Stability dependence of the drag and bulk transfer coefficients over a coastal sea surface

Bulk transfer coefficients were evaluated from eddy correlation flux measurements on a fixed pier during onshore winds. The mean values are C _D = 1.69 × 10^-3, C _H = 2.58 × 10^-3 and C _E = 1.51 × 10^-3. The drag coefficient, C _D, gradually increases with wind speed but C _H and C _E are independent of wind speed. According to theory and empirical formulas based on experimental results over flat grassland, the transfer coefficients should gradually increase with increasing instability. This is confirmed experimentally in the stable region in our case. However, the drag coefficient appears to decrease with increasing instability, which is against the theoretical result. A stability dependence is not clearly observed for C _H or C _E.     

Synthesis and crystal-chemical characterization of MgSiO3 perovskite

The orthorhombic MgSiO₃ perovskite has been synthesized with the aid of a double-stage split-sphere-type high-pressure apparatus at about 280 kbar and 1000°C. The unit cell dimensions are: a = 4.7754(3)Å, b = 4.9292(4)Å and c = 6.8969(5)Å with the probable space group Pbnm. Calculated density is 4.108 g cm^?3. Crystal structure determination has been carried out by means of both the geometrical simulation (DLS) technique and the ordinary powder X-ray analysis. The results indicate that the MgSiO₃ perovskite is closer to the ideal perovskite than ScAlO₃ perovskite.     

Formation of olivine textures in pallasites and thermal history of pallasites in their parent body

An analysis of the textures of pallasites has been made using data concerning the kinetic and rheological properties of silicates and metals. Pallasites containing rounded olivines (e.g., the Springwater and Brehnam pallasites) have been heated to above the solidus temperature of the metallic iron phases, ～ 1270 K. The rounded olivines of grain size 0.5–1.0 cm observed in the Springwater pallasites were formed between 1270 and 1370 K. On the other hand, those of grain size 0.5–1.0 mm as found in the Brehnam pallasites may have been heated to above 1370 K; however, the duration of heating at such high temperatures must have been less than 5 × 10³ y. Pallasites containing angular olivines with microscopically rounded corners (e.g., the Eagle Station, Dora pallasites) have suffered shock events fracturing the olivine grains, which may correspond to collisions during the accretional stage of the parent body, and experienced successive annealing during cooling from a temperature between 1150 and 1270 K.     

The Kolmogorov constant for carbon dioxide in the atmospheric surface layer over a paddy field

From measurements in the atmospheric surface layer over a paddy field, the Kolmogorov constants for CO₂ and longitudinal wind velocity were obtained. In this study, the nondimensional dissipation rate _nc = (1–16 _v )^-1/2 for CO₂ variance and = (1–16 _v )^-1/4 – _v for turbulent energy were used, assuming the equality of the local production term and the local dissipation term, and neglecting the divergence flux term in the budget equation. The value of the constant for CO₂ was consistent with recent determinations for temperature and humidity. The constant for longitudinal wind velocity showed good agreement with other recent observations.     

High-pressure X-ray diffraction studies on β- and γ-Mg2SiO4

Pressure effects on the lattice parameters of β- and γ-Mg₂SiO₄ have been measured at room temperature and at pressures up to 100 kbar using a multi-anvil high-pressure X-ray diffraction apparatus. The volume changes (ΔV/V₀) at 90 kbar are 5.4 · 10^?2 and 4.2 · 10^?2 for β- and γ-Mg₂SiO₄, respectively. Isothermal bulk moduli at zero pressure have been calculated from least-square fits of the data to straight lines. They turn out to be 1.66 ± 0.4 and 2.13 ± 0.1 Mbar for β- and γ-Mg₂SiO₄, respectively. The α → γ transition obeys Wang's linear V_φ?ρ relation but the α → β transition does not.     

High-pressure synthesis of ZnSiO3 ilmenite

High-pressure phase relations in ZnSiO₃ and Zn₂SiO₄ were investigated at about 1000°C and in the pressure range of 100–500 kbar, using a double-staged split-sphere type of high-pressure apparatus.Clinopyroxene-type ZnSiO₃ transforms directly into a polymorph with the ilmenite structure at 120 kbar. The hexagonal unit cell dimensions of the ZnSiO₃ ilmenite are determined to be $\text{a = 4.746 ± 0.001}\text{A}\text{?}\text{and}\text{c = 13.755 ± 0.002}\text{A}\text{?}$ under ambient conditions.The following reactions are also recognized at about 1000°C:

and:

The stabilities of silicate ilmenites, especially the absence of ilmenite of transition metal silicate composition, is discussed. It is pointed out that data on phase relations in zinc silicates may be informative for the consideration on those in magnesium silicates under very high pressures. It is suggested that the silicate ilmenite may be a major constituent in the lower mantle.     

Melting relations of peridotite and the density crossover in planetary mantles

Melting relations of primitive peridotite were studied up to 25 GPa. The change of the liquidus phase from olivine to majorite occurs at 16 GPa. We confirmed the density crossover of the FeO-rich peridotite melt and the equilibrium olivine (Fo₉₀) at 7 GPa. Sinking of equilibrium olivine (Fo₉₅) in the primitive peridotite melt was observed up to 10 GPa. The compression curves of FeO-rich peridotitic and komatiite melts reported in this and earlier work suggest that the density crossover in the Earth's mantle will be located at 11–12 GPa at 2000°C, consistent with an previous estimation by C.B. Agee and D. Walker.

The density crossover can play a key role in the Moon and the terrestrial planets, such as the Earth, Venus and Mars. Majorite and some fraction of melt could have separated from the ascending diapir and sunk downwards at the depths below the density crossover. This process could have produced a garnet-rich transition zone in the Earth's mantle. The density crossover may exist in the FeO-rich lunar mantle at around the center of the Moon. The density crossover which exists at the depth of 600 km in the Martian mantle plays a key role in producing a fractionated mantle, which is the source the parent magmas of the SNC meteorites.     

Partitioning of heavy metals into mineral and organic fractions in a sediment core sample from Osaka Bay

Partitioning of copper, zinc, iron and manganese into oxide, sulfide, organic and silicate fractions has been determined with a selective chemical leaching technique on sediment samples from a core collected in Osaka Bay. The samples have been dated by the²¹⁰Pb method. Most of the copper and zinc in the polluted surface sediment layer are contained in both oxide and sulfide fractions. This suggests that the transformation of oxides and hydroxides to sulfides under anoxic conditions within the sediment is significant for the fixation of copper and zinc discharged through human activities into the sediment. Manganese is apparently enriched in oxide and hydroxide fractions of the surface layer due to the post-depositional migration of manganese within the sediment. The copper, zinc and manganese contents of the 30 % H₂O₂ soluble fraction (mostly organic fraction) decrease with depth in the sediment core, and correlate significantly with the organic carbon content. The heavy metal (Cu, Zn, Fe and Mn) contents of the silicate fraction, without exchangeable sites, are almost constant with depth.     

The international at-sea intercomparison of fCO2 systems during the R/V Meteor Cruise 36/1 in the North Atlantic Ocean

The ‘International Intercomparison Exercise of fCO₂ Systems’ was carried out in 1996 during the R/V Meteor Cruise 36/1 from Bermuda/UK to Gran Canaria/Spain. Nine groups from six countries (Australia, Denmark, France, Germany, Japan, USA) participated in this exercise, bringing together 15 participants with seven underway fugacity of carbon dioxide (fCO₂) systems, one discrete fCO₂ system, and two underway pH systems, as well as systems for discrete measurement of total alkalinity and total dissolved inorganic carbon. Here, we compare surface seawater fCO₂ measured synchronously by all participating instruments. A common infrastructure (seawater and calibration gas supply), different quality checks (performance of calibration procedures for CO₂, temperature measurements) and a common procedure for calculation of final fCO₂ were provided to reduce the largest possible amount of controllable sources of error. The results show that under such conditions underway measurements of the fCO₂ in surface seawater and overlying air can be made to a high degree of agreement (±1 μatm) with a variety of possible equilibrator and system designs. Also, discrete fCO₂ measurements can be made in good agreement (±3 μatm) with underway fCO₂ data sets. However, even well-designed systems, which are operated without any obvious sign of malfunction, can show significant differences of the order of 10 μatm. Based on our results, no “best choice” for the type of the equilibrator nor specifics on its dimensions and flow rates of seawater and air can be made in regard to the achievable accuracy of the fCO₂ system. Measurements of equilibrator temperature do not seem to be made with the required accuracy resulting in significant errors in fCO₂ results. Calculation of fCO₂ from high-quality total dissolved inorganic carbon (C_T) and total alkalinity (A_T) measurements does not yield results comparable in accuracy and precision to fCO₂ measurements.