North American transect of stable hydrogen and oxygen isotopes in water beetles from a museum collection

Museum collections contain a wealth of insect remains originating from a wide geographic range, which can be used to investigate their utility as a proxy for environmental isotope ratios. Chitinous remains of insects such as beetles (Coleoptera) are chemically stable and their stable isotope composition is strongly related to that of environmental water in the period of cuticle formation. We present a dataset of chitin ??D and ??¹⁸O in two genera of water beetles from a museum collection containing 40 locations for Helophorus (water scavenging beetles) and 48 locations for Hydroporus (predaceous diving beetles) that were selected from latitudes 27?C82°N in North America. Only two genera were used to minimize inter-sample variation caused by species-specific differences in metabolic effects, feeding strategy, habitat, and life cycle. The isotopic composition of water beetle exoskeletons had a strong latitudinal trend (North?CSouth) from ?160 to +65??? for ??D and from 7 to 34??? for ??¹⁸O, paralleling gradients of isotopes in precipitation. Strong relationships were observed between isotopic composition of beetles and modelled July precipitation (0.71?<?R ²?<?0.82, p?<?0.001). The relationship between ??D and ??¹⁸O in the beetle samples had a systematic offset from the global meteoric water line, which was likely caused by metabolic effects during chitin formation. The offset between ??D values in beetles and in modelled precipitation was 33??? larger, on average, for Hydroporus compared with Helophorus, suggesting fractionation of hydrogen isotopes during passage through the food chain. This trophic level effect was not observed for stable oxygen isotopes. Furthermore, the observed deviations between isotopic composition of water beetles and modelled precipitation at collection sites were not constant and indicated local hydrological deviations from modelled precipitation. The largest deviations were observed for sites in the Southern US and the Arctic that are highly evaporative and at sites in the Rocky Mountains and Coastal Mountains that were fed by snow melt. Our results indicated that the isotopic composition of water beetles from a museum collection was systematically related to ??D and ??¹⁸O values of precipitation at the collection site.     

Hydrological and nitrogen distributed catchment modeling to assess the impact of future climate change at Trichonis Lake, western Greece

According to regional climatic models, climate change may affect Mediterranean lakes significantly in terms of water availability and quality. Trichonis Lake catchment covers a semi-mountainous area of 403 km² including the largest Greek lake by volume (2.6?×?10⁹?m³), located in western Greece. The impact of climate change on the hydrology and water quality of the lake, in terms of lake water level and nutrient concentrations, has been assessed. Water balance estimates and geographical information system tools were then used to set up a physically based, spatially distributed model. The calibrated model was simulated for two future scenarios specified by the Intergovernmental Panel on Climate Change: A2 (pessimistic) and B2 (more optimistic), which involved temperature/evaporation/evapotranspiration increase and small precipitation decrease. The model was calibrated efficiently for the 1990–1992 period. The two basic climatic scenarios illustrated that the responses of the lake water levels will show a decrease of 24.2 and 12 cm, respectively, and an increase of total nitrogen concentrations by 3.4 and 10%, in relation to the early 1990s values. These important findings suggest that mitigation and optimum management plans should be developed to eliminate the aforementioned climate change impacts and further research should follow.     

Early Wisconsinan (MIS 4) Arctic ground squirrel middens and a squirrel-eye-view of the mammoth-steppe

Fossil arctic ground squirrel (Spermophilus parryii) middens were recovered from ice-rich loess sediments in association with Sheep Creek-Klondike and Dominion Creek tephras (ca 80 ka) exposed in west-central Yukon. These middens provide plant and insect macrofossil evidence for a steppe-tundra ecosystem during the Early Wisconsinan (MIS 4) glacial interval. Midden plant and insect macrofossil data are compared with those previously published for Late Wisconsinan middens dating to ～25–29¹⁴C ka BP (MIS 3/2) from the region. Although multivariate statistical comparisons suggest differences between the relative abundances of plant macrofossils, the co-occurrence of steppe-tundra plants and insects (e.g., Elymus trachycaulus, Kobresia myosuroides, Artemisia frigida, Phlox hoodii, Connatichela artemisiae) provides evidence for successive reestablishment of the zonal steppe-tundra habitats during cold stages of the Late Pleistocene. Arctic ground squirrels were well adapted to the cold, arid climates, steppe-tundra vegetation and well-drained loessal soils that characterize cold stages of Late Pleistocene Beringia. These glacial conditions enabled arctic ground squirrel populations to expand their range to the interior regions of Alaska and Yukon, including the Klondike, where they are absent today. Arctic ground squirrels have endured numerous Quaternary climate oscillations by retracting populations to disjunct “interglacial refugia” during warm interglacial periods (e.g., south-facing steppe slopes, well-drained arctic and alpine tundra areas) and expanding their distribution across the mammoth-steppe biome during cold, arid glacial intervals.     

Bridges and bottlenecks: Andrei Sher’s role in the development of international collaboration in Beringian science

Andrei Sher played a leading role in the development of international cooperation and exchange of ideas in Beringian science. The Cold War created great tensions between the USSR and the NATO countries, as the Bering Strait region became one of the front lines of potential military conflict. However, through the persistent efforts of such people as Andrei Sher in Russia and David Hopkins in the USA, scientists were able to overcome political obstacles to attend international Beringian conferences, visit each other’s militarized zones to do fieldwork, and collaborate on joint projects.     

The circumvention of the natural biopurification of calcium along nutrient pathways by atmospheric inputs of industrial lead

Biopurification factors for Ca with respect to Sr, Ba, and natural, uncontaminated Pb were measured for different nutrient-consumer pairs in a remote subalpine ecosystem. The factor for Sr is expressed as: (nutrient $\text{Sr}\text{Ca}$) ÷ (consumer $\text{Sr}\text{Ca}$). Similar expressions were used for $\text{Ba}\text{Ca}$ and $\text{Pb}\text{Ca}$. It was found that Ca was biopurified of Sr 3-fold, of Ba 16-fold, and of Pb 100-fold in going from rock to sedge leaves. In going from sedge leaf to vole, Ca was biopurified of Sr 4-fold, of Ba 8-fold, and of Pb 16-fold. In going from meadow vole to pine marten, Ca was biopurified of Sr 6-fold, of Ba 7-fold, and of Pb 1.1-fold. Similar ranges of values for these factors were obtained for detrital and amphibian food chains. Fluxes of industrial lead entering the ecosystem as precipitation and dry deposition were measured and it was found that 40% of the lead in soil humus and soil moisture, 82% of the lead in sedge leaves, 92% of the lead in vole, and 97% of the lead in marten was industrial. The natural skeletal $\text{Pb}\text{Ca}$ ratio in carnivores (4 × 10^?8) was determined by means of corrections for inputs of industrial lead, food chain relationships, and measured biopurification factors for the ecosystem studied. This represents a 1700-fold reduction of the average $\text{Pb}\text{Ca}$ ratio in igneous rocks at the earth's surface (6.4 × 10^?5) by the compounding of successive Pb biopurification factors in transferring Ca from rock to carnivore. The natural ratio is similar to the value of 6 × 10^?8 observed for $\text{Pb}\text{Ca}$ in the bones of Peruvians who lived 2000 years ago but is 1/900th of the value of about 3.5 × 10^?5 for the skeletal $\text{Pb}\text{Ca}$ ratio found in present day Americans.This study shows experimentally how the $\text{Ba}\text{Ca}$ ratio in average surface igneous rock (3 × 10^?3) has been reduced 800-fold through compounding of successive biopurification steps to provide the skeletal $\text{Ba}\text{Ca}$ ratio of about 4 × 10^?6 observed in humans. It also provides biopurification factors for Sr and Ba among a number of nutrient-consumer pairs which anthropologists can use to delineate degrees of herbivory in diets of hominids within the last 10,000 years.     

Real-time measurement of volcanic SO2 emissions: validation of a new UV correlation spectrometer (FLYSPEC)

A miniaturized, lightweight and low-cost UV correlation spectrometer, the FLYSPEC, has been developed as an alternative for the COSPEC, which has long been the mainstay for monitoring volcanic sulfur dioxide fluxes. Field experiments have been conducted with the FLYSPEC at diverse volcanic systems, including Masaya (Nicaragua), Poás (Costa Rica), Stromboli, Etna and Vulcano (Italy), Villarica (Chile) and Kilauea (USA). We present here those validation measurements that were made simultaneously with COSPEC at Kilauea between March 2002 and February 2003. These experiments, with source emission rates that ranged from 95 to 1,560 t d⁻¹, showed statistically identical results from both instruments. SO₂ path-concentrations ranged from 0 to >1,000 ppm-m with average correlation coefficients greater than r ²=0.946. The small size and low cost create the opportunity for FLYSPEC to be used in novel deployment modes that have the potential to revolutionize the manner in which volcanic and industrial monitoring is performed.     

Pollutant concentrations in fog and low cloud water at selected sites of the Czech Republic

In this paper, the basic composition of fog and low cloud water are presented, resulting from the analyses of water samples from 111 fog/cloud events. The samples were collected at five sites located in various regions of the Czech Republic. Two sampling sites are in mountainous regions and three sites represent various urban areas. The mountain stations are located in two regions of the Czech Republic with different industry types. At all the sites, active fog collectors were employed. In the water samples, the conductivity, acidity (pH), cations (H⁺, Na⁺, K⁺, NH₄⁺, Mg²⁺, Ca²⁺) and anions (F⁻, Cl⁻, NO₃⁻, SO₄²⁻) were determined.A mean pH value of about 4.5 was obtained at mountain sites whereas the measurements in urban areas showed mean pH values from 4.9 to 6.4. The mean conductivity values in the samples from the two mountain stations were 137 and 191.5 μS cm⁻¹. The samples from urban sites showed mean values between 127.7 and 654.4 μS cm⁻¹. The maximum concentration means for the three dominant pollutants (expressed by the ratio mountain sites/urban sites) are 32.9/99.6 mg l⁻¹ for NO₃⁻, 32.5/192.9 mg l⁻¹ for SO₄²⁻ and 18.5/52.7 mg l⁻¹ for NH₄⁺. As expected, we found higher ion concentrations in the northern part of the Czech Republic where larger numbers of lignite-burning power plants, chemical factories and opencast lignite mines are located. A decrease in ion concentrations was observed at higher altitude sites, probably reflecting at least in part higher liquid water contents at these locations.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part I: Isotopic (C,O) study of the Khushaym Matruk natural analogue (central Jordan)

The Khushaym Matruk site in central Jordan may represent a natural analogue depicting the interaction of alkaline solutions with a clayey sedimentary formation or with clay-rich confining barriers at the interface with concrete structures in waste disposal sites. In this locality, past spontaneous combustion of organic matter in a clayey biomicritic formation produced a ca. 60 m-thick layer of cement-marble containing some of the high-temperature phases usually found in industrial cements (e.g., spurrite, brucite, and Ca-aluminate). A vertical cross-section of the underlying sediments was used in order to study the interaction between cement-marbles and neighbouring clayey limestones under weathering conditions. A thermodynamic approach of the alteration parageneses (calcite–jennite–afwillite–brucite and CSH phases) in the cement-marbles constrains the interacting solutions to have had pH-values between 10.5 and 12. Over 3 m, the sediments located beneath the metamorphic unit were compacted and underwent carbonation. They display large C and O isotopic variations with respect to “pristine” sediments from the bottom of the section. Low δ¹³C-values down to −31.4‰/PDB show the contribution of CO₂ derived from the oxidization of organic matter and from the atmosphere to the intense carbonation process affecting that particular sedimentary level. The size of the C isotopic anomalies, their geometrical extent and their coincidence with the variations of other markers like the Zn content, the structure of organic matter, the mineralogical composition, all argue that the carbonation process was induced by the percolation of high pH solutions which derived from the alteration of cement-marbles. The temperature of the carbonation process remains conjectural and some post-formation O isotopic reequilibration likely affected the newly-formed carbonate. Carbonation induced a considerable porosity reduction, both in fractures and matrixes. The Khushaym Matruk site may have some bearing to the early life of a repository site, when water saturation of the geological formations hosting the concrete structures is incomplete, enabling simultaneous diffusion of alkaline waters and gaseous CO₂ in the near field.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part II: Organic matter evolution,magnetic susceptibility and metals (Ti,Cr, Fe) at the Khushaym Matruk natural analogue (Central Jordan)

Spontaneous combustion, less than 1 Ma ago, affected a 60-m thick sediment pile of biomicrite at the Khushaym Matruck site (Jordan). The present study shows that three retrograde alteration stages occurred: weathering, thermal stress and oxidative alkaline perturbation. μ-FT-i.r. spectra of isolated kerogens and oxygen index of whole rocks indicate that oxidation of organic matter occurred down to ∼10 m beneath the metamorphosed zone at Khushaym Matruck. The occurrence of the oxidative weathering bacterially mediated, as suggested by the mass chromatograms of saturated hydrocarbons, can explain high Rock-Eval T_max values and low petroliferous potential measured along the sedimentary pile. On the other hand, the thermal extent of combustion events was limited to the first 2 m from the contact. The mean reflectance of 0.20–0.24% and porosity of ca. 50% of the grey clayey biomicrites indicate that organic matter was very immature and sediments were unconsolidated at the time of the combustion event. Using mineralogy, microscopic analyses of vegetable debris and magnetic susceptibility, a suite of characteristic points corresponding to the thermal imprint can be assessed: (i) x = 0m, T ∼ 1000 °C, (ii) x = 1 m, T ∼ 350 °C, (iii) x = 2 m, T ∼ 150 °C and (iv) x > ∼ 8 m, T ∼ 30 °C. Paleocirculation of meteoric groundwater in the ‘cement-marbles’ generated high-pH fluids that have circulated via fractures and through the matrix porosity of the underlying biomicrites but have also induced alkaline hydrolysis and oxidative attack of the organic matter. The polysaccharide/lignin ratio derived from μ-FT-i.r. analyses shows that the delignification of vegetable debris and degradation of polysaccharides progressively decline in the indurated zone, which indicates a decrease in the pH of migrating solutions. The latter also severely oxidized organic matter at 2.10 and 3.05 m as revealed by the oxygen index and induced the generation of bitumen. The spatial correlation between the oxidation levels of organic matter and the metal contents (Fe, Ti and Cr) suggests that redox reactions were responsible for the immobilization of metals in the indurated biomicrites. The intensity of these reactions is attributed to changes in the fluid flow regime within the sedimentary column.     

Separation between Gould Belt and Disk Stars in the Solar Neighbourhood

The adoption of a parametric model for the spatial distribution of Gould Belt and Galactic Disk stars allows the classification by their membership probabilities of stars from the Hipparcos catalogue in the Solar vicinity and the estimation of structural parameters for both stellar systems for several age groups. The observed kinematics of Gould Belt and Disk stars are shown to be different. This revised version was published online in July 2006 with corrections to the Cover Date.