Time-dependent uptake of NO3 by sea salt

Using a coated-insert flow tube reactor coupled to a low-energy electron-impact mass spectrometer with molecular beam sampling, we studied uptake of NO₃ by sea salt at room temperature and [NO₃]?=?8?10¹¹???4?10¹³ molecule cm^?3. The radical uptake coefficient γ(t) is time dependent: its initial value (γ _ini) decreases exponentially with the characteristic time (τ) to its steady-state value (γ _ss) at given [NO₃]. The parameters γ _ini, γ _ss and τ depend on [NO₃], whereas γ _ss is water vapor independent at [H₂O]?=?8?10¹²???1.6?10¹⁵ molecule cm^?3 and RH ≤ 0.5 %. HCl and NO₂ are uptake products detected in the gas phase. We used these findings to estimate γ values under tropospheric conditions for urban coastal and remote marine environments: at high NO₃ (~90 ppt), the time dependence becomes important, and the γ value averaged over the aerosol lifetime is 4?10^?3; at low NO₃ (~1 ppt), the radical uptake is time independent and proceeds faster with γ _ini?=?8?10^?3     

Recent geomorphological changes of the middle and lower Calore River (Campania, Southern Italy)

The geomorphological changes experienced by the middle and lower Calore River (Southern Italy) between 1957 and 1998 were investigated. Data derived from field surveys and interpretation of topographic maps and aerial photos were introduced into a geographic information system (GIS) and processed. The results showed that the Calore River underwent a mean narrowing of 66 %, with a peak of 86 %. The channel length increased by approximately 75 m and the sinuosity from 1.311 to 1.314. The extension of fluvial bars reduced by more than 83 %, while their number increased from 151 to 381. Field evidence of riverbed lowering, such as river terraces formed in the considered time span and exhumation of foundations of bridges and flood-walls, were also constantly detected. Due to these channel adjustments, the Calore River morphology changed from transitional to single-thread. These results were coherent with those reported in the pre-existing literature about channel adjustments experienced by many rivers during the twentieth century. They all were explainable with a reduction of the bedload transport; this latter, in turn, is completely in accordance with the environmental changes that affected the Calore River system in the considered period (i.e., damming and/or channelization of the main tributaries, reduction of liquid discharge due to water withdrawals and sediment mining from the riverbed).     

Stellar populations in the nuclear regions of nearby radio galaxies

We present optical spectra of the nuclei of seven luminous ( P _178 MHz≳10²⁵ W Hz⁻¹ Sr⁻¹) nearby ( z <0.08) radio galaxies, which mostly correspond to the FR II class. In two cases, Hydra A and 3C 285, the Balmer and λ 4000-Å break indices constrain the spectral types and luminosity classes of the stars involved, revealing that the blue spectra are dominated by blue supergiant and/or giant stars. The ages derived for the last burst of star formation in Hydra A are between 7 and 40 Myr, and in 3C 285 about 10 Myr. The rest of the narrow-line radio galaxies (four) have a λ 4000-Å break and metallic indices consistent with those of elliptical galaxies. The only broad-line radio galaxy in our sample, 3C 382, has a strong featureless blue continuum and broad emission lines that dilute the underlying blue stellar spectra. We are able to detect the Ca  ii triplet in absorption in the seven objects, with good quality data for only four of them. The strengths of the absorptions are similar to those found in normal elliptical galaxies, but these values are consistent both with stellar populations of roughly similar ages (as derived from the Balmer absorption and break strengths) and with mixed young+old populations.     

Total mercury in terrestrial systems (air-soil-plant-water) at the mining region of San Joaquín,Queretaro, Mexico

Deficient management of cinnabar mining left the San Joaquín region with high concentrations of mercury in its soils (2.4 – 4164 mg kg^-1). Numerous cinnabar mines have contributed to the dispersion of mercury into agricultural (0.5 –314 mg kg^-1) and forest (0.2 – 69 mg kg^-1) soils. Sediments are a natural means of transportation for mercury, causing its spreading, especially in areas near mine entrances (0.6 – 687 mg kg^-1). The nearness of maize crops to mines favors mercury accumulation in the different plant structures, such as roots, stems, leaves, and grain (0.04 – 8.2 mg kg^-1); these being related to mercury volatilization and accumulation in soils. Mercury vapor present in the settlements could indicate a constant volatilization from lands and soils (22 – 153 ng m^-3). The mercury levels found in the soils, in maize grain, and in the air resulted greater than the standards reported by the Official Mexican Norm (NOM) and the World Health Organization (WHO). Mercury in rainwater is due mainly to the presence of suspended atmospheric particles, later deposited on the surface (1.5 – 339 μg |^-1). Mercury dissolution was found in the drinking water (10 – 170 ng |^-1), with concentrations below those established by the NOM and the WHO. The contamination existing in the San Joaquín region does not reach the levels of the world’s greatest mercury producers: Almaden (Spain) and Idrija (Slovenia). It is, however, like that found in other important second degree world producers such as Guizhou (China). The population of San Joaquín, as well as its surrounding environment, are constantly exposed to mercury contamination, thus making a long term monitoring necessary to determine its effects, especially to people.     

Long Term Evolution of Solar Meridional Circulation and Phase Synchronization Viewed Through a Symmetrical Kuramoto Model

The solar-cycle oscillations of the toroidal and poloidal components of the solar magnetic field in the northern solar hemisphere have a persistent phase difference of about \(\pi \). We propose a symmetrical Kuramoto model with three coupled oscillators as a simple way to understand this anti-synchronization. We solve an inverse problem and reconstruct natural frequencies of the top and bottom oscillators under the conditions of a constant coupling strength and a non-delayed coupling. These natural frequencies are associated with angular velocities of the meridional flow circulation near the solar surface and in the deep layer of the solar convection zone. A relationship between our reconstructions of the shallow and the deep meridional flow speed during recent Solar Cycles 21?–?23 is in agreement with estimates obtained in helioseismology and flux-transport dynamo modeling. The reconstructed top oscillator speed presents significant solar-cycle like variations that agree with recent helioseismical reconstructions. The evolution of reconstructed natural frequencies strongly depends on the coupling strength. We find two stable regimes in the case of strong coupling with a change of regime during anomalous solar cycles. We see the onset of a new transition in Solar Cycle 24. We estimate the admitted range of coupling values and find evidence of cross-equatorial coupling between solar hemispheres not accounted for by the model.     

Using ocean quahog (<Emphasis Type="Italic">Arctica islandica</Emphasis>) shells to reconstruct palaeoenvironment in Öresund,Kattegat and Skagerrak,Sweden

Shells of Arctica islandica collected between 1884 and 2004 from Öresund, Kattegat and Skagerrak (Swedish West Coast) were used to monitor local climate variations and the influence of human activities on the local environment. For this purpose, we analysed the growth, structure and chemical composition of these shells and compared them with shells collected from Kiel Bay, Norway and Iceland. The growth rate of the studied shells registers an NAO periodicity of ca 8 years. However, the observed signal is weak because of other environmental interferences that are either of natural or anthropogenic origin. For example, the oxygen isotope ratios show temperature fluctuation, but also the influx of low salinity water. Higher contents of S, N, Cu, Zn, As, Cd and P in shell portions formed during the last century are related to human activities such as mining and industrial development. Our study indicates that in order to use Arctica shells as archives of climate change it is necessary to study the full range of environmental data that is recorded in the shells by using a multi element and isotope approach in combination with different analytical techniques including investigation of growth rates and shell structure.     

EOF analysis of a time series with application to tsunami detection

Fragments of deep-ocean tidal records up to 3 days long belong to the same functional sub-space, regardless of the record’s origin. The tidal sub-space basis can be derived via Empirical Orthogonal Function (EOF) analysis of a tidal record of a single buoy. Decomposition of a tsunami buoy record in a functional space of tidal EOFs presents an efficient tool for a short-term tidal forecast, as well as for an accurate tidal removal needed for early tsunami detection and quantification [Tolkova, E., 2009. Principal component analysis of tsunami buoy record: tide prediction and removal. Dyn. Atmos. Oceans 46 (1–4), 62–82] EOF analysis of a time series, however, assumes that the time series represents a stationary (in the weak sense) process. In the present work, a modification of one-dimensional EOF formalism not restricted to stationary processes is introduced. With this modification, the EOF-based de-tiding/forecasting technique can be interpreted in terms of a signal passage through a filter bank, which is unique for the sub-space spanned by the EOFs. This interpretation helps to identify a harmonic content of a continuous process whose fragments are decomposed by given EOFs. In particular, seven EOFs and a constant function are proved to decompose 1-day-long tidal fragments at any location. Filtering by projection into a reduced sub-space of the above EOFs is capable of isolating a tsunami wave within a few millimeter accuracy from the first minutes of the tsunami appearance on a tsunami buoy record, and is reliable in the presence of data gaps. EOFs with ∼$\sim$3-day duration (a reciprocal of either tidal band width) allow short-term (24.75 h in advance) tidal predictions using the inherent structure of a tidal signal. The predictions do not require any a priori knowledge of tidal processes at a particular location, except for recent 49.5 h long recordings at the location.     

Significance of vertical flux as a sink for surface water DMSP and as a source for the sediment surface in coastal zones of northern Europe

In April 1997 and 1998 the significance of sedimentation as a sink for epipelagic dimethylsulphoniopropionate (DMSP) production and as a source for marine sediments was reassessed using a newly designed sediment trap. The behaviour of the traps in immersion was monitored continuously and the collection efficiency was evaluated with ²³⁴Th measurements. Net DMS(P) fluxes were corrected for some physical and biological losses during the whole sedimentation process providing reliable estimates of gross DMSP fluxes. It is shown that daily losses by sedimentation account for between 0.1% and 16% of seawater particulate DMSP (DMSPp) standing stocks, and between 3% and 75% of daily DMSPp production. In the Malangen fjord we observed temporal increases of DMSP production and standing stocks which resulted also in increases of DMSP vertical fluxes and DMS(P) concentrations at the sediment surface. This result illustrates how tight the coupling can be between pelagos and benthos, and confirms that DMS(P) concentration in the sediment was a reliable diagnostic indicator of vertical export from overlying waters in Malangen fjord. In Ullsfjord, however, DMS(P) concentrations in the sediment were poorly indicators of Phaeocystis pouchetii export during the early stage of growth of a bloom. The high load of DMS(P) in Balsfjord's sediments could neither be attributed to local vertical sedimentation nor to short-term lateral advection of fresh DMSP-containing phytoplanktonic material, and provides indication that this tracer sometimes also can be misleading. The highest loads of DMS(P) in sediments and the fastest rates of sedimentation occurred in the Southern Bight of the North Sea.     

Petrological and experimental evidence for differentiation of water-rich magmas beneath St. Kitts,Lesser Antilles

St. Kitts lies in the northern Lesser Antilles, a subduction-related intraoceanic volcanic arc known for its magmatic diversity and unusually abundant cognate xenoliths. We combine the geochemistry of xenoliths, melt inclusions and lavas with high pressure–temperature experiments to explore magma differentiation processes beneath St. Kitts. Lavas range from basalt to rhyolite, with predominant andesites and basaltic andesites. Xenoliths, dominated by calcic plagioclase and amphibole, typically in reaction relationship with pyroxenes and olivine, can be divided into plutonic and cumulate varieties based on mineral textures and compositions. Cumulate varieties, formed primarily by the accumulation of liquidus phases, comprise ensembles that represent instantaneous solid compositions from one or more magma batches; plutonic varieties have mineralogy and textures consistent with protracted solidification of magmatic mush. Mineral chemistry in lavas and xenoliths is subtly different. For example, plagioclase with unusually high anorthite content (An_≤100) occurs in some plutonic xenoliths, whereas the most calcic plagioclase in cumulate xenoliths and lavas are An₉₇ and An₉₅, respectively. Fluid-saturated, equilibrium crystallisation experiments were performed on a St. Kitts basaltic andesite, with three different fluid compositions (XH₂O = 1.0, 0.66 and 0.33) at 2.4 kbar, 950–1025 °C, and fO₂ = NNO ? 0.6 to NNO + 1.2 log units. Experiments reproduce lava liquid lines of descent and many xenolith assemblages, but fail to match xenolith and lava phenocryst mineral compositions, notably the very An-rich plagioclase. The strong positive correlation between experimentally determined plagioclase-melt Kd_Ca–Na and dissolved H₂O in the melt, together with the occurrence of Al-rich mafic lavas, suggests that parental magmas were water-rich (> 9 wt% H₂O) basaltic andesites that crystallised over a wide pressure range (1.5–6 kbar). Comparison of experimental and natural (lava, xenolith) mafic mineral composition reveals that whereas olivine in lavas is predominantly primocrysts precipitated at low-pressure, pyroxenes and spinel are predominantly xenocrysts formed by disaggregation of plutonic mushes. Overall, St. Kitts xenoliths and lavas testify to mid-crustal differentiation of low-MgO basalt and basaltic andesite magmas within a trans-crustal, magmatic mush system. Lower crustal ultramafic cumulates that relate parental low-MgO basalts to primary, mantle -derived melts are absent on St. Kitts.     

Grain boundary and volume diffusion experiments in yttrium aluminium garnet bicrystals at 1,723 K: a miniaturized study

Yb-Y inter-diffusion along a single grain boundary of a synthetic yttrium aluminium garnet (YAG) bicrystal has been studied using analytical transmission electron microscopy (ATEM). To investigate the diffusion, a thin-film containing Yb as the diffusant was deposited perpendicular to the bicrystal grain boundary by pulsed laser deposition (PLD). Structural properties and their change with time in both the diffusant source and the grain boundary are reported. The diffusion profiles are incorporated in a numerical diffusion model, which is applied to determine the grain boundary diffusion coefficient, D _gb , at 1.723 K it is equal to 3 × 10⁻¹⁵ m²/s. We find that grain boundary diffusion is 4.85 orders of magnitude faster than volume diffusion, which was determined from the same diffusion experiment. This result is discussed in the context of special versus general grain boundaries. Finally, we successfully tested the capability of synchrotron-based nano-X-ray fluorescence analysis to map micro-chemical patterns in two dimensions with sub-micrometre resolution.