Petrological and experimental evidence for differentiation of water-rich magmas beneath St. Kitts,Lesser Antilles

St. Kitts lies in the northern Lesser Antilles, a subduction-related intraoceanic volcanic arc known for its magmatic diversity and unusually abundant cognate xenoliths. We combine the geochemistry of xenoliths, melt inclusions and lavas with high pressure–temperature experiments to explore magma differentiation processes beneath St. Kitts. Lavas range from basalt to rhyolite, with predominant andesites and basaltic andesites. Xenoliths, dominated by calcic plagioclase and amphibole, typically in reaction relationship with pyroxenes and olivine, can be divided into plutonic and cumulate varieties based on mineral textures and compositions. Cumulate varieties, formed primarily by the accumulation of liquidus phases, comprise ensembles that represent instantaneous solid compositions from one or more magma batches; plutonic varieties have mineralogy and textures consistent with protracted solidification of magmatic mush. Mineral chemistry in lavas and xenoliths is subtly different. For example, plagioclase with unusually high anorthite content (An_≤100) occurs in some plutonic xenoliths, whereas the most calcic plagioclase in cumulate xenoliths and lavas are An₉₇ and An₉₅, respectively. Fluid-saturated, equilibrium crystallisation experiments were performed on a St. Kitts basaltic andesite, with three different fluid compositions (XH₂O = 1.0, 0.66 and 0.33) at 2.4 kbar, 950–1025 °C, and fO₂ = NNO ? 0.6 to NNO + 1.2 log units. Experiments reproduce lava liquid lines of descent and many xenolith assemblages, but fail to match xenolith and lava phenocryst mineral compositions, notably the very An-rich plagioclase. The strong positive correlation between experimentally determined plagioclase-melt Kd_Ca–Na and dissolved H₂O in the melt, together with the occurrence of Al-rich mafic lavas, suggests that parental magmas were water-rich (> 9 wt% H₂O) basaltic andesites that crystallised over a wide pressure range (1.5–6 kbar). Comparison of experimental and natural (lava, xenolith) mafic mineral composition reveals that whereas olivine in lavas is predominantly primocrysts precipitated at low-pressure, pyroxenes and spinel are predominantly xenocrysts formed by disaggregation of plutonic mushes. Overall, St. Kitts xenoliths and lavas testify to mid-crustal differentiation of low-MgO basalt and basaltic andesite magmas within a trans-crustal, magmatic mush system. Lower crustal ultramafic cumulates that relate parental low-MgO basalts to primary, mantle -derived melts are absent on St. Kitts.     

Nonequilibrium Processes in the Solar Corona,Transition Region,Flares, and Solar Wind <Emphasis Type="Italic">(Invited Review)</Emphasis>

We review the presence and signatures of the non-equilibrium processes, both non-Maxwellian distributions and non-equilibrium ionization, in the solar transition region, corona, solar wind, and flares. Basic properties of the non-Maxwellian distributions are described together with their influence on the heat flux as well as on the rates of individual collisional processes and the resulting optically thin synthetic spectra. Constraints on the presence of high-energy electrons from observations are reviewed, including positive detection of non-Maxwellian distributions in the solar corona, transition region, flares, and wind. Occurrence of non-equilibrium ionization is reviewed as well, especially in connection to hydrodynamic and generalized collisional-radiative modeling. Predicted spectroscopic signatures of non-equilibrium ionization depending on the assumed plasma conditions are summarized. Finally, we discuss the future remote-sensing instrumentation that can be used for the detection of these non-equilibrium phenomena in various spectral ranges.     

Narrow-band CCD photometry of giant H ii regions

We have obtained accurate CCD narrow-band Hβ and Hα photometry of giant H  ii regions (GEHRs) in M33, NGC 6822 and M101. Comparison with previous determinations of emission-line fluxes shows large discrepancies; their probable origins are discussed. Combining our new photometric data with global velocity dispersion ( σ ) derived from emission linewidths, we review the     relation. A re-analysis of the properties of the GEHRs included in our sample shows that age spread and the superposition of components in multiple regions introduce a considerable spread in the regression. Combining the information available in the literature regarding ages of the associated clusters, evolutionary footprints on the interstellar medium, and kinematical properties of the knots that build up the multiple GEHRs, we find that a subsample – which we refer to as young and single GEHRs – do follow a tight relation in the     plane.     

Secondary phase validation—Phase classification by polarization

A long-standing problem in operational seismology is that of reliable focal depth estimation. Standard analyst practice is to pick and identify a ‘phase’ in the P-coda. This picking will always produce a depth estimate but without any validation it cannot be trusted. In this article we ‘hunt’ for standard depth phases like pP, sP and/or PmP but unlike the analyst we use Bayes statistics for classifying the probability that polarization characteristics of pickings belong to one of the mentioned depth phases given preliminary epicenter information. In this regard we describe a general-purpose PC implementation of the Bayesian methodology that can deal with complex nonlinear models in a flexible way. The models are represented by a data-flow diagram that may be manipulated by the analyst through a graphical-programming environment. An analytic signal representation is used with the imaginary part being the Hilbert transform of the signal itself. The pickings are in terms of a plot of posterior probabilities as a function of time for pP, Sp or PmP being within the presumed azimuth and incident angle sectors for given preliminary epicenter locations. We have tested this novel focal depth estimation procedure on explosion and earthquake recordings from Cossack Ranger II stations in Karelia, NW Russia, and with encouraging results. For example, pickings deviating more than 5° off ‘true’ azimuth are rejected while Pn-incident angle estimate exhibit considerable scatter. A comprehensive test of our approach is not quite easy as recordings from so-called Ground Truth events are elusive.     

The Juchatengo complex: an upper-level ophiolite assemblage of late Paleozoic age in Oaxaca,southern Mexico

International Journal of Earth Sciences - The Juchatengo complex (JC) suite is located between the Proterozoic Oaxacan complex to the north and the Xolapa complex to the south, and was amalgamated...     

Contributions of terrestrial and GRACE data to the study of the secular geoid changes in North America

This paper tests and discusses different statistical methods for modelling secular rates of change of the geoid in North America. In particular, we use the method of principal component/empirical orthogonal functions (PC/EOF) analysis to model the geoid rates from Gravity Recovery and Climate Experiment (GRACE) satellite data. As demonstrated, the PC/EOF analysis is useful for studying the contributions from different signals (mainly residual hydrology signals and leakage effects) to the GRACE-derived geoid rates. The PC/EOF analysis leads to smaller geoid rates compared to the conventional least-squares fitting of a trend and annual and semi-annual cycles to the time series of the spherical harmonic coefficients. This is because we filter out particular spatiotemporal modes of the regional geoid changes.We apply the method of least-squares collocation with parameters to combine terrestrial data (GPS vertical velocities from the Canadian Base Network and terrestrial gravity rates from the Canadian Gravity Standardization Net) with the GRACE-derived vertical motion to obtain again the geoid rates. The combined model has a peak geoid rate of 1.4 mm/year in the southeastern area of Hudson Bay contrary to the GRACE-derived geoid rates that show a large peak of 1.6–1.7 mm/year west of Hudson Bay. We demonstrate that the terrestrial data, which have a longer time span than the GRACE data, are important for constraining the GRACE-derived secular signal in the areas that are well sampled by the data.     

The Afragola settlement near Vesuvius,Italy: The destruction and abandonment of a Bronze Age village revealed by archaeology,volcanology and rock-magnetism

Public works in progress in the Campanian plain north of Somma-Vesuvius recently encountered the remains of a prehistoric settlement close to the town of Afragola. Rescue excavations brought to light a Bronze Age village partially destroyed and buried by pyroclastic density currents (PDCs) of the Vesuvian Pomici di Avellino eruption (3.8 ¹⁴C ka BP) and subsequently sealed by alluvial deposits. Volcanological and rock-magnetic investigations supplemented the excavations.Careful comparison between volcanological and archaeological stratigraphies led to an understanding of the timing of the damage the buildings suffered when they were struck by a series of PDCs. The first engulfed the village, located some 14 km to the north of the inferred vent, and penetrated into the dwellings without causing major damage. The buildings were able to withstand the weak dynamic pressure of the currents and deviate their path, as shown by the magnetic fabric analyses. Some later collapsed under the load of the deposits piled up by successive currents. Stepwise demagnetization of the thermal remanent magnetization (TRM) carried by potsherds embedded in the deposits yields deposition temperatures in the order of 260–320 °C, fully consistent with those derived from pottery and lithic fragments from other distal and proximal sites. The fairly uniform temperature of the deposits is here ascribed to the lack of pervasive air entrainment into the currents. This, in turn, resulted from the lack of major topographical obstacles along the flat plain.The coupling of structural damage and sedimentological analyses indicates that the currents were not destructive in the Afragola area, but TRM data indicate they were still hot enough to cause death or severe injury to humans and animals. The successful escape of the entire population is apparent from the lack of human remains and from thousands of human footprints on the surface of the deposits left by the first PDCs. People were thus able to walk barefoot across the already emplaced deposits and escape the subsequent PDCs. The rapid cooling of the deposits was probably due to both their thinness and heat dissipation due to condensation of water vapour released in the mixture by magma–water interaction.     

Recent geomorphological changes of the middle and lower Calore River (Campania, Southern Italy)

The geomorphological changes experienced by the middle and lower Calore River (Southern Italy) between 1957 and 1998 were investigated. Data derived from field surveys and interpretation of topographic maps and aerial photos were introduced into a geographic information system (GIS) and processed. The results showed that the Calore River underwent a mean narrowing of 66 %, with a peak of 86 %. The channel length increased by approximately 75 m and the sinuosity from 1.311 to 1.314. The extension of fluvial bars reduced by more than 83 %, while their number increased from 151 to 381. Field evidence of riverbed lowering, such as river terraces formed in the considered time span and exhumation of foundations of bridges and flood-walls, were also constantly detected. Due to these channel adjustments, the Calore River morphology changed from transitional to single-thread. These results were coherent with those reported in the pre-existing literature about channel adjustments experienced by many rivers during the twentieth century. They all were explainable with a reduction of the bedload transport; this latter, in turn, is completely in accordance with the environmental changes that affected the Calore River system in the considered period (i.e., damming and/or channelization of the main tributaries, reduction of liquid discharge due to water withdrawals and sediment mining from the riverbed).