Long-term thermo-mechanical behavior of energy pile in dry sand

A small-scale pile has been developed in the laboratory to investigate the thermo-mechanical behavior of energy piles subjected to a significant number of thermal cycles. The pile (20 mm external diameter), installed in dry sand, was initially loaded at its head to 0, 20, 40 and 60% of its ultimate bearing capacity (500 N). At the end of each loading step, 30 heating/cooling cycles were applied. The long-term behavior of the pile was observed in terms of head settlement, axial force profile, soil and pile temperature, and stress in soil. The results evidence the irreversible settlement of the pile head induced by thermal cycles under constant load head. In addition, the incremental irreversible settlement that accumulates after each thermal cycle decreases when the number of cycles increases. The evolution of irreversible pile head settlement versus number of cycles can be reasonably predicted by an asymptotic equation.     

Brown algae overproduce cell wall polysaccharides as a protection mechanism against the heavy metal toxicity

Brown algae are often used as heavy metal biomonitors and biosorbents because they can accumulate high concentrations of metals. Cation-exchange performed by cell wall polysaccharides is pointed out as the main chemical mechanism for the metal sequestration. Here, we biochemically investigated if the brown alga Padina gymnospora living in a heavy metal contaminated area would modify their polysaccharidic content. We exposed non-living biomass to Cd and Pb and studied the metals adsorption and localization. We found that raw dried polysaccharides, sulfate groups, uronic acids, fucose, mannose, and galactose were significantly higher in contaminated algae compared with the control ones. Metal concentrations adsorbed by non-living biomass were rising comparatively to the tested concentrations. Electron microscopy showed numerous granules in the cell walls and X-ray microanalysis revealed Cd as the main element. We concluded that P. gymnospora overproduces cell wall polysaccharides when exposed to high metal concentrations as a defense mechanism.     

Investigating the hydromechanical behaviour of bentonite pellets by swelling pressure tests and discrete element modelling

Acta Geotechnica - Bentonite pellet mixtures are candidate material for the sealing of galleries in radioactive waste disposals. The hydromechanical behaviour of assemblies of bentonite pellets is...     

Nature and origin of the BIF-hosted São Bento gold deposit, Quadrilátero Ferrífero, Brazil, with special emphasis on structural controls

The orogenic banded iron formation (BIF)-hosted Au mineralization at São Bento is a structurally-controlled, hydrothermal deposit hosted by Archean rocks of the Rio das Velhas greenstone belt, Quadrilátero Ferrífero region, Brazil. The deposit has reserves of 14.3 t Au and historical (underground) production of 44.6 t Au between 1987 and 2001. The oxide-facies São Bento BIF is mineralized at its lower portion, where in contact with carbonaceous, pelitic schists, particularly in the proximity of sulfide-bearing quartz veins. Shear-related Au deposition is associated with the pervasive, hydrothermal sulfidation (mainly arsenopyrite) of the Fe-rich bands of the São Bento BIF. Auriferous, sulfide- and quartz-rich zones represent proximal alteration zones. They are enveloped by ankerite-dominated haloes, which reflect progressive substitution of siderite and magnetite within the BIF by ankerite and pyrrhotite, respectively. The São Bento BIF was intensely and extensively deformed, first into open, upright folds that evolved into tight, asymmetric, isoclinal folds. The inverse limb of these folds attenuated and gave way to sheath folds and the establishment of ductile thrusts. Mineralized horizons at São Bento result from early structural modifications imposed by major transcurrent and thrusts faults, comprising the Conceição, Barão de Cocais and São Bento shear zones. Dextral movement on the SW–NE-directed Conceição shear zone may have generated splays at a compressional side-stepping zone, such as the São Bento shear zone, which is the structural locus for the São Bento gold mineralization. Relaxation of the Conceição shear zone under more brittle conditions resulted in the development of dilatational zones where gold–sulfide–quartz veins formed. These structures are considered to have been generated in the Archean. Geochronological data are scarce, with Pb–Pb analyses of refractory arsenopyrite and pyrite from bedded and remobilized ore plotting on a single-stage growth curve at 2.65 Ga. A later compressional, ductile deformation of unknown age overprinted, rotated and flattened the original, N60E-directed structure of the whole rock succession, with development of planar and linear fabrics that appear similar to Proterozoic-aged structures. Fluid inclusion studies indicate low salinity, aqueous fluids, with or without CO₂ and/or CH₄, with extremely variable CO₂/CH₄ ratios, of probable metamorphic origin. Fluid evolution shows a paragenetic decrease in the carbonic phase from 10–15% to 5%, and increase in the H₂O/(CO₂ + CH₄) and CO₂/CH₄ ratios, suggesting important interaction with carbonaceous sediment. Trapping conditions indicate a temperature of 300 °C at 3.2 kbar.     

New 40Ar/39Ar constraints for the “Grande Nappe”: The largest rhyolitic eruption from the Mont-Dore Massif (French Massif Central)

Since the 1960s, an early explosive activity in the Mont-Dore Massif is associated with a major pyroclastic rhyolitic eruption (5–7 km³) known as the “Grande Nappe” (GN). This event, linked to the formation of a 6-km-diameter cryptic caldera named “Haute Dordogne”, was before our investigation dated by ⁴⁰Ar/³⁹Ar at 3.07 ± 0.04 Ma. Our new single-crystal laser fusion ⁴⁰Ar/³⁹Ar dates obtained on two outcrops of the GN (Rochefort-Montagne and Ludières) questioned several hypotheses made concerning this “landmark” event of the Mont-Dore Massif history. We demonstrate that: (1) the GN rhyolitic eruption has occurred much later than previously estimated (i.e. 2.77 ± 0.02–0.07 Ma full external uncertainties); (2) the correlation made between the Vendeix rhyolitic complexes (intra-caldera position) dated back to 2.74 ± 0.04 Ma and the GN is proposed; (3) xenocryst contamination could be very high (i.e. 70% for the Rochefort-Montagne GN outcrop) and explains the noticeable older age obtained previously; (4) a link between the GN eruption and the formation of a caldera is questionable; the hypothesis of a northward-oriented blast channeled eastward toward the paleo-Allier River is thus proposed.     

Thermal history of inter-cluster relativistic electron gas heated by quasars

The thermal evolution of an inter-cluster gas of relativistic electrons heated by quasars with redshifts up toz=3 and 4 is studied in the framework of a Friedmann-Robertson-Walker universe. The gas cools by Compton scattering with the microwave backgroud radiation and by adiabatic cooling due to the universe expansion. Power and exponential laws of cosmological evolution of the comoving density of sources are considered. The obtained temperatures are sensitive to the form of these laws and to the heating epochs. Compared to the nonrelativistic models, the results obtained in the case of the power law present strong differences. These differences decrease when the exponential law is considered. Thermalization times are compared to the characteristic time of variation of the universe energy density and to the time-scales of energy loss by bremsstrahlung radiation and by Compton scattering. It is shown that, in some cases, nonequilibrium effects may be important. The time delay effects in the propagation of electromagnetic waves in cosmic plasma are shown to be very important for the analysis of theoretical models.     

Estimates of coda Q attenuation in the João Câmara area (Northeastern Brazil)

S coda wave of seventy-four local earthquakes recorded in a network of ten seismic stations were used to calculate coda Q attenuation (Q_c) in the João Câmara area (northeastern Brazil). The estimates show Q_c as a strong function of frequency in the range from 6.0 to 20.0 Hz. We found out that Q_c in João Câmara has a functional form given by Q_c= Q₀ f, where Q₀= 151 ± 99 and = 0.98 ± 0.05. If the standard deviations are taken into account,we conclude that there are no relevant changes in both Q₀ and values from one station to another. The estimated Q₀ values at the different stations suggest that the Samambaia fault is a boundary between two different seismic attenuation zones. In one side of the fault (left), where stations were installed in Pre-Cambrian terrain and thick sedimentary layer, the seismic attenuation is stronger than in the other side (stations installed in thin sedimentary layer and limestone outcrop).The anomalous Q₀ values in the left side of the Samambaia fault can be explained due to the presence of a shallow conductive layer in the upper crust( 10 km), such as proposed by Padilha et al. (1992). According to our results, if there is a conductive layer in the area, it probably spreads over João Câmara city and surrounding regions.However, more detailed investigation either with seismic methods (seismic attenuation,3D tomography with P and/or S wave velocities) or with other geophysical methods is needed to interpret the observed differences in Q₀ values between the two sides of the Samambaia fault.     

Search for Spatial Structures at Scales Z∼ 1. III. The Effect of Lensing on QSO ?

We carried out a search for peak in homogeneities in the distribution of matter – namely clumps and voids, within the range Z ∼ 1-3. We used a new method, based on the lensing of quasars by a combination of lenses, belonging to the above sought in homogeneities in the matter distribution. This work confirms the evidence of the existence of in homogeneities found by us earlier – of a clump (superattractor N.1), and of a void(supervoid). Besides, the existence of a new gigantic clump (superattractorN.2) was also discovered at Z ∼ 3. These clumps could well serve ascenters of the Bose-condensation in the early Universe; in particular –as Anselm's arion condensate, which leads to the formation of quasiperiodic structures with a period p ∼ 100-200 Mpc. This revised version was published online in July 2006 with corrections to the Cover Date.     

Influence of damage on pore size distribution and permeability of rocks

The model proposed in this article relates permeability to porosity measurements that can easily be performed in the laboratory. The pore size distribution (PSD) curve is updated with strains and damage. The updated volumetric fractions of natural pores and cracks are introduced in the expression of permeability. Contrary to classical permeability models based on PSD integrations, the model proposed in this article accounts for possible changes in the porosity modes: one mode for undamaged samples and two modes for cracked samples. The proposed approach also accounts for varying states of damage, as opposed to classical fracture network models, in which the cracks pattern is fixed. The only material parameters that are required to describe the microstructure are the lower and upper bounds of the pores size for both natural pores and cracks. All the other PSD parameters involved in the model are related to macroscopic parameters that can easily be determined in the laboratory, such as the initial void ratio. The framework proposed in this article can be used in any damage constitutive model to determine the permeability of a brittle porous medium. Drained triaxial compression tests have been simulated. Before cracks initiation, permeability decreases while the larger natural pores are getting squeezed. After the occurrence of damage, permeability grows due to the increase of cracks density. The model performs well to represent the influence of the confining pressure on damage evolution and permeability variations. Copyright © 2012 John Wiley & Sons, Ltd.     

Vitellogenin in winter flounder (Pleuronectes americanus) from Long Island Sound and Boston Harbor

Vitellogenin is an egg-yolk precursor protein in teleosts which is crucial to the survival of larvae. Manufactured in the liver, where pollutants are known to accumulate, and transported to the ovary by the blood, its synthesis by the liver or uptake by the gonad can be compromised by accumulation of xenobiotics. In three studies, winter flounder (Pleuronectes americanus) blood samples were taken to determine normal levels of vitellogenin during the reproductive cycle, and to learn how its production might be affected in degraded environments. Specifically, these studies followed the seasonal cycle of vitellogenin production in winter flounder through monthly sampling at relatively clean (Shoreham, New York) and degraded areas (Black Rock and New Haven harbors, Connecticut) in Long Island Sound; examined the relationship between parental vitellogenin levels and survival of offspring by sampling fish that had been spawned at the Milford Laboratory for a reproductive success study; and determined the effect of gross liver lesions on vitellogenin production by sampling flounder from Boston Harbor, Massachusetts, which have been reported to have a high prevalence of liver tumors. Blood vitellogenin levels were determined by measuring alkali-labile phosphate (ALP). Large fish (>30 cm) from the two degraded sites had elevated serum ALP levels relative to those from the clean area. Lowered total ovarian lipid levels in large fish from Black Rock Harbor suggested impaired vitellogenin uptake. There were no significant differences in serum ALP among the small (≤30 cm) fish from the three sampling sites. Boston Harbor flounder with gross liver lesions had lower ALP values than fish without such lesions. There were no significant differences in ALP values among the spawned fish.