Strontium as a tracer of weathering processes in a silicate catchment polluted by acid atmospheric inputs, Strengbach, France

This paper determines the weathering and atmospheric contributions of Ca in surface water from a small spruce forested silicate catchment (N–E France) receiving acid atmospheric inputs. The bedrock is a granite with K-feldspar and albite as dominant phases. The calcium content in plagioclase is low and the Ca/Na ratio in surface water is high, reflecting other sources of calcium from those expected from the weathering of major mineral phases. The biotite content is low. Only traces of apatite were detected while no calcite was found in spite of a major hydrothermal event having affected the granite. The strontium isotopic ratio ⁸⁷Sr/⁸⁶Sr and Sr content was used as a tracer of weathering and was determined in minerals and bulk bedrock, open field precipitation, throughfall, soil solution, spring and stream water. The Sr isotopic ratio of the reacting weathering end-member was predicted by simulating the alteration of the granite minerals by incorporating strontium into the water–rock interaction kinetic code KINDIS. In the early stages of water–rock interaction, K-feldspar and biotite strongly influence the isotopic composition of the weathering solution whereas, the Na-rich plagioclase appears to be the main long-term reactive weathering end-member. Approximately 50% of dissolved Sr in streamwater are atmospherically derived. The ⁸⁷Sr/⁸⁶Sr ratios of exchangeable Sr in the fine fraction at 1-m depth from a soil profile indicate that the amount of exchangeable Sr seems essentially controlled by atmospheric inputs. The exception is the deep saprolite where weathering processes could supply the Sr (and Ca). Na-Plagioclase weathering obviously control the chemistry and the isotopic composition of surface waters. The weathering of trace mineral plays a secondary role, the exception is for apatite when plagioclase is absent. Our hydrochemical, mineralogical and isotopic investigations show that a major part of the strong Ca losses detected in catchment hydrochemical budgets that result from the neutralization of acid precipitation has an atmospheric origin. Consequently, in the long term, in such areas, the availability of such an exchangeable base cation might be strongly limited and surface waters consequently acidified.     

Petrology of lower-middle Miocene Zoumi Flysch Fm. (Mesorif sub-domain,Rif belt,Morocco): first evidence of mixed mode provenance and geodynamic setting

The Zoumi Basin was generated in a collisional tectonic setting during the Lower-Middle Miocene. The syn-orogenic flysch deposits of the basin have been well investigated by petrographic and geochemical studies to characterize the composition, source to sink routing system, and tectonic setting of the Zoumi flysch. Forty-three sandstone samples and 45 mudstone samples have been gathered from six measured stratigraphic sections. These samples have been analyzed using XRD, XRF, inductively coupled plasma-mass spectrometry (ICP-MS) for mudrocks and petrographic investigation for sandstones. The Lower-Middle Miocene Zoumi flysch is defined as sublitharenites and quartzarenites according to mineralogical content. Detrital grains are commonly subangular to subrounded, poorly sorted, and rich in quartz grains. Point counting modal analysis leads to craton interior and recycled orogen provenance with significant first-cycle sediment supply and low sedimentary recycling. Several chemical ratios (Al₂O₃/TiO₂, La/Th, Cr/Th, Th/Sc, Zr/Sc) as well as chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomaly suggest a dominant felsic rock sources. However, V-Ni-La*4, V-Ni-Th*10, and Th/Sc vs. Cr/Th plots do not exclude a mafic supply source nature which is evidenced by numerous ophiolitic outcrops scattered throughout the Mesorifan Subdomain (Mesorifan Ophiolitic Suture Zone).     

Perogenesis of granites, Sharm El-Sheikh area, South Sinai, Egypt: petrological constrains and tectonic evolution

Precambrian granites of the Sharm El-Sheikh area in south Sinai, Egypt belong to collisional and post-collisional Magmatism (610–580 Ma). The granites are widely distributed in the northern part of the Neoproterozoic Arabian-Nubian Shield. South Sinai includes important components of successive multiple stages of upper crust granitic rocks. The earliest stages include monzogranite and syenogranites while the later stages produced alkali feldspar granites and riebeckite-bearing granites. Numerous felsic, mafic dikes and quartz veins traverse the study granites. Petrographically, the granitic rocks consist mainly of perthite, plagioclase, quartz, biotite and riebeckite. Analysis results portray monzogranites displaying calc-alkaline characteristics and emplaced in island-arc tectonic settings, whereas the syenogranites, alkali-feldspar granites and the riebeckite bearing-granites exhibit an alkaline nature and are enriched in HFSEs similar to granites within an extensional regime. Multi-element variation diagrams and geochemical characteristics reinforce a post-collision tectonic setting. REEs geochemical modeling reveals that the rocks were generated as a result of partial melting and fractionation of lower crust basaltic magma giving rise to A₁ and A₂ subtype granites. They were subsequently emplaced within an intraplate environment at the end of the Pan-African Orogeny.     

Structure et caractérisation des matériaux utilisés dans la construction d'une mosaı̈que romaine de la cité de Volubilis (Maroc)

In Volubilis, Roman mosaics are very beautiful and reveal, from the bottom to the surface, three layers: (i) ‘hedgehog’ layer, (ii) coarse grain mortar layer (rudus + nucleus) and (iii) tesselatum. Mineralogical analysis of coarse grain mortar sampled in Flavius Germanus mosaic shows that it consisted of quartz and calcite, with some feldspar and probably mica and dolomite. Fine-grained mortar in tesselatum is made from a mixture of calcite and quartz only. Limestone tesserae (white, pink and brown) show petrographic facies that change from micritic to oolithic limestone. Conversely, black and brick red tesserae are respectively made of marble, red sandstone and from fire clay. Other colours as yellow, blue, green and grey are obtained from artificial glass with different chemical compositions. To cite this article: A. Dekayir et al., C. R. Geoscience 336 (2004).     

Spatial distribution and temporal trends of persistent organochlorine pollutants in sediments from Lake Maryut, Alexandria, Egypt

Organochlorine compounds (OCs) in surface and core sediments collected from Lake Maryut, Egypt, were examined to elucidate their distribution, ecological risk and historical trend. To our knowledge, this is the first study on residue levels of OCs in sediments from Lake Maryut. Concentrations of PCBs and DDTs were higher than other OCs, ranging from 3.06 to 388 and from 0.07 to 106 ng/g dry wt., respectively. The highest concentrations of OCs were found at stations near the discharge point of sewage and close to industrial areas. The distribution of DDT and its metabolites suggest no recent inputs into the lake environment. Contamination levels of sedimentary PCBs and DDTs, can be categorized moderate to high compared to other urbanized regions worldwide. Temporal trends in OCs levels were influenced by input pathways at two sites. Evaluation of ecotoxicological risks suggests that adverse biological effects are expected mainly in the main basin area.     

Mapping groundwater recharge potential zones in arid region using GIS and Landsat approaches,southeast Tunisia

The rapid growth of population and agricultural and industrial activities has caused an increase in demand on the Jeffara aquifers of Gabes (southeast Tunisia). In fact, the over-pumping of this aquifer system has resulted in water-level declines ranging from 0.25 to 1 m/year during the past three decades. The aim of this study is to identify favourable artificial recharge sites of this aquifer system based on the combined use of remotely sensed data, a geographic information system (GIS), the Shuttle Radar Topography Mission (SRTM) product and a multiple criteria decision making (MCDM) technique. The delineation of artificial recharge zones shows high to moderate potential for groundwater recharge (40%) in the Gabes region, with high precision of good potential proposed sites. Recharge processes need to account for natural conditions and ecosystems.     

Modeling and simulation of hybrid anaerobic/aerobic wastewater treatment system

Modeling and simulation using GPS-X software for a packed bed up-flow anaerobic sludge blanket followed by a biological aerated filter were studied. Both treatment units were packed with a non-woven polyester fabric as a bio-bed. The system was operated at a hydraulic and organic loading rate of 9.65 m³/m²/d and 2.64 kg BOD₅/m³/day. Verification of the experimental results and calibration of the model were carried out prior simulation and modeling. Variables under consideration were HLR, OLR, and surface area of the packing material. HLR and OLR are increased incrementally until the break through point has been achieved. The results obtained from modeling indicated that the treatment system has great potential to be used as an ideal and efficient option for high hydraulic and organic loading rates up to 19.29 m³/m²/d and 4.48 kg BOD₅/m³/day. The model indicated that increasing the input HLR and OLR loads to the treatment system up to 50 % of the original values achieved removal efficiencies 98 % for TSS, 88 % for BOD₅, and 85 % for COD. Moreover, increasing the HLR to four times the original value (38.59 m³/m²/d) reduced the efficiency of the treatment system to 50 % for COD and BOD₅. However, the removal rates of TSS, TKN, and TP were not affected. Also, the modeling results indicated that increasing the surface area of the packing material increased the overall efficiency of the treatment system.     

Hydrothermal alteration of plagioclase in granitic rocks from Proterozoic basement of SE Sweden

Petrographic examinations and electron microprobe analyses of Proterozoic granitic rocks, SE Sweden aimed to characterize and unravel the mechanisms and conditions of plagioclase alterations. These alterations include saussuritization, albitization and replacement of plagioclase by K‐feldspar. The hydrothermal alterations, which are inferred to have occurred at ca. 250–400°C, resulted in concomitant formation of Al‐rich titanite, epidote, calcite, pumpellyite, prehnite and iron oxides. Replacement of plagioclase by K‐feldspar occurs in red‐stained zones, which have developed close to thin fractures owing to the precipitation of tiny Fe‐oxide pigment particles within the altered plagioclase, whereas saussuritized plagioclase has less systematic spatial relationships to these fractures. Albitization of plagioclase occurred in rocks that are poor in biotite compared to rocks that suffered extensive saussuritization. The chemical and textural characterization of various types of plagioclase alterations allows elucidation of the granitic hydrothermal systems. Features of feldspar alteration in the granitic rocks are similar to those encountered in feldspathic sandstones and should hence be considered in studies on diagenetic changes of siliciclastic successions during basin evolution. Copyright © 2009 John Wiley & Sons, Ltd.     

Analytical solution for distributed torsional low strain integrity test for pipe pile

Low strain integrity tests (LSITs) are the most popular non-destructive methods for pile testing. However, traditional LSITs have encountered unprecedented challenges as the need for long pile and existing pile testing keeps multiplying. Compared to traditional longitudinal excitations, the torsional wave is less influenced by the velocity attenuation effect and can be subjected at the pile shaft for existing piles. Distributed torsional LSIT is proposed in this article with the presentation of the corresponding analytical solutions that exhibiting the velocity responses along the pile shaft. The solution is verified with previous simplified theoretical and rigorous finite element method (FEM) answers. At the end, the application of this method is exhibited through the identification of necking and concrete segregation defects on pipe piles, which shows the advantage of this method on long pile testing.