Time-dependent uptake of NO3 by sea salt

Using a coated-insert flow tube reactor coupled to a low-energy electron-impact mass spectrometer with molecular beam sampling, we studied uptake of NO₃ by sea salt at room temperature and [NO₃]?=?8?10¹¹???4?10¹³ molecule cm^?3. The radical uptake coefficient γ(t) is time dependent: its initial value (γ _ini) decreases exponentially with the characteristic time (τ) to its steady-state value (γ _ss) at given [NO₃]. The parameters γ _ini, γ _ss and τ depend on [NO₃], whereas γ _ss is water vapor independent at [H₂O]?=?8?10¹²???1.6?10¹⁵ molecule cm^?3 and RH ≤ 0.5 %. HCl and NO₂ are uptake products detected in the gas phase. We used these findings to estimate γ values under tropospheric conditions for urban coastal and remote marine environments: at high NO₃ (~90 ppt), the time dependence becomes important, and the γ value averaged over the aerosol lifetime is 4?10^?3; at low NO₃ (~1 ppt), the radical uptake is time independent and proceeds faster with γ _ini?=?8?10^?3     

Study of Local Seismic Events in Lithuania and Adjacent Areas Using Data from the PASSEQ Experiment

The territory of Lithuania and adjacent areas of the East European Craton have always been considered a region of low seismicity. Two recent earthquakes with magnitudes of more than 5 in the Kaliningrad District (Russian Federation) on 21 September 2004 motivated re-evaluation of the seismic hazard in Lithuania and adjacent territories. A new opportunity to study seismicity in the region is provided by the PASSEQ (Pasive Seismic Experiment) project that aimed to study the lithosphere–asthenosphere structure around the Trans-European Suture Zone. Twenty-six seismic stations of the PASSEQ temporary seismic array were installed in the territory of Lithuania. The stations recorded a number of local and regional seismic events originating from Lithuania and adjacent areas. This data can be used to answer the question of whether there exist seismically active tectonic zones in Lithuania that could be potentially hazardous for critical industrial facilities. Therefore, the aim of this paper is to find any natural tectonic seismic events in Lithuania and to obtain more general view of seismicity in the region. In order to do this, we make a manual review of the continuous data recorded by the PASSEQ seismic stations in Lithuania. From the good quality data, we select and relocate 45 local seismic events using the well-known LocSAT and VELEST location algortithms. In order to discriminate between possible natural events, underwater explosions and on-shore blasts, we analyse spatial distribution of epicenters and temporal distribution of origin times and perform both visual analysis of waveforms and spectral analysis of recordings. We show that the relocated seismic events can be grouped into five clusters (groups) according to their epicenter coordinates and origin and that several seismic events might be of tectonic origin. We also show that several events from the off-shore region in the Baltic Sea (at the coasts of the Kaliningrad District of the Russian Federation) are non-volcanic tremors, although the origin of these tremor-type events is not clear.     

Granitic magmatism,basement ages,and provenance indicators in the Malay Peninsula: Insights from detrital zircon U–Pb and Hf-isotope data

The Malay Peninsula lies on two continental blocks, Sibumasu and East Malaya, which are intruded by granitoids in two provinces: the Main Range and Eastern. Previous models propose that Permian–Triassic granitoids are subduction-related and syn-to post-collisional. We present 752 U–Pb analyses that were carried out on zircons from river sands in the Malay Peninsula; of these, 243 grains were selected for Hf-isotope analyses. Our data suggest a more complex Sibumasu–East Malaya collision history. ¹⁷⁶Hf/¹⁷⁷Hf_i ratios reveal that Permian–Triassic zircons were sourced from three magmatic suites: (a) Permian crustally-derived granitoids, (b) Early-Middle Triassic granitoids with mixed mantle–crust sources, and (c) Late Triassic crustally-derived granitoids. This suggests three Permian–Triassic episodes of magmatism in the Malay Peninsula, two of which occurred in the Eastern Province. Although the exact timing of the Sibumasu–East Malaya collision remains unresolved, current data suggest that it occurred before the Late Triassic, probably in Late Permian–Early Triassic. Our data also indicate that Sibumasu and East Malaya basements are chronologically heterogeneous, but predominantly of Proterozoic age. Some basement may be Neoarchaean but there is no evidence for basement older than 2.8 Ga. Finally, we show that Hf-isotope signatures of Triassic zircons can be used as provenance indicators.     

Stellar populations in the nuclear regions of nearby radio galaxies

We present optical spectra of the nuclei of seven luminous ( P _178 MHz≳10²⁵ W Hz⁻¹ Sr⁻¹) nearby ( z <0.08) radio galaxies, which mostly correspond to the FR II class. In two cases, Hydra A and 3C 285, the Balmer and λ 4000-Å break indices constrain the spectral types and luminosity classes of the stars involved, revealing that the blue spectra are dominated by blue supergiant and/or giant stars. The ages derived for the last burst of star formation in Hydra A are between 7 and 40 Myr, and in 3C 285 about 10 Myr. The rest of the narrow-line radio galaxies (four) have a λ 4000-Å break and metallic indices consistent with those of elliptical galaxies. The only broad-line radio galaxy in our sample, 3C 382, has a strong featureless blue continuum and broad emission lines that dilute the underlying blue stellar spectra. We are able to detect the Ca  ii triplet in absorption in the seven objects, with good quality data for only four of them. The strengths of the absorptions are similar to those found in normal elliptical galaxies, but these values are consistent both with stellar populations of roughly similar ages (as derived from the Balmer absorption and break strengths) and with mixed young+old populations.     

Nonequilibrium Processes in the Solar Corona,Transition Region,Flares, and Solar Wind <Emphasis Type="Italic">(Invited Review)</Emphasis>

We review the presence and signatures of the non-equilibrium processes, both non-Maxwellian distributions and non-equilibrium ionization, in the solar transition region, corona, solar wind, and flares. Basic properties of the non-Maxwellian distributions are described together with their influence on the heat flux as well as on the rates of individual collisional processes and the resulting optically thin synthetic spectra. Constraints on the presence of high-energy electrons from observations are reviewed, including positive detection of non-Maxwellian distributions in the solar corona, transition region, flares, and wind. Occurrence of non-equilibrium ionization is reviewed as well, especially in connection to hydrodynamic and generalized collisional-radiative modeling. Predicted spectroscopic signatures of non-equilibrium ionization depending on the assumed plasma conditions are summarized. Finally, we discuss the future remote-sensing instrumentation that can be used for the detection of these non-equilibrium phenomena in various spectral ranges.     

Environmental and political implications of Vietnam's water vulnerabilities: A multiscale assessment

Vietnam's low‐lying areas of the Lower Mekong Basin are prone to floods, salt water inundation, and riparian competition with upstream neighbours. Vietnam's opening to the global economy, accompanied by industrialization and a rapidly growing population, impose multiscale (global, regional, local) stresses on urban and rural water systems resulting in water contamination and groundwater overdraft. Water vulnerability is a function of both natural and social hazards and depends on the scope of capital investment, political and ideological institutions, managerial capacity and governance. Water distribution and riparian ecosystem health are also hydropolitical issues related to dam‐building activity by Vietnam and its transboundary neighbours, Laos, Cambodia and particularly China, whose territory contains the source of the Mekong River. A multiscale assessment of Vietnam's interlinked water vulnerabilities indicates that the resilience of the country's social‐ecological water system rests on peaceful resolution of regional transboundary conflicts based on shared economic interests and on improved managerial practices of local authorities.     

The ionization balance of the Fe in the solar corona for a non-Maxwellian electron distribution function

The ionization equilibrium of the Fe in the solar corona for a non-Maxwellian electron distribution with an enhanced number of particles in the high-energy tail is presented. A parametric form of the distribution function is used to demonstrate the changes in the ionization equilibrium with changes in the shape of the distribution. The results over the range of temperature 10⁵ K T 10⁸ K for different deviations of the distribution from a Maxwellian are given in tabular form. The results can be used for specific applications in the solar corona, especially in the active corona, where deviations from the Maxwellian distribution can be significant.     

Slow and Fast Rotating Coronal Holes from Geomagnetic Indices

The evolution of the 27-day recurrence in the series of two solar indices (Wolf number WN and 10.7 cm radio flux F) and two geomagnetic indices (Dst and ζ, variance of the geomagnetic field recorded at a magnetic observatory) have been studied over the 1957 – 2007 time span. Spectral energies contained in two period domains (25 – 27.3 and 27.3 – 31 days), designated as E ₁ and E ₂, have been computed. Whereas the evolution of E ₁ is the same for the four indices, that of E ₂ is essentially different for WN and F on the one hand, Dst and ζ on the other hand. Some general conclusions on the dynamics of the solar outer layers are inferred from these results. First the solar activity, as measured by WN, and when averaged over a few years, evolves in the same way whatever the latitude. Second, two families of coronal holes (CHs) are identified; the rapidly and the slowly rotating CHs evolve quite differently.     

The results of geochronological and isotope–geochemical study of zircons from tuff of the Sylvitsa Group (western slope of the Middle Urals): The origin of ash layers in Vendian rocks of the East European Platform

Doklady Earth Sciences - New LA-ICP-MS data on the U–Pb isotope age, Hf isotope characteristics, and concentrations of trace elements in zircons from volcanic tuff of the Upper Vendian...