Numerical modeling of 3D fully nonlinear potential periodic waves

A simple and exact numerical scheme for long-term simulations of 3D potential fully nonlinear periodic gravity waves is suggested. The scheme is based on the surface-following nonorthogonal curvilinear coordinate system. Velocity potential is represented as a sum of analytical and nonlinear components. The Poisson equation for the nonlinear component of velocity potential is solved iteratively. Fourier transform method, the second-order accuracy approximation of vertical derivatives on a stretched vertical grid and the fourth-order Runge–Kutta time stepping are used. The scheme is validated by simulation of steep Stokes waves. A one-processor version of the model for PC allows us to simulate evolution of a wave field with thousands degrees of freedom for hundreds of wave periods. The scheme is designed for investigation of nonlinear 2D surface waves, generation of extreme waves, and direct calculations of nonlinear interactions.     

Hydrological and geochemical control of metals and arsenic in a Mediterranean river contaminated by acid mine drainage (the Amous River,France); preliminary assessment of impacts on fish (Leuciscus cephalus)

Dissolved and particulate concentrations of metals (Fe, Al, Mn, Co, Ni, Cu, Zn, Cd, Tl, Pb) and As were monitored over a 5 year period in the Amous River downstream of its confluence with a creek severely affected by acid mine drainage (AMD) originating from a former Pb–Zn mine. Water pH ranged from 6.5 to 8.8. Metals were predominantly in dissolved form, except Fe and Pb, which were in particulate form. In the particulate phase, metals were generally associated with Al oxides, whereas As was linked to Fe oxides. Metal concentrations in the dissolved and/or particulate phase were generally higher during the wet season due to higher generation of AMD. Average dissolved (size < 0.22 μm) metal concentrations (μg/L) were 1 ± 4 (Fe), 69 ± 49 (Al), 140 ± 118 (Mn), 4 ± 3 Co, 6 ± 4 (Ni), 1.3 ± 0.8 (Cu), 126 ± 81 (Zn), 1.1 ± 0.7 (Cd), 0.9 ± 0.5 (Tl), 2 ± 3 (Pb). Dissolved As concentrations ranged from 5 to 134 μg/L (30 ± 23 μg/L). During the survey, the concentration of colloidal metals (5 kDa < size < 0.22 μm) was less than 25% of dissolved concentrations. Dissolved metal concentrations were generally higher than the maximum concentrations allowed in European surface waters for priority substances (Ni, Cd and Pb) and higher than the environmental quality standards for other compounds. Using Diffusion Gradient in Thin Film (DGT) probes, metals were shown to be in potentially bioavailable form. The concentrations in Leuciscus cephalus were below the maximum Pb and Cd concentrations allowed in fish muscle for human consumption by the European Water Directive. Amongst the elements studied, only As, Pb and Tl were shown to bioaccumulate in liver tissue (As, Pb) or otoliths (Tl). Bioaccumulation of metals or As was not detected in muscle.     

A petrological and geochemical study on time-series samples from Klyuchevskoy volcano,Kamchatka arc

To understand the generation and evolution of mafic magmas from Klyuchevskoy volcano in the Kamchatka arc, which is one of the most active arc volcanoes on Earth, a petrological and geochemical study was carried out on time-series samples from the volcano. The eruptive products show significant variations in their whole-rock compositions (52.0–55.5 wt.% SiO₂), and they have been divided into high-Mg basalts and high-Al andesites. In the high-Mg basalts, lower-K and higher-K primitive samples (>9 wt.% MgO) are present, and their petrological features indicate that they may represent primary or near-primary magmas. Slab-derived fluids that induced generation of the lower-K basaltic magmas were less enriched in melt component than those associated with the higher-K basaltic magmas, and the fluids are likely to have been released from the subducting slab at shallower levels for the lower-K basaltic magmas than for higher-K basaltic magmas. Analyses using multicomponent thermodynamics indicates that the lower-K primary magma was generated by ~13% melting of a source mantle with ~0.7 wt.% H₂O at 1245–1260?°C and ~1.9 GPa. During most of the evolution of the volcano, the lower-K basaltic magmas were dominant; the higher-K primitive magma first appeared in AD 1932. In AD 1937–1938, both the lower-K and higher-K primitive magmas erupted, which implies that the two types of primary magmas were present simultaneously and independently beneath the volcano. The higher-K basaltic magmas evolved progressively into high-Al andesite magmas in a magma chamber in the middle crust from AD 1932 to ~AD 1960. Since then, relatively primitive magma has been injected continuously into the magma chamber, which has resulted in the systematic increase of the MgO contents of erupted materials with ages from ~AD 1960 to present.     

Experimental Investigation of Reinforced Soil Slopes in a Geotechnical Centrifuge,with the Use of Optical Fibre Sensors

The purpose of this experimental investigation is to obtain strain measurements via optical fibre sensors in the drum geotechnical centrifuge of ETH Zurich. It is part of a test series with main goal to study the behaviour of reinforced slopes subjected to self weight loading and subsequently to an impact from a rockfall event. In total 13 scaled reinforced slope models were built with a height of 180 mm and a slope inclination of 2V:1H, optimising the materials used and the different ways of model making. The maximum g-levels were 50 and 100 g and the impact loading was applied at 50 g. The optical fibre sensors were placed on various layers of the reinforcement and at different positions. Strain measurements that were recorded during different tests are logical and expected, demonstrating that optical fibre sensors can successfully be used for measuring linear strain on reinforcement layers that are tested under enhanced gravity in the geotechnical centrifuge. The experimental set up as well as the opportunities and challenges of these measurements are presented and discussed. Finally, correspondent prototype numerical models were created and analysed and the results of this analysis are compared to the corresponding experimental ones.     

Correlations between fatty acid composition of seston and zooplankton and effects of environmental parameters in a eutrophic Siberian reservoir

During two sampling seasons we analyzed on weekly basis fatty acid (FA) composition of seston fraction <130 μm and zooplankton fraction >130 μm, and compared them using a multivariate canonical correlation analysis (CCA). Besides, we evaluated a possible impact of water temperature and inorganic nutrients on FA composition of the seston and the zooplankton.In spite of significant differences in percentages of several individual FAs, we found very strong canonical correlation (cross-correlation, 1-week lag) between FA composition of the seston and the zooplankton. The most important factor, providing the overall canonical cross-correlation between FA profiles of the seston and the zooplankton fractions was eicosapentaenoic acid (20:5ω3, EPA). FA composition of the zooplankton fraction had comparatively poor correlations with taxonomic composition of the zooplankton. Thus, seasonal variations of FA composition of the zooplankton were determined primarily by seasonal changes in FA composition of the seston, rather than by taxonomic differences of FA profiles between rotifers, cyclopoids and cladocerans. FA composition of the seston was strongly affected by its taxonomic composition, namely by that of phytoplankton. According to CCA, the highest factor loadings pertained to diatoms interacting with their marker acids, including EPA, and cyanobacteria and greens, interacting with their marker acids. Ciliates and small rotifers composed considerable and sometimes major part of the seston biomass, but according to CCA their contributions to seasonal variations of the total FA profile of the seston were insignificant. This finding indirectly support the conclusion of the other authors, that the main source of FAs presented in ciliates and rotifers must be sought in algae and that they do not modify FA composition of food consumed, apart from repackaging it.Water temperature was the principal environmental parameter which drove the overall variations of FA composition. Factor loadings for the inorganic nutrients were comparatively negligible. The main contribution in the seasonal variation of FA composition of the seston was given by negative interaction between water temperature and percentage of EPA in the seston.     

Evidence for xenolith–host basalt interaction from chemical patterns in Fe–Ti-oxides from mafic granulite xenoliths of the Bakony–Balaton Volcanic field (W-Hungary)

We investigate the effects of xenolith–host basalt interaction on lower crustal mafic granulite xenoliths from the Central Pannonian Basin. The xenoliths are devoid of any signs of melting, nevertheless various phenomena are identified, which indicate that the original mineralogy and chemistry of the xenoliths was modified during interaction with the host basalt. The rock-forming silicates are only slightly affected by alteration, but the Fe–Ti-oxides are overprinted to a significant extent. Complex chemical zoning patterns are detected using high-resolution element mapping in ilmenites and in lamellar titanomagnetite–ilmenite intergrowths. The chemical alteration of the Fe–Ti-oxides was diffusion-controlled and, hence, time and temperature dependent. On the basis of diffusion profiles in titanomagnetite we estimate the duration of xenolith–host basalt interaction to be at least 9–20 h. This is comparable to the time necessary for the ascent of the host basalt to the surface. It is too short to reflect alteration during granulite facies metamorphism in the deep crust. The chemical alteration of the titanomagnetite thus reflects the total duration of the xenolith–host basalt interaction.     

Precision abundance analysis of bright H ii galaxies

We present high signal-to-noise ratio spectrophotometric observations of seven luminous H  ii galaxies. The observations have been made with the use of a double-arm spectrograph which provides spectra with a wide wavelength coverage, from 3400 to 10 400 Å free of second-order effects, of exactly the same region as that of a given galaxy. These observations are analysed applying a methodology designed to obtain accurate elemental abundances of oxygen, sulphur, nitrogen, neon, argon and iron in the ionized gas. Four electron temperatures and one electron density are derived from the observed forbidden line ratios using the five-level atom approximation. For our best objects, errors of 1 per cent in t _e([O  iii ]), 3 per cent in t _e([O  ii ]) and 5 per cent in t _e([S  iii ]) are achieved with a resulting accuracy of 7 per cent in total oxygen abundances, O/H.
The ionization structure of the nebulae can be mapped by the theoretical oxygen and sulphur ionic ratios, on the one side, and the corresponding observed emission line ratios, on the other – the η and η' plots. The combination of both is shown to provide a means to test photoionization model sequences presently applied to derive elemental abundances in H  ii galaxies.     

Is the Linné impact crater morphology influenced by the rheological layering on the Moon's surface? Insights from numerical modeling

Linné is a simple crater, with a diameter of 2.23 km and a depth of 0.52 km, located in northwestern Mare Serenitatis. Recent high‐resolution data acquired by the Lunar Reconnaissance Orbiter Camera revealed that the shape of this impact structure is best described by an inverted truncated‐cone. We perform morphometric measurements, including slope and profile curvature, on the Digital Terrain Model of Linné, finding the possible presence of three subtle topographic steps, at the elevation of +20, ?100, and ?200 m relative to the target surface. The kink at ?100 m might be related to the interface between two different rheological layers. Using the iSALE shock physics code, we numerically model the formation of Linné crater to derive hints on the possible impact conditions and target physical properties. In the initial setup, we adopt a basaltic projectile impacting the Moon with a speed of 18 km s^?1. For the local surface, we consider either one or two layers, in order to test the influence of material properties or composite rheologies on the final crater morphology. The one‐layer model shows that the largest variations in the crater shape take place when either the cohesion or the friction coefficient is varied. In particular, a cohesion of 10 kPa marks the threshold between conical‐ and parabolic‐shaped craters. The two‐layer model shows that the interface between the two layers would be exposed at the observed depth of 100 m when an intermediate value (~200 m) for the upper fractured layer is set. We have also found that the truncated‐cone morphology of Linné might originate from an incomplete collapse of the crater wall, as the breccia lens remains clustered along the crater walls, while the high‐albedo deposit on the crater floor can be interpreted as a very shallow lens of fallout breccia. The modeling analysis allows us to derive important clues on the impactor size (under the assumption of a vertical impact and collision velocity equal to the mean value), and on the approximate, large‐scale preimpact target properties. Observations suggest that these large‐scale material properties likely include some important smaller scale variations, disclosed as subtle morphological steps in the crater walls. Furthermore, the modeling results allow advancing some hypotheses on the geological evolution of the Mare Serenitatis region where Linné crater is located (unit S14). We suggest that unit S14 has a thickness of at least a few hundreds of meters up to about 400 m.     

RNA:DNA ratios of Baltic Sea herring larvae and copepods in embayment and open sea habitats

Elucidation of important nursery habitats for young fish can aid in the management and assessment of fish stocks. Herring (Clupea harengus) in the Baltic Sea primarily spawn in coastal areas, but larvae are also present in off-shore, open sea areas. To investigate if sheltered coastal habitats provide a better growth environment for larval herring, we compared short-term growth (as indexed by whole body RNA:DNA ratios) of larval herring from three habitat types of the northwest Baltic proper (sheltered inner bay, exposed outer bay, and open sea). In addition, we compared individual RNA content of adult female Eurytemora affinis (a common Baltic copepod) among these different habitats. High RNA levels in these copepods indicate high production of nauplii, which are important food for larval herring. Both RNA:DNA ratios of larval herring and RNA content of E. affinis were significantly greater in embayment habitats, suggesting that the sheltered coastal areas are high quality nursery habitats for young Baltic herring.