Water and sediment quality parameters in the Chalan Beel,the largest wetland of Bangladesh

A study was conducted to investigate the status of the water and sediment quality in the Chalan Beel——a major fresh water fish reservoir of the country for a period of one year from July 2007 to June 2008. The mean values of water quality parameters(depth: 214.73±152.22 cm, temperature 27.68±4.26℃, transparency 123±82 cm, p H 9.7±0.47, total alkalinity 137±42 mg/L, conductivity 307±147 μs/cm, total dissolved solids 183±89 mg/L, ammonia-N 0.27±0.39 mg/L, nitrate-N 0.09±0.07 mg/L, phosphate-P 2.01±2.53 mg/L) and sediment quality parameters(p H 7.21±0.35, organic matter 2.59±0.52%, total nitrogen 0.09±0.04%, available phosphorus 5.4±3.6 Meq./100 g and exchangeable potassium 0.43±0.14 Meq./100 g) were within the range recommended for most of the inland fishes of Bangladesh. Although the water and sediment quality parameters except ammonia and phosphate are in the suitable range, the overall results suggest that better management techniques should be practiced in order to overcome the declining trend of associated aquatic life(fauna and flora) of this important fresh water body of Bangladesh.     

O and H diffusion in uraninite: Implications for fluid-uraninite interactions, nuclear waste disposal, and nuclear forensics

Diffusion coefficients for oxygen and hydrogen were determined from a series of natural uraninite-H₂O experiments between 50 and 700 °C. Under hydrous conditions there are two diffusion mechanisms: (1) an initial extremely fast-path diffusion mechanism that overprinted the oxygen isotopic composition of the entire crystals regardless of temperature and (2) a slower volume-diffusive mechanism dominated by defect clusters that displace or eject nearest neighbor oxygen atoms to form two interstitial sites and two partial vacancies, and by vacancy migration. Using the volume diffusion coefficients in the temperature range of 400-600 °C, diffusion coefficients for oxygen can be represented by D = 1.90e⁻⁵ exp (−123,382 J/RT) cm²/s and for temperatures between 100 and 300 °C the diffusion coefficients can be represented by D = 1.95e⁻¹⁰ exp (−62484 J/RT) cm²/s, where the activation energies for uraninite are 123.4 and 62.5 kJ/mol, respectively. Hydrogen diffusion in uraninite appears to be controlled by similar mechanisms as oxygen. Using the volume diffusion coefficients for temperatures between 50 and 700 °C, diffusion coefficients for hydrogen can be represented by D = 9.28e⁻⁶ exp (−156,528 J/RT) cm²/s for temperatures between 450 and 700 °C and D = 1.39e⁻¹⁴ exp (−34518 J/RT) cm²/s for temperatures between 50 and 400 °C, where the activation energies for uraninite are 156.5 and 34.5 kJ/mol, respectively.Results from these new experiments have implications for isotopic exchange during natural UO₂-water interactions. The exceptionally low δ¹⁸O values of natural uraninites (i.e. −32‰ to −19.5‰) from unconformity-type uranium deposits in Saskatchewan, in conjunction with theoretical and experimental uraninite-water and UO₃-water fractionation factors, suggest that primary uranium mineralization is not in oxygen isotopic equilibrium with coeval clay and silicate minerals. The low δ¹⁸O values have been interpreted as resulting from the low temperature overprinting of primary uranium mineralization in the presence of relatively modern meteoric fluids having δ¹⁸O values of ca. −18‰, despite petrographic and U-Pb isotope data that indicate limited alteration. Our data show that the anomalously low oxygen isotopic composition of the uraninite from the Athabasca Basin can be due to meteoric water overprinting under reducing conditions, and meteoric water or groundwater can significantly affect the oxygen isotopic composition of spent nuclear fuel in a geologic repository, with minimal change to the chemical composition or texture. Moreover, the rather fast oxygen and hydrogen diffusion coefficients for uraninite, especially at low temperatures, suggest that oxygen and hydrogen diffusion may impart characteristic isotopic signals that can be used to track the route of fissile material.     

REE and actinide microdistribution in Sahara 97072 and ALHA77295 EH3 chondrites: A combined cosmochemical and petrologic investigation

We report the results of rare earth elements (REEs) and U-Th inventory of individual minerals (oldhamite, enstatite and niningerite) in two of the most unequilibrated and primitive EH3 known so far, ALHA77295 and Sahara 97072. Under the highly reducing condition that prevailed during the formation of enstatite chondrites, REEs are mainly chalcophile and concentrated in oldhamite. The study is guided by detailed petrographic investigations of the individual minerals in chondrules, complex sulfide-metal clasts and enstatite-dominated matrices.We developed two textural parameters in order to resolve the evolution of oldhamite condensates and their residence in the solar gas prior to their accretion in the individual objects or in matrices and relate these textural features to the measured REE patterns of the individual oldhamite crystals. These textural parameters are the crystal habit of oldhamite grains (idiomorphic or anhedral) and their host assemblages. REE concentrations were measured by SIMS and LA-ICPMS.Oldhamite grains display REE enrichments (10-100 × CI). Four types of REE patterns are encountered in oldhamite in ALHA77295. In general the REE distributions cannot be assigned to a specific oldhamite-bearing assemblage. The most represented REE pattern is characterized by both slight to large positive Eu and Yb anomalies and is enriched in light REEs relative to heavy REEs. This pattern is present in 97% of oldhamite in Sahara 97072, suggesting a different source region in the reduced part of the nebula or different parental EH asteroids for the two EH3 chondrites. Different parental asteroids are also supported by MgS-FeS zoning profiles in niningerite grains adjacent to troilite revealing both normal and reverse zoning trends and different MnS contents. The observed homogeneity of REE distribution in oldhamite grains in Sahara 97072 is not related to the mild metamorphic event identified in this meteorite that caused breakdown of the major K- and Rb-bearing sulfide (djerfisherite).REE concentrations in enstatite range between 0.2 and 8 × CI. Hence, enstatite is an important REE host next to oldhamite. Most patterns are characterized by negative Eu and Yb anomalies. Niningerites are negligible contributors to bulk EH3 REE inventory. Average positive Eu and Yb anomalies observed in most oldhamite are complimentary to the negative ones in enstatite thus explaining the flat patterns of the bulk meteorites. The condensation calculations based on cosmic abundances predict that the first oldhamite condensates should have flat REE patterns with Eu and Yb depletions since Eu and Yb condense at lower temperature than other REE. However, this pattern is seen in enstatite. Our findings are at odds with the predicted negative Eu and Yb anomalies in oldhamite earliest condensates from a closed system in a reduced solar source. Our petrographic, mineral chemistry and REE abundances of oldhamite, enstatite and niningerite discards an origin of oldhamite by impact melting (Rubin et al., 2009).Our results do not support in first order the scenario of the incorporation of REE in the Earth’s core to explain ¹⁴²Nd excess in terrestrial samples relative to chondrites because oldhamite is the major REE carrier phase and has super-chondritic Sm/Nd ratios.     

Erratum: Trace Elements in Sediments and Mussels – Spatial Distribution,Chemical Partitioning,and Risk Assessment

Sediment samples were collected from 30 different locations in Abu Qir Bay (Mediterranean Sea), East Alexandria, Egypt and analyzed for trace elements. The highest concentrations of most of the elements were observed in the nearshore stations in the vicinity of the major anthropogenic activities as industrial settlements, wastewater discharges, and agricultural drainage. In addition, mussel samples of Mactra corallina and Tapes decussata were collected corresponding to the sediment samples. Concentrations of As, Cd, Cr, Mn, and Zn in the mussel tissues were higher than concentrations in sediments, thus indicating their relatively high bioavailability. Sequential extraction procedure was performed on selected sediment samples. Significant correlations were observed between the concentrations of Cu, Mn, Pb, and Zn in the exchangeable fraction of the sediments and the corresponding tissues of M. corallina. The output of the risk assessment applied on the sediments revealed that adverse ecological effects to benthic species could occur and that a higher level of risk is expected from the exposure to Cd, Cr, Hg, and Zn. No adverse carcinogenic or non‐carcinogenic human health effects are expected from the consumption of the two mussel species from Abu Qir Bay.     

Determination of Cu,Fe, and Ni in Spices after Preconcentration on Diaion‐HP 20 Resin as Their Zincon Complexes

In this work, a new separation–preconcentration method was developed for the determination of trace amounts of Cu(II), Ni(II), and Fe(III) by flame atomic absorption spectrometry (FAAS). Analytes were complexed by using zincon (2‐[2‐[alpha(2‐hydroxy‐5‐sulfophenylazo) benzylidene] hydrazino] benzoic acid sodium salt). The analyte ions were quantitatively adsorbed on a Diaion HP‐20 resin at pH 5. The retained metal ions on the resin were eluted by acetone. The analytical parameters such as pH of the sample, eluent type and volume, sample volume, and flow rates of the solution and the eluent were investigated. The influences of concomitant ions on the recoveries of the analytes were also examined. The instrumental detection limits for the analytes after application of the presented solid‐phase extraction procedure were in the range of 0.72–1.41 µg/L. The validation of the presented procedure was checked by analyzing certified reference material of SRM1515 Apple Leaves. The procedure was performed by analyzing some spice samples.     

Uncertainty and Reliability Analysis Applied to Slope Stability: A Case Study From Sungun Copper Mine

Nowadays, there are many new methods for slope stability analysis; including probabilistic methods assessing geotechnical uncertainties to develop safety factors. In this paper, a reliability index analysis for the Sungun copper mine slope stability is evaluated based on three methods of uncertainties consisting Taylor series method, Rosenblueth point estimate method and Monte-Carlo simulation method. Sungun copper mine will be one of the Iran’s biggest mines with final pit’s height of 700 meters. For this study two of its main slopes were assessed, one dipping to the NE (030) and the other to the SE (140). Probability density function of cohesion and angle of friction for the slopes were developed using limit equilibrium methods. These shear strengths were then used to determine the probability density function of safety factor and reliability index using the probabilistic methods. Results of the probabilistic analysis indicate that with ascending values of the uncertainties the reliability index decreases. Furthermore, it was determined that with the Monte Carlo simulation the seed number used has little effect on the reliability index of the safety factor especially with seed numbers in excess of 1200. Variations in the overall reliability index of safety factor were observed between the two slopes and this difference is explained by the differences in complexities of the geology within the cross-section.     

Mineralogy,geochemistry, radioactivity and environmental impacts of Gabal Marwa granites,southeastern Sinai,Egypt

The Gabal Marwa area is located in the southeastern part of Sinai,Egypt.It comprises gneisses and migmatites,granodiorites and monzogranites.Field,petrographic,mineralogic and chemical investigations indicated that the Gabal Marwa granites are classified as granodiorites and monzogranites.The monzogranites constitute the most predominant rock unit exposed in the study area.They have been subjected to hydrothermal alterations,especially along the shear zones.Sericitization,desilicification,nametasomatism and development of spotty or dendritic manganese oxides are the most pronounced alteration features.These alterations resulted in the increase of TiO2,Al2O3,FeOt,MnO,CaO,MgO,Na2O,K2O and Cr,Zr,Rb,Y and Sr and the decrease of SiO2,P2O5,Ni,Zn,Ba and Nb.Radiometric studies indicated that the altered granites belong to high thorium,high uranium granites.The U,Th,U and Th,Th/U,Th and U-K variation diagrams suggested that magmatic processes controlled the distribution of these elements but the effect of hydrothermal alteration processes were clearly distinct.The Scanning Electron Microscope and X-ray Diffraction analyses indicated that the most important radioactive minerals include uranothorite,thorite,zircon,monazite and samarskite.Cinnabar and Mn minerals were also found.From the U,Th,Ra and K activity concentrations obtained for all the studied granitic samples,radium equivalent activity(Raeq),external hazard index(Hex),and internal hazard index(Hin),were calculated to assess the radiation hazard to human beings living in dwellings made of the studied granites.Altered monzogranites have radioactivity above the proposed acceptable level and,therefore,caution must be taken when these granites are used as building materials.     

Palynostratigraphy and paleoenvironmental significance of the Cretaceous succession in the Gebel Rissu-1 well,north Western Desert,Egypt

Palynological investigation of the Cretaceous Abu Roash, Bahariya, Kharita, Alamein, Alam El Bueib and Betty formations, encountered in the Gebel Rissu-1 well, north Western Desert, Egypt yielded 27 species of pteridophytic spores, 24 of gymnosperm pollen, 25 of angiosperm pollen and 11 of dinoflagellate cysts in addition to some acritarchs, foraminiferal test linings and freshwater algae. This enabled us to recognize five miospore biozones arranged from youngest to oldest as: Classopollis brasiliensis–Afropollis cf. kahramanensis–Dichastopollenites ghazalataensis Assemblage Zone (Late Cenomanian); Elaterosporites klaszii–Sofrepites legouxae–Afropollis jardinus Assemblage Zone (Middle/Late Albian–Early Cenomanian); Pennipollis peroreticulatus–Duplexisporites generalis-Tricolpates Assemblage Zone (Early Aptian–Early Albian); Tucanopollis crisopolensis–Afropollis sp. Assemblage Zone (Barremian) and Appendicisporites cf. tricornitatus–Ephedripites spp. Assemblage Zone (Late Neocomian).The Early Cretaceous Kharita, Alam El Bueib and the Betty formations encountered in the Gebel Rissu-1 well are interpreted to indicate oxic proximal and distal shelf deposits, characterized by type III/IV, V kerogen, which is gas prone but having little potential to produce hydrocarbons. The Upper Cretaceous Abu Roash and Bahariya formations are characterized by a distal suboxic–anoxic and marginal dysoxic–anoxic environment, and their kerogen type III/II indicates gas/oil prone nature. The Bahariya and Kharita Albian–Cenomanian sediments in the present study witnessed the onset of a semi-arid to arid climate, with local or seasonal humid conditions, based on the continuous high abundance of the elaterates pollen and Afropollis-producing plants that inhabited the paleotropical humid coastal plains.