁ is linearly attenuated as it progresses landwards. In the inner parts of the lagoon, 24-h oscillations are mainly forced by the combined effect of diurnal tides and sea breeze action. They are tied with a natural period of oscillation of 24 h. Results also indicate that these are not inertial frequency oscillations, despite the lagoon being placed in a critical 30°S area. The interaction between astronomical tides and meteorological effects produces a complicated picture for tidal forecasting derived from data collected inside the lagoon.