Dielectric constant estimation of the uppermost Basal Unit layer in the martian Boreales Scopuli region

An electromagnetic inversion model has been applied to echoes from the subsurface sounding Shallow Radar (SHARAD) to retrieve the dielectric properties of the uppermost Basal Unit (BU) beneath the North Polar Layered Deposits of Mars. SHARAD data have been carefully selected to satisfy the assumption of the inversion model which requires a stratigraphy consisting of mostly plane parallel layers. The resulting values of the dielectric constant have been interpreted in terms of a variable percentage of dust in an ice–dust mixture through the use of a mixing model for dielectric properties. The resulting dust content exceeds 65%, reaching perhaps 95%, depending on the permittivity values assumed for the dust. Such a concentration is higher than that obtained by Selvans et al. (Selvans, M.M., Plaut, J.J., Aharonson, O. [2010]. J. Geophys. Res, 115, E09003). This discrepancy could be justified considering that our observations refer to the uppermost BU layer, whereas Selvans et al. (Selvans, M.M., Plaut, J.J., Aharonson, O. [2010]. J. Geophys. Res, 115, E09003) probed the BU full thickness. Moreover, if the BU is considered spatially inhomogeneous, with very different dust content and thickness (Tanaka, K.L., Skinner, J.A., Fortezzo, C.M., Herkenhoff, K.E., Rodriguez, J.A.P., Bourke, M.C., Kolb, E.J., Okubo, C.H. [2008]. Icarus, 196, 318–358), the discrepancy could be furtherly reconciled.     

Analysis of the goodness of empirical approaches in predicting explosive detonation parameters

Goodness of empirical models for predicting explosive detonation velocity and pressure was analysed using 3 databases consisting of experimental velocity and pressure measurements for different explosives. The first database was used to estimate experimental errors for detonation velocity and pressure measurements. The second database was used to compare residuals obtained by the experimental models and by various thermochemical codes. Finally, the third database, consisting of some 600 data on 130 explosive substances, was used to estimate residual bias and dispersion resulting from the application of the experimental models. Also analysed was model coherence with the ideal detonation theory. Our main conclusion is that all the models introduce bias in their predictions depending on the density and oxygen balance values of the explosive. Of those analysed, the Xiong model was notable for its good results, with residual dispersion comparable to that obtained from application of the best thermochemical codes. Our results would indicate that the Xiong model is the only model that may be compatible with the ideal detonation theory. The pressure equation derived from the ideal detonation theory and calibrated with experimental data had excellent predictive capacity.     

δ53Cr values of catchment runoff exhibit seasonality regardless of bedrock Cr concentrations: Role of periodically changing chromium export fluxes

One pre-requisite for the construction of a global chromium isotope mass balance is detailed understanding of Cr isotope systematics in the critical zone where redox-processes can modify the isotope signature of geogenic Cr input into the hydrosphere. A Cr isotope inventory of bedrock, soil, and runoff was performed in a Central European headwater catchment underlain by amphibolite, situated in the vicinity of two previously studied catchments underlain by different bedrock types (serpentinite and leucogranite). Fresh bedrock in the amphibolite catchment NAZ contained ~300 mg/kg Cr, serpentinite at PLB contained ~800 mg/kg Cr, and leucogranite at LYS contained ~2 mg/kg Cr. Monthly hydrochemical monitoring at all three sites revealed higher Cr(VI) export fluxes in winter than in summer. NAZ was characterized by a distinct seasonality in the δ⁵³Cr values, with minima during winter/spring snowmelts (−0.35‰) and maxima during dry summers (0.40‰). Similar seasonality in δ⁵³Cr values had been reported from PLB and LYS. Bedrock at all three sites had similar Cr isotope composition close to −0.10‰, a value indistinguishable from the δ⁵³Cr value of bulk silicate Earth (BSE). Positive mean δ⁵³Cr value of NAZ runoff indicated Cr-isotope fractionations during weathering of geogenic Cr(III), combined with adsorption of the resulting Cr(VI) on soil particles during pedogenesis. However, the mass-weighted mean δ⁵³Cr of NAZ runoff was lower (−0.08‰), indistinguishable from the Cr isotope signature of bedrock. The same pattern of lower mass-weighted mean δ⁵³Cr values of runoff, compared to arithmetic mean δ⁵³Cr values of runoff, were observed also at PLB and LYS. We suggest that elevated Cr runoff fluxes in winter remove some of the residual isotopically light Cr that accumulated in the soil during summer. Seasonality in runoff δ⁵³Cr values appears to be a relatively widespread phenomenon, de-coupled from Cr availability for chemical weathering.     

Imposex levels and concentrations of organotin compounds (TBT and its metabolites) in Nassarius nitidus from the Lagoon of Venice

Specimens of Nassarius nitidus were collected in seven stations of the Venice Lagoon to assess the levels of tributyltin (TBT) and its metabolites monobutyltin and dibutyltin in the tissues and monitor their effect on organisms, in particular the phenomenon of imposex (superimposition of male sexual characteristics on females). The following values of population indices were found: vas deferens sequence: 1.2 ± 0.7–4.0 ± 0.5; relative penis length: 6–47%. The least impacted station was situated in the northern part of the Lagoon, where females without imposex were found and Butyltin (BuTs) concentrations in the organisms (average sum of BuTs = 43 ± 14 ng Sn g⁻¹ w.) were significantly lower than in the other stations (range of average sum of BuTs: 101 ± 22–217 ± 27 ng Sn g⁻¹ d.w.). Population indices were found to be related to the TBT content in the tissues. In particular VDSI had a significant logarithmic correlation: r = 0.95, n = 8, p < 0.05.     

Shallow water tidal currents in close proximity to the seafloor and boundary-induced turbulence

Velocity measurements with vertical resolution 0.02 m were conducted in the lowest 0.5 m of the water column using acoustic Doppler current profiler (ADCP) at a test site in the western part of the East China Sea. The friction velocity u _* and the turbulent kinetic energy dissipation rate ε _wl(ζ) profiles were calculated using log-layer fits; ζ is the height above the bottom. During a semidiurnal tidal cycle, u _* was found to vary in the range (1–7) × 10⁻³ m/s. The law-of-the-wall dissipation profiles ε _wl(ζ) were consistent with the dissipation profiles ε _mc(ζ) evaluated using independent microstructure measurements of small-scale shear, except in the presence of westward currents. It was hypothesized that an isolated bathymetric rise (25 m height at a 50-m seafloor) located to the east of the measurement site is responsible for the latter. Calculation of the depth integrated internal tide generating body force in the region showed that the flanks of the rise are hotspots of internal wave energy that may locally produce a significant turbulent zone while emitting tidal and shorter nonlinear internal waves. This distant topographic source of turbulence may enhance the microstructure-based dissipation levels ε _mc(ζ) in the bottom boundary layer (BBL) beyond the dissipation ε _wl(ζ) associated with purely locally generated turbulence by skin currents. Semi-empirical estimates for dissipation at a distance from the bathymetric rise agree well with the BBL values of ε _mc measured 15 km upslope.     

Imposex levels and concentrations of organotin compounds (TBT and its metabolites) in Nassarius nitidus from the Lagoon of Venice

Specimens of Nassarius nitidus were collected in seven stations of the Venice Lagoon to assess the levels of tributyltin (TBT) and its metabolites monobutyltin and dibutyltin in the tissues and monitor their effect on organisms, in particular the phenomenon of imposex (superimposition of male sexual characteristics on females). The following values of population indices were found: vas deferens sequence: 1.2+/-0.7-4.0+/-0.5; relative penis length: 6-47%. The least impacted station was situated in the northern part of the Lagoon, where females without imposex were found and Butyltin (BuTs) concentrations in the organisms (average sum of BuTs=43+/-14 ngSng(-1)w.) were significantly lower than in the other stations (range of average sum of BuTs: 101+/-22-217+/-27 ngSng(-1)d.w.). Population indices were found to be related to the TBT content in the tissues. In particular VDSI had a significant logarithmic correlation: r=0.95, n=8, p<0.05.     

Probabilistic assessment of structural operational efficiency in emergency limit conditions: the I.OPà.CLE method

One major issue in the aftermath of a strong earthquake is the emergency management, which cannot be guaranteed if the physical components necessary for the operability of the contingency plan are either damaged, unusable or inaccessible. In order to assess the physical efficiency of the emergency system on which a contingency plan is based, the I.OPà.CLE method (Indices for evaluation of the Operational efficiency of Limit Condition Emergency) has been set up by the Italian Civil Protection Department. It is basically aimed at supporting civil protection decision makers in evaluating emergency systems and establishing strategies and priorities concerning strengthening interventions at national, regional or municipality level. The method must be potentially applied to any of the around 8000 municipalities all over Italy, and then it must refer to a minimum information dataset readily available for any municipality. Therefore, I.OPà.CLE has been specifically tailored for the minimum standard information that is provided by the analysis of Limit Condition for Emergency, as formulated in 2012 by the Italian Civil Protection Department. This analysis defines the standard framework of the physical layout of a municipal seismic emergency plan, relying on a limited number of information. Notwithstanding the numerically extensive target and limited amount of information available, the ambition of I.OPà.CLE is to perform simplified analyses without renouncing to rigor in the methodology. The present paper illustrates the analytic formulation of I.OPà.CLE and its capabilities, as well as two real examples. In the conclusion, future upgrading of the model are discussed, even in relation to the availability of further pieces of information.     

Correlations between fatty acid composition of seston and zooplankton and effects of environmental parameters in a eutrophic Siberian reservoir

During two sampling seasons we analyzed on weekly basis fatty acid (FA) composition of seston fraction <130 μm and zooplankton fraction >130 μm, and compared them using a multivariate canonical correlation analysis (CCA). Besides, we evaluated a possible impact of water temperature and inorganic nutrients on FA composition of the seston and the zooplankton.In spite of significant differences in percentages of several individual FAs, we found very strong canonical correlation (cross-correlation, 1-week lag) between FA composition of the seston and the zooplankton. The most important factor, providing the overall canonical cross-correlation between FA profiles of the seston and the zooplankton fractions was eicosapentaenoic acid (20:5ω3, EPA). FA composition of the zooplankton fraction had comparatively poor correlations with taxonomic composition of the zooplankton. Thus, seasonal variations of FA composition of the zooplankton were determined primarily by seasonal changes in FA composition of the seston, rather than by taxonomic differences of FA profiles between rotifers, cyclopoids and cladocerans. FA composition of the seston was strongly affected by its taxonomic composition, namely by that of phytoplankton. According to CCA, the highest factor loadings pertained to diatoms interacting with their marker acids, including EPA, and cyanobacteria and greens, interacting with their marker acids. Ciliates and small rotifers composed considerable and sometimes major part of the seston biomass, but according to CCA their contributions to seasonal variations of the total FA profile of the seston were insignificant. This finding indirectly support the conclusion of the other authors, that the main source of FAs presented in ciliates and rotifers must be sought in algae and that they do not modify FA composition of food consumed, apart from repackaging it.Water temperature was the principal environmental parameter which drove the overall variations of FA composition. Factor loadings for the inorganic nutrients were comparatively negligible. The main contribution in the seasonal variation of FA composition of the seston was given by negative interaction between water temperature and percentage of EPA in the seston.