Late Proterozoic older granitoids from the North Eastern desert of Egypt: petrogenesis and geodynamic implications

Major, trace, and REE data for three localities of calc?Calkaline older granitoid rocks exposed in the north Eastern Desert of Egypt are presented. These rocks were selected to cover wide compositional spectrum of the Egyptian older granitoid varieties. They are petrographically represented by granodiorite, tonalite, quartz?Cdiorite, and quartz?Cmonzodiorite. The rocks are comparable with the peraluminous, unfractionated calc?Calkaline suites and fall within the volcanic arc and I-type granite fields. So, they can be regarded as belonging to the volcanic arc collision stage (665?C614?Ma). The granitoids are geochemically similar to other rocks recorded from continental margin arc-systems being exhibit light-REE enriched patterns with variable but chiefly positive Eu anomaly. The latter has reverse relationship with the ??REE, which was attributed to the fractionation of hornblende during partial melting. These patterns are comparable with models involving partial melting of amphibolitic source. This source must represent basalts, gabbros, or volcanics of an island arc system that were transformed to the level of the island arc crust during continental growth where the P?CT conditions are suitable for partial melting. Thus, it is plausible that the studied rocks were derived by partial melting of LREE-enriched, garnet-free, and amphibole-bearing (i.e., hydrated) mafic source. Wadi Milaha granitoids are consistent with the derivation by a high degree of partial melting (30?C40%) of amphibolite protolith in the deep crust. However, the two other localities (Wadi Umm Anab and West Gharib) are matching with 20?C30% partial melting. Within each locality, variation in rock types from granodiorite to tonalite is said to be dominated by variable degree of restite separation during magma ascent. The high water and volatile contents in Wadi Milaha granitoids allowed higher degree of partial melting (30?C40%). Moreover, the lower volatile contents in the other two localities (Wadi Umm Anab and West Gharib) gave lower degrees of partial melting (20?C30%). These processes may resemble important geodynamic features of the Arabo-Nubian Shield evolution in the north Eastern Desert of Egypt.     

Tunisian landfill leachate treatment using <Emphasis Type="Italic">Chlorella</Emphasis> sp.: effective factors and microalgae strain performance

The potential of the autoclaved Tunisian landfill leachate treatment using microalgae (Chlorella sp.) cultivation was investigated in this study. Landfill leachate was collected from Borj Chakir landfill, Tunisia. A full factorial experimental design 2² was proposed to study the effects of the incubation time and leachate ratio factors on the organic matter removal expressed in chemical oxygen demand (COD) and ammoniacal nitrogen (NH₄─N) and on the biological response of Chlorella sp. expressed by the cell density and chlorophyll content. All experiments were batch runs at ambient temperature (25 ± 2 °C). The Chlorella sp. biomass and chlorophyll a concentrations of 1.2 and 5.32 mg L^?1, respectively, were obtained with 10% leachate spike ratio. The obtained results showed that up to 90% of the ammoniacal nitrogen in landfill leachate was removed in 10% leachate ratio spiked medium with a residual concentration of 40 mg L^?1. The maximum COD removal rate reached 60% within 13 days of incubation time indicating that microalgae consortium was quite effective for treating landfill leachate organic contaminants. Furthermore, with the 10% leachate ratio spiked medium, the maximum lipid productivity was 4.74 mg L^?1 d^?1. The present study provides valuable information for potential adaptation of microalgae culture and its contribution for the treatment of Tunisian landfill leachate.     

Iron isotope fractionation in subduction-related high-pressure metabasites (Ile de Groix,France)

Characterisation of mass transfer during subduction is fundamental to understand the origin of compositional heterogeneities in the upper mantle. Fe isotopes were measured in high-pressure/low-temperature metabasites (blueschists, eclogites and retrograde greenschists) from the Ile de Groix (France), a Variscan high-pressure terrane, to determine if the subducted oceanic crust contributes to mantle Fe isotope heterogeneities. The metabasites have δ⁵⁶Fe values of +0.16 to +0.33‰, which are heavier than typical values of MORB and OIB, indicating that their basaltic protolith derives from a heavy-Fe mantle source. The δ⁵⁶Fe correlates well with Y/Nb and (La/Sm)_PM ratios, which commonly fractionate during magmatic processes, highlighting variations in the magmatic protolith composition. In addition, the shift of δ⁵⁶Fe by +0.06 to 0.10‰ compared to basalts may reflect hydrothermal alteration prior to subduction. The δ⁵⁶Fe decrease from blueschists (+0.19 ± 0.03 to +0.33 ± 0.01‰) to eclogites (+0.16 ± 0.02 to +0.18 ± 0.03‰) reflects small variations in the protolith composition, rather than Fe fractionation during metamorphism: newly-formed Fe-rich minerals allowed preserving bulk rock Fe compositions during metamorphic reactions and hampered any Fe isotope fractionation. Greenschists have δ⁵⁶Fe values (+0.17 ± 0.01 to +0.27 ± 0.02‰) similar to high-pressure rocks. Hence, metasomatism related to fluids derived from the subducted hydrothermally altered metabasites might only have a limited effect on mantle Fe isotope composition under subsolidus conditions, owing to the large stability of Fe-rich minerals and low mobility of Fe. Subsequent melting of the heavy-Fe metabasites at deeper levels is expected to generate mantle Fe isotope heterogeneities.     

Flow dynamics at the origin of thin clayey sand lacustrine turbidites: Examples from Lake Hazar,Turkey

Turbidity currents and their deposits can be investigated using several methods, i.e. direct monitoring, physical and numerical modelling, sediment cores and outcrops. The present study focused on thin clayey sand turbidites found in Lake Hazar (Turkey) occurring in eleven clusters of closely spaced thin beds. Depositional processes and sources for three of those eleven clusters are studied at three coring sites. Bathymetrical data and seismic reflection profiles are used to understand the specific geomorphology of each site. X‐ray, thin sections and CT scan imagery combined with grain‐size, geochemical and mineralogical measurements on the cores allow characterization of the turbidites. Turbidites included in each cluster were produced by remobilization of surficial slope sediment, a process identified in very few studies worldwide. Three types of turbidites are distinguished and compared with deposits obtained in flume studies published in the literature. Type 1 is made of an ungraded clayey silt layer issued from a cohesive flow. Type 2 is composed of a partially graded clayey sand layer overlain by a mud cap, attributed to a transitional flow. Type 3 corresponds to a graded clayey sand layer overlain by a mud cap issued from a turbulence‐dominated flow. While the published experimental studies show that turbulence is damped by cohesion for low clay content, type 3 deposits of this study show evidence for a turbulence‐dominated mechanism despite their high clay content. This divergence may in part relate to input variables, such as water chemistry and clay mineralogy, that are not routinely considered in experimental studies. Furthermore, the large sedimentological variety observed in the turbidites from one coring site to another is related to the evolution of a sediment flow within a field‐scale basin made of a complex physiography that cannot be tackled by flume experiments.     

Net radiation over the Aswan High Dam Lake

Summary Net radiation is an essential parameter for estimating evaporation from large water surfaces by energy balance method. Net radiation has been measured for the first time over the Aswan High Dam Lake on the Nile River for 132 days including warm and cold seasons. A high multiple linear correlation coefficient of 0.98 was obtained between the measured net radiation on the one hand and the global solar radiation measured at Aswan and the difference between water and air temperatures measured over the Lake on the other hand.Seven different empirical formulae for estimating the effective outgoing radiation have been applied on the average data measured over the Lake for days of clear sky. It has been found that the Swinbank formula is the best one suitable for the location of the Aswan High Dam Lake.With 2 Figures     

Pore‐scale modeling of surface erosion in a particle bed

A fully coupled transient two‐dimensional model was employed to study fundamentals of flood‐induced surface erosion in a particle bed. The interaction of the liquid and solid phases is the key mechanism related to surface erosion. The solid phase was idealized at a particle scale by using the discrete element method. The fluid phase was modeled at a mesoscale level and solved using the lattice Boltzmann method. The fluid forces applied on the particles were calculated on the basis of the momentum the fluid exchanges with the particle. The proposed approach was used to model both single particles and particle beds subjected to Couette flow conditions. The behavior of both the single particle and the particle bed depended on particle diameter and surface shear fluid velocity. The conducted simulations show that the fluid flow profile penetrates the bed for a small distance. This penetration initiates sheet‐flow and surface erosion as the fluid interacts with particles. The effect of suppressing particle rotation on the fluid‐induced forces on the particle was also examined. Suppressing particle spinning may lead to underestimated erosion rate. Results of fluid and particle velocities were compared against experimental results and appeared to agree with the observed trends.Copyright © 2013 John Wiley & Sons, Ltd.     

Time dependent chemical study of contracting interstellar clouds. II. abundances of oxygen- and sulphur-bearing molecules

Abstract. We have constructed a chemical reaction system in a contracting interstellar cloud. In paper (I) we have presented the details of the physical and chemical scheme and the method of solution. The results of our chemical model produce fractional abundances of H₂CO, CO, OH, H₂O, SO and OCS which are in good agreement with the results of observations. On the other hand, the results of chlorine-bearing species are not in agreement with those of the observations. The calculated abundances of H₂CO, CO, OH, H₂O, SO, OCS and Cl⁺ are in agreement with the results of previous theoretical studies.     

Nonequilibrium solidification and microstructures of metal phases in the shock-induced melt of the Yanzhuang (H6) chondrite

Abstract— Dendrites in the metal-troilite spherules in both shock-induced melt veins and a melt pocket of the Yanzhuang chondrite show zoning in their microstructures. This feature is indicative of nonequilibrium solidification of the metal phases. Dendrites in the melt pocket have a typical crust-core structure consisting of martensitic interiors (7.5–8.1 wt% Ni) and Ni-rich rims (12.5–23.3 wt% Ni). In comparison, the dendrites in melt veins have three microstructural areas: (1) core (6.4–7.3 wt% Ni); (2) martensite between the core and rim (7.4–8.5 wt.% Ni); (3) Ni-rich rim (12.8–21.4 wt% Ni). It is suggested that the difference in cooling rates following shock-induced high temperature melting might be an important factor in producing the different dendritic microstructures in melt veins and melt pocket. Cooling rates deduced from measurements of secondary dendritic arm spacings are 100–400 °C/s in the melt veins and 6–30 °C/s in the melt pocket, respectively, and lie in the temperature interval 950 to 1400 °C.     

Unusual occurrence of glauconite in a shallow lagoonal environment (Lower Cretaceous, northern Aquitaine Basin, SW France)

Some minerals are considered to be representative of specific natural environments. Among them glauconite is considered to be formed in marine deep platform conditions. However, the term glauconitic is misused to designate green minerals formed in marine outer-shelf environments. X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray analyses of individual green materials were carried out leading to the identification of glauconite in the Purbeckian facies. Green glauconite grains predominantly occur as burrow fills and occasionally as faecal pellet replacements. Two depositional environments have been identified from bottom to top of the succession: (1) an argillaceous dolomitic lagoonal sediment formed in saline, shallow water; (2) a marl-limestone alternation deposited in a brackish water estuary. The crystallochemical properties of the glauconites change abruptly. These findings show that glauconite may form in coastal environments and not only in mid-shelf to upper deep water platform environments as classically assumed. Moreover, the glauconite composition changes with the chemical conditions imposed by the local environment.     

Angular radiation transfer in inhomogeneous dispersive media

The equation of radiative transfer for an inhomogenous dispersive finite medium subject to general boundary conditions is solved. The Padé approximation technique is used to calculate the angular distribution of radiation. Numerical results for the [0/1] Padé approximant lead to numerical results that compared with the exact results.