New particle formation by ion-induced nucleation during dissipation stage of thunderstorm

A case of new particle formation observed during dissipation stage of a thunderstorm at a tropical station, Pune, India on 3 June 2008 is reported. The flash rate and rainfall intensity increased as high as 110 flashes per 5 minutes and 150 mm hour^− 1 respectively during the active stage of thunderstorm, and then gradually decreased during the dissipation stage. The number concentration of particles in the size range of 10–100 nm sharply increased from 350 particles cm^− 3 to ∼8000 particles cm^− 3 during the dissipation stage of a thunderstorm and grew to larger diameter subsequently. Observations suggest that the atmospheric conditions such as (i) reduced background aerosol concentration after heavy rain, (ii) high humidity condition, and (iii) increased ion concentration during the dissipation stage by corona discharges, favoured generation of new particles by ion-induced nucleation (IIN). Observations also suggest that generation of unipolar ions by corona discharges may be more favourable for IIN and subsequent growth of the particles.     

Atmospheric ultrafine aerosol number concentration and its correlation with vehicular flow at two sites in the western Himalayan region: Kullu-Manali,India

The concentration of ultrafine aerosol particles of aitken and nucleation mode having size in the range of 1–20 nm was monitored with water-based Condensation Particle Counter. The monitoring was carried out from midnight-to-midnight in every alternate day on a fortnightly basis to represent summer, monsoon and winter (autumn) seasons of 2008 at Mohal (1154 m amsl) and Kothi (2530 m amsl) in Kullu-Manali area of the northwestern Himalayan region of India. The results indicate that diurnal pattern has faint bimodal structure with two peaks, one in morning and the other in evening at both the sites but it is not as distinct as found in plains. There is rather a constant particle density pattern of large magnitude consistent with vehicular movement from morning till evening. The monthly 24 h average particle density gradually picks up from January, increases rapidly in summer months and then decreases in monsoon season at Mohal but at Kothi it keeps on rising from April to October with a slight more increase in September. The particle density is more in summer than in monsoon season at Mohal, a trend opposite to plains. It may be due to the development of warm thermal layer on valley floor while a cold layer develops along snowy hilltops in winter leading to convection of fine particle up the slopes of valley during daytime. At Kothi, the trend is same as it is in continental plains but opposite to Mohal. The relatively more value of particle density in September and October at both the sites may be due to month long International Kullu Dussehra fair in the valley. The vehicular survey conducted agrees well with entire study period averaged diurnal variations and monthly 24 h averaged value of fine particle density. The average value of ultrafine particle density at each hour of a day for entire study period is 20369 ± 1230 Ncm^− 3 and 14389 ± 1464 Ncm^− 3 at Mohal and Kothi sites, respectively. The comparison with earlier results shows a significant increase indicating impact of vehicular onslaught on pure air of this hilly region.     

Study on capillary rise from shallow groundwater and critical water table depth of a saline-sodic soil in western Songnen plain of China

The objective of this study was to develop an empirical equation for estimating the capillary rise in the saline-sodic soil area of Songnen Plain in China based on the Averianov formula. The capillary rise was observed under five controlled groundwater levels by lysimeters. Field experiment results indicated that capillary rise had close relationship with the groundwater table depth, soil moisture of 10–40 cm soil layer and leaf area index. These factors have been taken into account to develop the empirical equation for capillary rise simulation. The model parameters for Songnen Plain were derived by Levenberg–Marquardt and global optimization calculating method. The modeled capillary rise has a good agreement with the observed data (r ² = 0.875). With the simulation model, the critical water table depth was identified as 2.5 m, indicating that soil secondary salinization will not occur when the water table depth is deeper than 2.5 m. Therefore, in the irrigation areas, groundwater table depth should be controlled to be higher than 2.5 m to prevent the occurrence of soil secondary salinization. The results from this research will provide useful information for the water sources management and soil secondary salinization control in Songnen Plain of China, one of the most serious saline-affected areas in the world.     

Discovery of Ordovician–Silurian metamorphic monazite in garnet metapelites of the Alpine External Aiguilles Rouges Massif

The pre-Mesozoic, mainly Variscan metamorphic basement of the Col de Bérard area (Aiguilles Rouges Massif, External domain) consists of paragneisses and micaschists together with various orthogneisses and metabasites. Monazite in metapelites was analysed by the electron microprobe (EMPA-CHIME) age dating method. The monazites in garnet micaschists are dominantly of Variscan age (330–300 Ma). Garnet in these rocks displays well developed growth zonations in Fe–Mg–Ca–Mn and crystallized at maximal temperatures of 670°C/7 kbar to the west and 600°C/7–8 kbar to the east. In consequence the monazite is interpreted to date a slightly pressure-dominated Variscan amphibolite-facies evolution. In mylonitic garnet gneisses, large metamorphic monazite grains of Ordovician–Silurian (~440 Ma) age but also small monazite grains of Variscan (~300 Ma) age were discovered. Garnets in the mylonitic garnet gneisses display high-temperature homogenized Mg-rich profiles in their cores and crystallized near to ~800°C/6 kbar. The Ordovician–Silurian-age monazites can be assigned to a pre-Variscan high-temperature event recorded by the homogenised garnets. These monazite age data confirm Ordovician–Silurian and Devonian–Carboniferous metamorphic cycles which were already reported from other Alpine domains and further regions in the internal Variscides.     

Light Requirements for Growth and Survival of Eelgrass (<Emphasis Type="Italic">Zostera marina</Emphasis> L.) in Pacific Northwest (USA) Estuaries

We developed light requirements for eelgrass in the Pacific Northwest, USA, to evaluate the effects of short- and long-term reductions in irradiance reaching eelgrass, especially related to turbidity and overwater structures. Photosynthesis-irradiance experiments and depth distribution field studies indicated that eelgrass productivity was maximum at a photosynthetic photon flux density (PPFD) of about 350–550 μmol quanta m⁻² s⁻¹. Winter plants had approximately threefold greater net apparent primary productivity rate at the same irradiance as summer plants. Growth studies using artificial shading as well as field monitoring of light and eelgrass growth indicated that long-term survival required at least 3 mol quanta m⁻² day⁻¹ on average during spring and summer (i.e., May-September), and that growth was saturated above about 7 mol quanta m⁻² day⁻¹. We conclude that non-light-limited growth of eelgrass in the Pacific Northwest requires an average of at least 7 mol quanta m⁻² day⁻¹ during spring and summer and that long-term survival requires a minimum average of 3 mol quanta m⁻² day⁻¹.     

Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics

Molybdenum disulfide (MoS₂), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS₂ is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia.     

Investigating a reservoir bank slope displacement history with multi-frequency satellite SAR data

Slope instability arisen along with dam construction is a common problem of great concern in reservoir areas. Thus, displacement monitoring of active slopes is of great importance for the safety of dam operation. The unstable Guobu slope is located only about 1.5 km away from Laxiwa hydropower station in upstream Yellow River. In this study, Synthetic Aperture Radar (SAR) datasets acquired by C-band Environmental Satellite (ENVISAT) Advanced Synthetic Aperture Radar (ASAR), L-band Advanced Land Observing Satellite 2 (ALOS-2) Phased Array type L-band Synthetic Aperture Radar 2 (PALSAR-2), and X-band TerraSAR-X covering different evolution stages of Guobu slope were collected to investigate the displacement history so as to facilitate understanding of its deformation and failure mechanisms. The displacements occurred during the past decade were quantitatively identified for the first time by SAR pixel offset tracking analyses. The results show that before the reservoir impoundment, the maximum accumulative displacements on the slope were more than 7 m from 2003 to 2008, while the post-impoundment displacements also exceeded 7 m in just 1 year from September 2009 to September 2010. Furthermore, this slope is still in active deformation up to now. Nevertheless, the displacement rates seem decreased recently according to the interferometric results of TerraSAR-X data pairs from September 2015 to March 2016.     

A New Equation for the Shear Strength of Cable Bolts Incorporating the Energy Balance Theory

The application of cable bolts as a secondary support system is an increasing trend in underground coal mines worldwide. The performances of cable bolts have been evaluated under both axial and shear loading conditions. Two methods of testing cables for shear, single and double shear, have been recognised. This paper examines the shear behaviour of a variety of cable bolts under different pre-tension loads by double shear testing. Plain, spiral and the combination of both cable types were used in this study. The initial axial load and the type of cable bolts are the main factors affecting their shear strength. By increasing the axial pre-tension load, the peak shear load occurs at lower shear displacement. The failure angle due to cable bending across the joint at different pre-tension loads varied between 41° and 49°. This demonstrates that the ratio of axial and perpendicular displacements is almost constant and on average the failure occurs at about 45°. A novel analytical model is proposed to evaluate the shear behaviour of pre-tensioned fully grouted cable bolts subjected to double shearing. Energy and Fourier Series methods were incorporated in the model to simulate the shear behaviour of cable bolts. The comparison of the experimental results with the proposed model shows a good agreement.     

Estimation of groundwater recharge using the soil moisture budget method and the base-flow model

A detailed characterization of the site is crucial to designing an efficient method of managing the risks associated with tailings from abandoned mines. Therefore, samples collected from various depths within tailings in Guryong mine, Korea, were analyzed for their chemical, physical and mineralogical characteristics. All samples of the Guryong tailings had acid-generating potential. However, in the oxidation zone, the net acid generation (NAG) was low (30 kg H₂SO₄ t⁻¹) although the acid neutralization potential (ANP) was less than zero. The ANP values in the unoxidation zone were higher (> −56.0 kg CaCO₃ t⁻¹) than in the other zones. As a result, the amount of alkali ions that are needed to neutralize the acid needs to be considered. In this experiment G3, G4 and G6 drill cores containing fine tailings particles near the unoxidation zone were observed to contain calcite (CaCO₃) with acid-neutralizing capacity. A low pH (2−4) in the oxidation zone of the tailings changed to a neutral pH in the unoxidation zone of the tailings. These results suggest that the acid-neutralizing capacity of the tailings was controlled by particle and mineral composition of tailings.     

Settlement and Recruitment Patterns of the Soft-Shell Clam, <Emphasis Type="Italic">Mya arenaria</Emphasis>, on the Northern Shore of the Bay of Fundy,Canada

To examine the roles of settlement and early postsettlement processes in the recruitment of the soft-shell clam, Mya arenaria, abundance of recent settlers and juveniles was monitored over two field seasons at four locations on the northern shore of the Bay of Fundy in New Brunswick, Canada. Results showed great spatial and temporal variability in patterns of settlement. M. arenaria appeared to become highly vulnerable to postsettlement processes at a shell length of approximately 2 mm. Postsettlement processes drastically altered patterns of settlement less than 1 year after they were established. Results suggest that local factors at specific sites within the Bay of Fundy, such as hydrodynamics, larval behavior, and early postsettlement events, likely control the abundance of juvenile clams. Additionally, postsettlement events are extremely important in shaping M. arenaria populations in this area. Very few mature adult clams greater than 50 mm in shell length were found at any sampling sites, and no relationship was found between abundance of setters and density of juveniles and adults.