Chromite composition and platinum-group mineral assemblage in the Uktus Uralian-Alaskan-type complex (Central Urals,Russia)

Chromitite segregations in dunites of the Uktus Uralian-Alaskan-type complex (Central Urals, Russia) display large variation of the chromite composition: Cr/(Cr+Al)=0.46-0.77, Fe²⁺/(Fe²⁺+Mg)=0.28-0.66, and Fe³⁺/(Fe³⁺+Fe²⁺)=0.23-0.59. Three types of PGM assemblages have been recognized, varying in accordance with chromite composition: type I, dominated by Ru-Os-Ir (sulfides), is associated with magnesiochromite having Fe³⁺/(Fe³⁺+Fe²⁺)<0.30, in the southern dunite body. Type II, containing abundant Pt-Ir (alloys, minor sulfides), is found in magnesiochromite with Fe³⁺/(Fe³⁺+Fe²⁺)=0.40-0.44; type III, consisting of Ir-Rh-Pt-Pd (alloys, sulfarsenides, antimonides) in Fe-rich chromite having Fe²⁺/(Fe²⁺+Mg)=0.66 and Fe³⁺/(Fe³⁺+Fe²⁺)=0.59. Positive anomalies of Ir and Pt, and a negative peak of Ru characterize the PGE patterns of chromitites with type II and III PGM assemblages, whereas a positive Pt anomaly is observed in their dunite host. Intensive fractionation of Pt-Fe alloys in the Uktus chromitites reflects the anomalous behavior of Pt which is decoupled from Rh and Pd. Among other factors, the high iron activity and oxygen fugacity in the parent melt appear to exert a major control on precipitation of Pt-Fe alloys, below sulfur saturation. The strong Pt anomaly in chromitites from Uktus may indicate that Uralian-Alaskan-type magmas were derived from a Pt-rich mantle source.     

Cytochrome P4501A expression,chemical contaminants and histopathology in roach,goby and sturgeon and chemical contaminants in sediments from the Caspian Sea,Lake Balkhash and the Ily River Delta,Kazakhstan

Roach, goby and sturgeon were examined for cytochrome P4501A (CYP1A) expression and histopathology, in relation to contaminant burdens in fish and sediment. Gradients of induction of CYP1A were observed. Roach from the Ural and Ily River Deltas and roach and goby from the two stations nearest the Caspian Sea oil fields displayed higher levels of CYP1A expression in several organs than was observed in fish from further offshore. Great sturgeon and Russian sturgeon showed higher levels of CYP1A expression than was seen in starred sturgeon and gobies in the Ural delta. No fish showed evidence of contaminant-related histopathologies in the organs examined, despite the elevated CYP1A levels. Low levels of polychlorinated biphenyls and elevated levels of inshore and riverine petroleum hydrocarbons from these habitats suggest that this ongoing hydrocarbon exposure, and that from natural sources and long-term oil exploration on the Northeastern Caspian shore, contributed to the CYP1A induction observed.     

The use of a non-lethal tool for evaluating toxicological hazard of organochlorine contaminants in Mediterranean cetaceans: new data 10 years after the first paper published in MPB

In the Mediterranean Sea, top predators, and particularly cetacean odontocetes, accumulate high concentrations of organochlorine contaminants and toxic metals, incurring high toxicological risk. In this paper we investigate the use of the skin biopsies as a non-lethal tool for evaluating toxicological hazard of organochlorines in Mediterranean cetaceans, presenting new data 10 years after the paper published by Fossi and co-workers [Mar. Poll. Bull. 24 (9) (1992) 459] in which this new methodology was first presented. Some organochlorine compounds, now with worldwide distribution, are known as endocrine disrupting chemicals (EDCs). Here the unexplored hypothesis that Mediterranean cetaceans are potentially at risk due to organochlorines with endocrine disrupting capacity is investigated. High concentrations of DDT metabolites and PCB congeners (known as EDCs) were found in the different Mediterranean species (Stenella coeruleoalba, Delphinus delphis, Tursiops truncatus and Balaenoptera physalus). In this paper we also propose benzo(a)pyrene monooxygenase (BPMO) activity in marine mammal skin biopsies (non-lethal biomarker) as a potential indicator of exposure to organochlorines, with special reference to the compounds with endocrine disrupting capacity. A statistically significant correlation was found between BPMO activity and organochlorine levels (DDTs, pp(')DDT, op(')DDT, PCBs and PCB99) in skin biopsies of males of B. physalus. Moreover a statistical correlation was also found between BPMO activity and DDT levels in skin biopsies of the endangered Mediterranean population of D. delphis. These results suggest that BPMO induction may be an early sign of exposure to organochlorine EDCs and can be used for periodic monitoring of Mediterranean marine mammal toxicological status.     

The late Quaternary evolution of the Negro River, Amazon, Brazil: Implications for island and floodplain formation in large anabranching tropical systems

The Rio Negro has responded significantly in the Late Pleistocene and Holocene to lagged environmental changes largely associated with activity during the last glacial in the Amazon basin. On the basis of geological structure, the Rio Negro can be divided into six distinct reaches that each reflects very marked differential processes and geomorphological styles. No deposits of the Upper Pleniglacial were recognized in the field. The oldest recognizable Late Pleistocene alluvial unit is the Upper Terrace of Middle Pleniglacial age (ca. 65–25 ka) (reach I), tentatively correlated with the oldest terrace identified on the left bank of reach III. At that time, the river was mainly an aggradational bed load system carrying abundant quartz sand, a product of more seasonal conditions in the upper catchment. The late glacial (14–10 ka) is represented by a lower finer-grained terrace along the upper basin (reach I), which was recognized in the Tiquié, Curicuriarí, and Vaupes rivers. At that time, the river carried abundant suspended load as a response to climatic changes associated with deglaciation.Since about 14 ka, the river has behaved as a progradational system, infilling in downstream series a sequence of structurally controlled sedimentary basins or ‘compartments,’ creating alluvial floodplains and associated anabranching channel systems. Reach II was the first to be filled, then reach III, both accumulating mainly sand. Fine deposits increase downstream in reach III and become predominant in some anabranch islands of the distal reach. The lowermost reaches of the Negro (V and VI) have been greatly affected by a rising base level and associated backwater effect from aggradation of the Amazon during late glacial and recent times. Reach V has acted almost entirely as a fine sediment trap. The remarkable Anavilhanas archipelago is the product of Holocene deposition in the upper part of this sedimentary basin; however, suspended sediment load declined about 1.5 ka, prior to the lower part of this basin becoming infilled.The progradational behavior of the Rio Negro, filling tectonic basins as successive sediment traps with sand in the upper basins and fines in the downstream ones, illustrates how a large river system responses to profound changes in Late Quaternary base level and sediment supply. The most stable equilibrium conditions have been achieved in the Holocene in reaches IIb and IIIa, where an anabranching channel and erosional–relictual island system relatively efficiently convey water and sediment downstream. Reaches IIIb and V never achieved equilibrium conditions during the Holocene, characterised as they are today with incomplete floodplains and open water.     

The North-South Asymmetry in the Green Corona

The north-south asymmetry of the Fe XIV 530.3 nm coronal emission line (the green corona) over cycle 22 was investigated. The green corona line brightness was dominant in the southern hemisphere during cycle 22 (A = –0.07), except for short periods of the ascending phase of the activity cycle. The asymmetry of the semi-annual mean over the period 1940 – 1996 was also studied. The asymmetry, during these years, reached its maximum in 1962 – 1966, and then decreased. Important periodicities of the asymmetry in cycle 22, e.g., 158 and 350 days, 2.39 years were found. Similar periodicities were also detected in the years 1940 – 1996. An FFT analysis was used to detect these periodicities.     

Longitudinal Structure of the Double Magnetic Cycle

The longitudinal structure of the double magnetic cycle of solar activity has been investigated using Stanford magnetograph data from 1976 to 1996 (cycles 21 and 22). It is shown that both high-frequency and low-frequency sources of the magnetic field are present in the data and that they reach their maxima in longitudinal zones that are separated by 20°. Some longitudinal zones are found to exist in which the high-frequency component is dominant and other longitudinal zones are found in which the low-frequency component is dominant.     

Hydroclimatic contrasts and their influence on the vegetation,Barranca del Cobre,Mexico —a lengthening of the tropics in temperate zone

The climate is a physical fact remarkably affecting the geography of the earth surface, besides, the hydrological characteristics mostly resulting from the climate, also greatly influence the appearance of the landscape. In the zone of Barranca del Cobre, the hydroclimatic characteristics are peculiar thus, in this paper they are emphasized, and it is shown how they influence the vegetation, spontaneous and cultivated.     

Diapiric emplacement in the upper crust of a granitic body: the La Bazana granite (SW Spain)

The ascent and emplacement of granites in the upper crust is a major geological phenomenon accomplished by a number of different processes. The active processes determine the final geometry of the bodies and, in some favourable cases, the inverse problem of deducing mechanisms can be undertaken by relying on the geometry of plutons. This is the case of the La Bazana granitic pluton, a small Variscan igneous body that intruded Cambrian rocks of the Ossa-Morena Zone (SW Iberian Massif) in the core of a large late upright antiform. The granite shows no appreciable solid-state deformation, but has a late magmatic foliation whose orientation, derived from field observations, defines a gentle dome. The regional attitude of the main foliation in the country rock (parallel to the axial plane of recumbent folds) is NW–SE, but just around the granite, it accommodates to the dome shape of the pluton. Flattening in the host rock on top of the granite is indicated by boudinaged and folded veins, and appears to be caused by an upward pushing of the magma during its emplacement. The dome-shaped foliation of the granite, geometrically and kinematically congruent with the flattening in the host rock, can be related in the same way to the upward pushing of the magma. The level of final emplacement was deduced from the mineral associations in the thermal aureole to be of 7–10 km in depth. Models of the gravity anomaly related to the granite body show that the granite has a teardrop–pipe shape enlarged at its top. Diapiric ascent of the magma through the lower middle crust is inferred until reaching a high viscous level, where final emplacement accompanied by lateral expansion and vertical flattening took place. This natural example suggests that diapirism may be a viable mechanism for migration and emplacement of magmas, at least up to 7–10 km in depth, and it provides natural evidence for theoretical discussion on the ability of magmatic diapirs to pierce the crust.     

Organic carbon and sulphur compounds in wetland soils: insights on structure and transformation processes using K-edge XANES and NMR spectroscopy

X-ray absorption near-edge structure (XANES) and nuclear magnetic resonance (NMR) spectroscopy were used in combination to characterize organic carbon structures in a series of wetland soils in Saskatchewan, and XANES spectroscopy was also used to examine sulphur speciation in the soils. The organic C contents of most of the wetland soils are consistently higher by a factor of two to five times compared to adjacent well-drained soils. NMR analyses indicate that the organic matter in the wetland soils consists of predominantly aliphatic structures such as carbohydrates and long chain poly(methylene) units which are refractory structures found in plant waxes. The poly(methylene) structures have a significant capacity to sorb nonpolar organic molecules. The phenolic OH and carboxyl group content of the wetland soils studied is an additional significant factor in their sequestering ability for heavy metals or pesticides. Carbon XANES spectroscopy shows that the surface (∼10 nm) layer of particulate organic matter has a structure dominated by aromatic, carbohydrate and carboxylic acid-like material apparently derived from partially degraded lignin and cellulose polymers which are adsorbed onto clay minerals. The aliphatic structures remaining in this surface layer are probably recalcitrant (poly)methylene units. At a depth of ∼100 nm, the aliphatic content significantly increases suggesting the presence of more labile structures. The presence of these more labile aliphatic compounds may be due to slow decomposition rates in the wet, often cool environments present and to the protective action of the more refractory components in the surface ∼10 nm of the organic matter. Drying of the wetlands, either by draining or as a result of climate change, is likely to result in the rapid decomposition of these labile organic structures releasing carbon dioxide. Our data indicate that the preservation of the organic carbon compounds in these soils is a result of their presence as surface adsorbed layers on the soil mineral particles. The soils contain three different classes of sulphur compounds: reduced organic sulphur such as sulphides, low valent oxidized sulphur such as sulphoxides, and high valent oxidized sulphur such as sulphonate and sulphate. Of these, reduced sulphur species constitute between one-third and two-thirds of the total. Sulphonate structures comprise between a fifth and a third of the total. Sulphates exhibit a wide variation in content, and sulphoxides are either not detected or are present to a lesser extent (<5%). Drying of the wetlands would cause oxidation of sulphides to sulphates.