Environmental and Health Impacts of Successive Mineral Fertilization in Egypt

Excessive amounts of mineral fertilizers are unnecessarily applied to agricultural soils in Egypt to increase crop yield. The current study aims at assessing the impacts of fertilization with different mineral fertilizers for different cultivation periods on the accumulation of heavy metals in soils and plants grown thereon. In addition, human risks resulted due to the exposure to these metal ions through ingestion, and dermal routes were evaluated. Soil and plant samples were collected from several locations in El‐Behira Governorate, Egypt and their heavy metal contents were measured. The result indicated that there is a continuous accumulation of heavy metals in the soils and the plants grown thereon. Calculation of the hazard index (HI) revealed that humans, especially children, have a potential health risk for both Pb and Cd, which have levels greater than the safe level (1). Finally, the obtained results showed that the continuous application of mineral fertilizers containing high levels of heavy metals pose a potential health threat.     

A roughness-corrected index of relative bed stability for regional stream surveys

Quantitative regional assessments of streambed sedimentation and its likely causes are hampered because field investigations typically lack the requisite sample size, measurements, or precision for sound geomorphic and statistical interpretation. We adapted an index of relative bed stability (RBS) for data calculated from a national stream survey field protocol to enable general evaluation of bed stability and anthropogenic sedimentation in synoptic ecological surveys. RBS is the ratio of bed surface geometric mean particle diameter (D_gm) divided by estimated critical diameter (D_cbf) at bankfull flow, based on a modified Shield's criterion for incipient motion. Application of RBS to adequately depict bed stability in complex natural streams, however, has been limited because typical calculations of RBS do not explicitly account for reductions in bed shear stress that result from channel form roughness. We modified the index (RBS) to incorporate the reduction in bed shear stress available for sediment transport that results from the hydraulic resistance of large wood and longitudinal irregularities in channel dimensions (“form roughness”). Based on dimensional analysis, we derived an adjustment to bankfull shear stress by multiplying the bankfull hydraulic radius (R_bf) by the one-third power of the ratio of particle-derived resistance to total hydraulic resistance (C_p/C_t)^1/3, where both resistances are empirically based calculations. We computed C_p using a Keulegan equation relating resistance to relative submergence of bed particles. We then derived an empirical equation to predict reach-scale hydraulic resistance C_t from thalweg mean depth, thalweg mean residual depth, and large wood volume based on field dye transit studies, in which total hydraulic resistance C_t was measured over a wide range of natural stream channel complexity, including manipulation of large wood volumes. We tested our estimates of C_t and RBS by applying them to data from a summer low flow probability sample of 104 wadeable stream reaches in the Coastal Ecoregion of Oregon and Washington, USA. Stream discharges calculated using these C_t estimates compared favorably with velocity–area measurements of discharge during summer low flow, and with the range of 1 to 2-year recurrence floods (scaled by drainage area) at U.S.Geological Survey gauged sites in the same region. Log [RBS] ranged from − 4.2 to + 0.98 in the survey region. D_gm ranged from silt to boulders, while estimated bankfull critical diameter, D_cbf, ranged from very fine gravel to large boulders. The median value of D_cbf (adjusted for form roughness influences) averaged 40% (inter quartile range 28 to 59%) of the unadjusted estimate D_cbf. Log[RBS] was consistently negatively related to human disturbances likely to produce excess sediment inputs or hydrologic alteration. Log [RBS] ranged from − 1.9 to + 0.5 in the streams within the lower quartile of human disturbance in their basin and riparian areas and was substantially lower (− 4.2 to − 1.1) in streams within the upper quartile of human disturbance. The synoptic survey methods and designs we used appear adequate to evaluate regional patterns in bed stability and sedimentation and their general relationship to human disturbances. Although the RBS concept also shows promise for evaluating sediment and bed stability in individual streams, our approach is relatively coarse, so site-specific assessments using these rapid field methods might prudently be confined to identifying severe cases of sedimentation or channel alteration. Greater confidence to discern subtle differences in site-specific assessments could be gained by calculating RBS using more precise field measurements of channel slope, bed particle size and bankfull dimensions, and by refining our adjustments for energy loss from channel form roughness.     

Broad-band calibration of marine seismic sources used by R/V Polarstern for academic research in polar regions

Air guns and air-gun arrays of different volumes are used for scientific seismic surveys with R/V Polarstern in polar regions. To assess the potential risk of these research activities on marine mammal populations, knowledge of the sound pressure field of the seismic sources is essential. Therefore, a broad-band (0–80 kHz) calibration study was conducted at the Heggernes Acoustic Range, Norway. A GI (2.4 l), a G (8.5 l) and a Bolt gun (32.8 l) were deployed as single sources, 3 GI (7.4 l), 3 G (25.6 l) and 8 VLF™ Prakla-Seismos air guns (24.0 l) as arrays. Each configuration was fired along a line of 3–4 km length running between two hydrophone chains with receivers in 35, 100, 198 and 263 m depth. Peak-to-peak, zero-to-peak, rms and sound exposure levels (SEL) were analysed as functions of range. They show the typical dipole-like directivity of marine seismic sources with amplitude cancellation close to the sea surface, higher amplitudes in greater depths, and sound pressure levels which continuously decrease with range. Levels recorded during the approach are lower than during the departure indicating a shadowing effect of Polarsterns's hull. Backcalculated zero-to-peak source levels range from 224–240 dB re 1 μPa @ 1 m. Spectral source levels are highest below 100 Hz and amount to 182–194 dB re 1 μPa Hz^–1. They drop off continuously with range and frequency. At 1 kHz they are ∼30 dB, at 80 kHz ∼60 dB lower than the peak level. Above 1 kHz amplitude spectra are dominated by Polarstern's self-noise. From the rms and sound exposure levels of the deepest hydrophone radii for different thresholds are derived. For a 180 dB rms-level threshold radii maximally vary between 200 and 600 m, for a 186 dB SEL threshold between 50 and 300 m.     

Using Na/K Ratios to Identify the Potential Impacts of Sewage Effluent on Groundwater Quality in Sohag,Egypt

Improper disposal of wastewater is an important source of groundwater contamination, as it poses serious threats to the environment and human health. In this case study, 18 groundwater and 3 sewage effluent samples were collected from the area adjacent to a wastewater treatment plant in Sohag, Egypt. These samples were subjected to detailed chemical and bacteriological analyses to quantify the potential impact of sewage effluent on the groundwater quality using geochemical indicators. The groundwater aquifer in the study area is represented by the highly permeable Qena Sands that are composed of sands and gravels. The bacteriological analyses indicated the presence of fecal coliform in groundwater at wells nearby the wastewater ponds and farm lands. NH₄ concentration of the contaminated groundwater samples ranged from 0.36 to 5.70 mg/L (78% of the samples > 1.20 mg/L) and the NH₄ in the non‐impacted samples ranged from 0.40 to 2.23 mg/L (22% > 1.20 mg/L). Variations in NH₄ concentrations are due to the transformation processes occurring in the aquifer. The groundwater samples were categorized based on the Na/K ratio into two classes. The first class shows the Na/K ratios vary from 2.52 to 12.19 for sewage effluent and contaminated samples, while in the second class they range from 12.85 to 31.60 for non‐impacted samples. As a result, the Na/K ratio in combination with other chemical and microbiological indicators is a useful screening tool for assessing possible sewage influence on shallow groundwater from shallow wells.     

The near-field method: a modified equivalent linear method for dynamic soil–structure interaction analysis. Part II: verification and example application

Usually for modeling of soil in a direct soil–structure interaction (SSI) problem, the equivalent linear soil properties are used. However, this approach is not valid in the vicinity of a foundation, where the soil experiences large strains and a high level of nonlinearity because of structural vibrations. The near-field method was developed and described in a companion paper to overcome this limitation. This method considers the effects of large strains and suggests a shear modulus and a damping ratio further modified in the near-field of a foundation. Validity and performance of this approach are evaluated, application examples are explained and the results of a parametric study about the role of soil and structure parameters in the extent of SSI effects on the nonlinear seismic response of structures are presented in this paper. One real existing and five, ten, fifteen and twenty story moment-resisting frame steel buildings with two different site conditions corresponding to firm and soft soils are considered and the responses obtained from the near-field method are compared with the recorded and rigorous responses. Moreover, various SSI modeling techniques are employed to investigate the accuracy and performance of each approach. The results show that the near-field method is a simple yet accurate enough approach for analysis of direct SSI problems.     

Thermal regime and amplitude of lithosphere extension in the Sirte basin, Libya: Numerical estimates in the plane basin modeling system

The GALO basin modeling system has been applied for the numerical reconstruction of the subsidence history, variations in temperature, and maturity of the organic matter of sedimentary rocks composing the main tectonic structures of Sirte Basin. The reconstruction was carried out for eight sedimentary cross sections along the profile stretching from the Cyrenaica Platform on the eastern coast of the basin to the Hun Graben on its western wall. The interval of depths for temperature calculations included the sedimentary layer, consolidated crust, and the mantle to below 100 km. This extensive depth coverage made it possible to use the analysis of the variations in the tectonic subsidence of the basin for estimating the amplitudes and duration of the events of thermal activation and extension of the lithosphere of the basin in the history of its evolution. The modeling suggests that thermal activations of the lithosphere in the Albian-Cenomanian and Oligocene-Pleistocene are common for all tectonic structures of the Sirte Basin and the Cyrenaica Platform and that a relatively high temperature regime is also characteristic of the present-day conditions in the Sirte Basin and Cyrenaica Platform. To a considerable extent, such a regime is caused by the thermal activation of the lithosphere of the basin during the last 10 Ma. The intensity of this activation is highest in the western part of the basin, where it is accompanied by the highest erosion amplitudes. The analysis of the variations in tectonic subsidence of the basement also suggests a series of intervals of lithospheric extension, which accounts for the stages of relatively rapid subsidence of the basin. Two intervals of significant extension of the lithosphere in the Upper Cretaceous and Paleocene are common for all areas within the basin. Here, the total amplitudes of the crustal extension attained 1.5 in the central part of the Sirte Basin (the Ajdabiya and Maradah troughs and Zelten and Dahra platforms), was equal to 1.3 in the Hameimat and Zallah troughs, and were minimal (1.11–1.17) in the periphery of the basin (within the Hun Graben and Cyrenaica Platform).     

Magnetic signature of indoor air pollution: Household dust study

The combination of magnetic and geochemical methods was used to determine the mineralogy, grain size and domain structure of magnetic particles in indoor dust collected in 195 sites in Warsaw, Poland. Data show an asymmetric distribution of magnetic susceptibility (χ) in the wide range of 20–1514 × 10^?8 m³ kg^?1. Comparison of magnetic parameters shows that the internal dust contains outside pollution characteristic for air and soil. More than 90% of indoor dust samples were characterized by roughly uniform magnetic mineralogy, typical for fine grained magnetite (diameter of 0.2–5 μm), and grain size between pseudo-single-domain and small multi-domain with small contribution of superpara-magnetic particles (～10%). Samples with χ larger than 220 × 10^?8 m³ kg^?1 contain mainly magnetite and an anthropogenic metallic Fe with T _C > 700°C. The indoor dust contains, characteristic for the urban areas, spherical magnetic particles originated from fossil fuel combustion processes and mixture of irregular angular iron-oxides grains containing other elements, including Na, Ca, Al, Si, K, S, Mn, Cl, and Mg.     

Seasonal dynamics of phytoplankton with relation to physicochemical water parameters above and below the hydroelectric plant on the Pasłęka River (North-East Poland)

The study of seasonal dynamics of net phytoplankton was carried out above and below the hydroelectric plant (HP) on the Pas ka River. Correlations were found between the abundance of diatoms and conductivity, O₂, PO₄; the abundance of cyanobacteria and water temperature and conductivity, and the abundance of chlorophytes and O₂ and N_tot. Multiple correlations revealed the most significant factor for diatom development is PO₄, for cyanobacteria is water temperature, and for chlorophytes is N_tot. A lower abundance and biomass of phytoplankton, and less species diversity and nutrient concentrations were registered below the HP than above it. The seasonal dynamics of phytoplankton abundance provided similar results. The maximum biomass of the assemblage was found earlier below the HP, in April, than above it, in May. However, no differences were recorded in the dominant species within phytoplankton abundance. The phytoplankton biomass was dominated by the Melosira varians and Spirogyra sp., which are typical taxa of plant periphyton and possibly emanate from the concrete elements of the dam. This HP changed the local hydrological and environmental conditions, affecting available nutrients, and thereby phytoplankton development in the vegetative season.     

Discovery of a broad iron line in the black hole candidate Swift J1753.5−0127, and the disc emission in the low/hard state revisited

We analysed simultaneous archival XMM–Newton and Rossi X-ray Timing Explorer observations of the X-ray binary and black hole candidate Swift J  1753.5−0127  . In a previous analysis of the same data, a soft thermal component was found in the X-ray spectrum, and the presence of an accretion disc extending close to the innermost stable circular orbit was proposed. This is in contrast with the standard picture in which the accretion disc is truncated at large radii in the low/hard state. We tested a number of spectral models and found that several of them fit the observed spectra without the need of a soft disc-like component. This result implies that the classical paradigm of a truncated accretion disc in the low/hard state cannot be ruled out by these data. We further discovered a broad iron emission line between 6 and 7 keV in these data. From fits to the line profile we found an inner disc radius that ranges between ∼6 and 16 gravitational radii, which can be in fact much larger, up to ∼250 gravitational radii, depending on the model used to fit the continuum and the line. We discuss the implications of these results in the context of a fully or partially truncated accretion disc.     

Applicability of Wakeby distribution in flood frequency analysis: a case study for eastern Australia

Parametric method of flood frequency analysis (FFA) involves fitting of a probability distribution to the observed flood data at the site of interest. When record length at a given site is relatively longer and flood data exhibits skewness, a distribution having more than three parameters is often used in FFA such as log‐Pearson type 3 distribution. This paper examines the suitability of a five‐parameter Wakeby distribution for the annual maximum flood data in eastern Australia. We adopt a Monte Carlo simulation technique to select an appropriate plotting position formula and to derive a probability plot correlation coefficient (PPCC) test statistic for Wakeby distribution. The Weibull plotting position formula has been found to be the most appropriate for the Wakeby distribution. Regression equations for the PPCC tests statistics associated with the Wakeby distribution for different levels of significance have been derived. Furthermore, a power study to estimate the rejection rate associated with the derived PPCC test statistics has been undertaken. Finally, an application using annual maximum flood series data from 91 catchments in eastern Australia has been presented. Results show that the developed regression equations can be used with a high degree of confidence to test whether the Wakeby distribution fits the annual maximum flood series data at a given station. The methodology developed in this paper can be adapted to other probability distributions and to other study areas. Copyright © 2014 John Wiley & Sons, Ltd.