Evaluation of phosphorus bioavailability in El Mex Bay and Lake Mariut sediments

Phosphorus (P) fractions and their bioavailability in the sediments from El Mex Bay and Lake Mariut in Egypt were investigated using different chemical extraction methods. Sodium bicarbonate (NaHCO3) extractable P (Olsen-P) was the largest fraction (14.42%), followed by algal available P (AAP) (3.56%), water soluble P (WSP) (0.79%), and readily desorbable P (RDP) (0.06%) for El Mex Bay. While AAP con-tributed 9.94% to total P in sediments from Lake Mariut, Olsen-P 8.53%, WSP 4.11%, and RDP 0.92%. Summation of the bioavailable P fractions didn't exceed the sediment quality guidelines, and, therefore, P doesn't represent a danger to marine organisms. Correlation coefficients showed that no apparent relations between total P (TP) and iron (Fe), aluminum (Al), and calcium (Ca) in the sediments. Fur-thermore, Fe:P ratio was less than 15 indicting that there was not enough Fe in surface sediments to bind to P at most of the sampling sites. The positive correlation between TP and organic matter (OM) for Lake Mariut and El Mex Bay sediments indicated that the organic matter content of the sediment was a useful predictor of the total phosphorus content. Data from this study constitute a baseline of phosphorus bioavailability in sediments from El Mex Bay and Lake Mariut and could be used as a reference for future studies on the changes of bioavailable and residual phosphorus fractions over time.     

Generalized total least squares to characterize biogeochemical processes of the ocean

The chemical composition of the global ocean is governed by biological, chemical, and physical processes. These processes interact with each other so that the concentrations of carbon, oxygen, nitrogen (mainly from nitrate, nitrite, ammonium), and phosphorous (mainly from phosphate), vary in constant proportions, referred to as the Redfield ratios. We construct here the generalized total least squares estimator of these ratios. The significance of our approach is twofold; it respects the hydrological characteristics of the studied areas, and it can be applied identically in any area where enough data are available. The tests applied to Atlantic Ocean data highlight a variability of the Redfield ratios, both with geographical location and with depth. This variability emphasizes the importance of local and accurate estimates of Redfield ratios.     

Performance evaluation of WAVEWATCH III model in the Persian Gulf using different wind resources

The third-generation wave model, WAVEWATCH III, was employed to simulate bulk wave parameters in the Persian Gulf using three different wind sources: ERA-Interim, CCMP, and GFS-Analysis. Different formulations for whitecapping term and the energy transfer from wind to wave were used, namely the Tolman and Chalikov (J Phys Oceanogr 26:497–518, 1996), WAM cycle 4 (BJA and WAM4), and Ardhuin et al. (J Phys Oceanogr 40(9):1917–1941, 2010) (TEST405 and TEST451 parameterizations) source term packages. The obtained results from numerical simulations were compared to altimeter-derived significant wave heights and measured wave parameters at two stations in the northern part of the Persian Gulf through statistical indicators and the Taylor diagram. Comparison of the bulk wave parameters with measured values showed underestimation of wave height using all wind sources. However, the performance of the model was best when GFS-Analysis wind data were used. In general, when wind veering from southeast to northwest occurred, and wind speed was high during the rotation, the model underestimation of wave height was severe. Except for the Tolman and Chalikov (J Phys Oceanogr 26:497–518, 1996) source term package, which severely underestimated the bulk wave parameters during stormy condition, the performances of other formulations were practically similar. However, in terms of statistics, the Ardhuin et al. (J Phys Oceanogr 40(9):1917–1941, 2010) source terms with TEST405 parameterization were the most successful formulation in the Persian Gulf when compared to in situ and altimeter-derived observations.     

High-resolution seismic imaging of crooked two-dimensional profiles in greenstone belts of the Canadian shield: results from the Swayze area,Ontario, Canada

In 2017, the Metal Earth multi-disciplinary exploration project acquired a total of 921 km of regional deep seismic reflection profiles and 184 km of high-resolution seismic reflection profiles in the Abitibi and Wabigoon greenstone belts of the Superior province of Canada. The Abitibi belt hosts several world-class mineral deposits, whereas the Wabigoon has sparse economic mineral deposits. Two high-resolution surveys in the Swayze area, a poorly endowed part of the western Abitibi greenstone belt, served as pioneer surveys with which to better understand subsurface geology and design a strategy to process other surveys in the near future. Swayze seismic data were acquired with crooked survey geometries along roads. Designing an effective seismic processing flow to address these geometries and complex geology required straight common midpoint lines along which both two-dimensional prestack dip-moveout correction and poststack migration processing were applied. The resulting seismic sections revealed steeply dipping and subhorizontal reflections; some correlate with folded surface rocks. An interpreted fault/deformation zone imaged in Swayze north would be a target for metal endowment if it extends the Porcupine–Destor structure. Because of the crooked line geometry of the surveys, two-dimensional /three-dimensional prestack time migration and swath three-dimensional processing were tested. The prestack time migration algorithm confirmed reflections at the interpreted base of the Abitibi greenstone belt. The swath three-dimensional images provided additional spatial details about the geometries of some reflections, but also had less resolution and did not detect many reflectors observed in two dimensions. Geological contacts between felsic, mafic and ultramafic greenstone rock layers are thought the main cause of reflectivity in the Swayze area.     

Look-ahead vertical seismic profiling inversion approach for density and compressional wave velocity in Bayesian framework

To reduce drilling uncertainties, zero-offset vertical seismic profiles can be inverted to quantify acoustic properties ahead of the bit. In this work, we propose an approach to invert vertical seismic profile corridor stacks in Bayesian framework for look-ahead prediction. The implemented approach helps to successfully predict density and compressional wave velocity using prior knowledge from drilled interval. Hence, this information can be used to monitor reservoir depth as well as quantifying high-pressure zones, which enables taking the correct decision during drilling. The inversion algorithm uses Gauss–Newton as an optimization tool, which requires the calculation of the sensitivity matrix of trace samples with respect to model parameters. Gauss–Newton has quadratic rate of convergence, which can speed up the inversion process. Moreover, geo-statistical analysis has been used to efficiently utilize prior information supplied to the inversion process. The algorithm has been tested on synthetic and field cases. For the field case, a zero-offset vertical seismic profile data taken from an offshore well were used as input to the inversion algorithm. Well logs acquired after drilling the prediction section was used to validate the inversion results. The results from the synthetic case applications were encouraging to accurately predict compressional wave velocity and density from just a constant prior model. The field case application shows the strength of our proposed approach in inverting vertical seismic profile data to obtain density and compressional wave velocity ahead of a bit with reasonable accuracy. Unlike the commonly used vertical seismic profile inversion approach for acoustic impedance using simple error to represent the prior covariance matrix, this work shows the importance of inverting for both density and compressional wave velocity using geo-statistical knowledge of density and compressional wave velocity from the drilled section to quantify the prior covariance matrix required during Bayesian inversion.     

Trace and REE element geochemistry of fluorite and its relation to uranium mineralizations,Gabal Gattar Area,Northern Eastern Desert,Egypt

Uranium mineralizations occur and form in a broad range of geologic setting and age, including magmatic to surfacial conditions, and there are numerous controls on their transportation and deposition, such as redox, pH, ligand concentration, complexation, and temperature. These temporal and spatial variations have caused a range of ore deposit mineral assemblages. Consequently, understanding their conditions of formation is still in its infancy. This research reports rare earth elements (REE) and trace elements of fluorite associated with hexavalent uranium mineralizations and tests of genetic models for the deposits. These data contribute to a better understanding of the variables controlling fluorite formation and uranium ore composition through understanding the evolution of these ore-forming hydrothermal systems. Fluorite in Gabal Gattar granite occurs as disseminations and/or thin veinlets and encrustations filling some uranium mineralized fissures and fractures along the northern margin of host granite mass. In the U-poor samples, fluorite forms well-developed large crystals that are commonly zoned. The zones are represented by alternating colorless and violet zones, and the outer zones are frequently dark violet. In the U-rich samples, fluorite is usually anhedral, unzoned, and has a dark violet color. The results of analysis of REE and trace element contents of fluorites using laser ablation inductively coupled plasma mass spectrometry indicate that total REE in the anhedral unzoned fluorite are elevated compared to the well developed zoned fluorite, and also total REE in dark violet zones of zoned fluorite are elevated with respect to the colorless zones. The fluorites and host granite are generally characterized by strongly negative Eu anomalies and slightly negative or chondritic Ce anomalies. Accordingly, REE patterns of the fluorite and host granite are roughly alike, indicating that the source of REE and trace elements of hydrothermal fluids is the host granite leached by fluids. Y/Y*, Ce/Ce,* and Eu/Eu* patterns show that fluorite clearly records the compositional evolution of the hydrothermal solutions that have transferred trace and REE from host granite during the fluid–wall rocks interactions. The high uranium contents of fluorite in Gabal Gattar granite suggest that parent fluids bearing fluorine have interacted with host granite to leach uranium from the accessory minerals of granite and tetravalent uranium minerals in reduced or weakly oxidized zones.     

Distribution and immobilization of heavy metals in Pliocene aquifer sediments in Wadi El Natrun depression, Western Desert

The Pliocene aquifer receives inflow of Miocene and Pleistocene aquifer waters in Wadi El Natrun depression. The aquifer also receives inflow from the agricultural activity and septic tanks. Nine sediment samples were collected from the Pliocene aquifer in Wadi E1 Natrun. Heavy metal (Cu, Sr, Zn, Mn, Fe, Al, Ba, Cr, Ni, V, Cd, Co, Mo, and Pb) concentrations of Pliocene aquifer sediments were investigated in bulk, sand, and mud fractions. The determination of extractable trace metals (Cu, Zn, Fe, Mn, and Pb) in Pliocene aquifer sediments using sequential extraction procedure (four steps) has been performed in order to study environmental pathways (e.g., mobility of metals, bounding states). These employ a series of successively stronger chemical leaching reagents which nominally target the different compositional fractions. By analyzing the liquid leachates and the residual solid components, it is possible to determine not only the type and concentration of metals retained in each phase but also their potential ecological significance. Cu, Sr, Zn, Mn, Fe, and Al concentrations are higher in finer sediments than in coarser sediments, while Ba, Cr, Ni, V, Cd, Co, Mo, and Pb are enriched in the coarser fraction. The differences in relative concentrations are attributed to intense anthropogenic inputs from different sources. Heavy metal concentrations are higher than global average concentrations in sandstone, USEPA guidelines, and other local and international aquifer sediments. The order of trace elements in the bulk Pliocene aquifer sediments, from high to low concentrations, is Fe?>?Al?>?Mn?>?Cr?>?Zn?>?Cu?>?Ni?>?V?>?Sr?>?Ba?>?Pb?>?Mo?>?Cd?>?Co. The Pliocene aquifer sediments are highly contaminated for most toxic metals, except Pb and Co which have moderate contamination. The active soluble (F0) and exchangeable (F1) phases are represented by high concentrations of Cu, Zn, Fe, and Mn and relatively higher concentrations of Pb and Cd. This may be due to the increase of silt and clay fractions (mud) in sediments, which act as an adsorbent, retaining metals through ion exchange and other processes. The order of mobility of heavy metals in this phase is found to be Pb?>?Cd?>?Zn?>?Cu?>?Fe?>?Mn. The values of the active phase of most heavy metals are relatively high, indicating that Pliocene sediments are potentially a major sink for heavy metals characterized by high mobility and bioavailability. Fe–Mn oxyhydroxide phase is the most important fraction among labile fractions and represents 22% for Cd, 20% for Fe, 11% for Zn, 8% for Cu, 5% for Pb, and 3% for Mn. The organic matter-bound fraction contains 80% of Mn, 72% of Cu, 68% of Zn, 60% of Fe, 35% of Pb, and 30% of Cd (as mean). Summarizing the sequential extraction, a very good immobilization of the heavy metals by the organic matter-bound fraction is followed by the carbonate-exchangeable-bound fraction. The mobility of the Cd metal in the active and Fe–Mn oxyhydroxide phases is the highest, while the Mn metal had the lowest mobility.     

Probabilistic analysis of strip footings based on enhanced Kriging metamodeling

Two advanced Kriging metamodeling techniques were used to compute the failure probability of geotechnical structures involving spatially varying soil properties. These methods are based on a Kriging metamodel combined with a global sensitivity analysis that is called in literature Global Sensitivity Analysis-enhanced Surrogate (GSAS) modeling for reliability analysis. The GSAS methodology may be used in combination with either the Monte Carlo simulation (MCS) or importance sampling (IS) method. The resulting Kriging metamodeling techniques are called GSAS-MCS or GSAS-IS. The objective of these techniques is to reduce the number of calls of the mechanical model as compared with the classical Kriging-based metamodeling techniques (called AK-MCS and AK-IS) combining Kriging with MCS or IS. The soil uncertain parameters were assumed as non-Gaussian random fields. EOLE methodology was used to discretize these random fields. The mechanical models were based on numerical simulations. Some probabilistic numerical results are presented and discussed.     

Characterizing seasonal groundwater storage in alpine catchments using time-lapse gravimetry,water stable isotopes and water balance methods

Alpine areas play a major role in water supply in downstream valleys by releasing water during warm and dry periods. However, the hydrogeology of alpine catchments, which are particularly exposed to the effects of climate change, is currently not well understood. Increasing our knowledge of alpine hydrogeological processes is thus of considerable importance for any forward-looking hydrological investigations in alpine areas. The objectives of this study are to quantify seasonal groundwater storage variations in a small Swiss alpine catchment and to evaluate the capabilities of time-lapse gravimetry in the identification of zones of high groundwater storage fluctuations. Time-lapse gravimetric measurements enable rapid localisation of zones of dynamic groundwater storage changes and help to highlight aquifers with a higher storage decrease. Temperature sensors enable measurement of the temporal trend in stream and spring drying in the post-snowmelt period. Stable isotope measurements allow us to identify the origin of surface water exiting the catchment. The results improve our comprehension of a conceptual schema highlighting two different hydrogeological systems: (a) a shallow, rapidly depleted one fed directly by snowmelt and (b) a deeper one, with a slower recession, fed by main recharge during peak snowmelt and emerging at the lower part of the catchment below the talus and moraine of the catchment where bedrock is exposed. These dynamics confirm the high variability of storage in the talus and moraine aquifers and highlight the dominant role of Quaternary deposits and their connectivity to store water over seasonal and multi-year time-scales. The mechanisms explaining the importance of Quaternary deposits are the combination of moraine and talus with different permeabilities allowing the storage of sufficient quantities of water permitting continuous release during drier periods of the year.     

Contributions of gravity and field data on the structural scheme updating of the Tellian domain and its foreland (Nefza-Bizerte region,northern Tunisia)

International Journal of Earth Sciences - The Nefza-Bizerte region, eastern part of the Tunisian Alpine chain, covers the thrust sheets domain called the Tell and its Atlassic foreland. The deep...