The role of hydrograph indices in parameter estimation of rainfall–runoff models

A reliable prediction of hydrologic models, among other things, requires a set of plausible parameters that correspond with physiographic properties of the basin. This study proposes a parameter estimation approach, which is based on extracting, through hydrograph diagnoses, information in the form of indices that carry intrinsic properties of a basin. This concept is demonstrated by introducing two indices that describe the shape of a streamflow hydrograph in an integrated manner. Nineteen mid‐size (223–4790 km²) perennial headwater basins with a long record of streamflow data were selected to evaluate the ability of these indices to capture basin response characteristics. An examination of the utility of the proposed indices in parameter estimation is conducted for a five‐parameter hydrologic model using data from the Leaf River, located in Fort Collins, Mississippi. It is shown that constraining the parameter estimation by selecting only those parameters that result in model output which maintains the indices as found in the historical data can improve the reliability of model predictions. These improvements were manifested in (a) improvement of the prediction of low and high flow, (b) improvement of the overall total biases, and (c) maintenance of the hydrograph's shape for both long‐term and short‐term predictions. Copyright © 2005 John Wiley & Sons, Ltd.     

Long‐term spruce budworm outbreak dynamics reconstructed from subfossil trees

We reconstructed the long‐term spruce budworm (SBW) (Choristoneura fumiferana Clem.) outbreak dynamics in the boreal forest of Quebec (Canada) using a dendrochronological approach with subfossil trees. Although the majority of the excavated wood belonging to the genus Picea could potentially reveal the past activity of spruce budworms in the tree rings, very few were cross‐dated due to a lack of marker rings. All cross‐dated trees were found within a particular zone of the peat bogs and the floating chronology was radiocarbon dated to ca. 5.1 cal ka BP. The results presented in this study suggest that the dynamics of SBW outbreaks in the studied area fluctuated during the last millennia and that severe outbreaks as observed during the 20th century seldom occurred in that part of the boreal forest since the end of the last glaciation. These results are in agreement with observations from other parts of eastern North America. Copyright © 2011 John Wiley & Sons, Ltd.     

Experimental study of cadmium interaction with periphytic biofilms

This study addresses the interaction of Cd with natural biofilms of periphytic diatoms grown during different seasons in metal-contaminated and metal-non-contaminated streams, along a tributary of the Lot River, France. Specifically, it aims to test whether the biofilms from contaminated sites have developed a protective mechanism due to high Cd exposure. Towards this goal, reversible adsorption experiments on untreated biofilms were performed in 0.01 M NaNO₃ with a pH ranging from 2 to 8, Cd concentration from 0.5 to 10,000 μg/L and exposure time from 1 to 24 h. Two types of experiments, pH-dependent adsorption edge and constant-pH “Langmuirian”-type isotherms were conducted. Results were adequately modeled using a Linear Programming Model. It was found that the adsorption capacities of natural biofilm consortia with respect to Cd do not depend on season and are not directly linked to the growth environment. The biofilms grown in non-contaminated (4.6 ppb Cd in solid) and contaminated (570 ppb Cd in solid) settings exhibit similar adsorption capacities in the Cd concentration range in solution of 100–10,000 μg/L but quite different capacities at low Cd concentration (0.5–100 μg/L); unexpectedly, the non-contaminated biofilm adsorbs approximately 10 times more Cd than the contaminated one. It is therefore possible that the strong low-abundant ligands (for example, phosphoryl or sulfhydryls) are already metal-saturated on surfaces of biofilm grown in the contaminated site whereas these sites are still available for metal adsorption in samples grown in non-contaminated sites.     

A Compilation of Silicon and Thirty One Trace Elements Measured in the Natural River Water Reference Material SLRS-4 (NRC-CNRC)

The natural river water certified reference material SLRS-4 (NRC-CNRC, National Research Council-Conseil National de Recherches Canada) has been routinely analysed for major and trace elements by six French laboratories. Most measurements were made using inductively coupled plasma-mass spectrometry. For silicon and thirty one trace elements (rare earth elements, Ag, B, Br, Cs, Ga, Ge, Li, P, Pd, Rb, Se, Th, Ti, Tl, W, Y and Zr), no certified values are assigned by NRC-CNRC. We propose some compilation values and related uncertainties according to the results obtained by the different laboratories.     

New geological insights and structural control on fluid circulation in La Fossa cone (Vulcano,Aeolian Islands,Italy)

Electric resistivity tomography (ERT), self-potential (SP), soil CO₂ flux, and temperature are used to study the inner structure of La Fossa cone (Vulcano, Aeolian Islands). Nine profiles were performed across the cone with a measurement spacing of 20 m. The crater rims of La Fossa cone are underlined by sharp horizontal resistivity contrasts. SP, CO₂ flux, and temperature anomalies underline these boundaries which we interpret as structural limits associated to preferential circulation of fluids. The Pietre Cotte crater and Gran Cratere crater enclose the main hydrothermal system, identified at the centre of the edifice on the base of low electrical resistivity values (<20 Ω m) and strong CO₂ degassing, SP, and temperature anomalies. In the periphery, the hydrothermal activity is also visible along structural boundaries such as the Punte Nere, Forgia Vecchia, and Palizzi crater rims and at the base of the cone, on the southern side of the edifice, along a fault attributed to the NW main tectonic trend of the island. Inside the Punte Nere crater, the ERT sections show an electrical resistive body that we interpret as an intrusion or a dome. This magmatic body is reconstructed in 3D using the available ERT profiles. Its shape and position, with respect to the Pietre Cotte crater fault, allows replacing this structure in the chronology of the development of the volcano. It corresponds to a late phase of activity of the Punte Nere edifice. Considering the position of the SP, soil CO₂ flux, and temperature maxima and the repartition of conductive zones related to hydrothermal circulation with respect to the main structural features, La Fossa cone could be considered as a relevant example of the strong influence of pre-existing structures on hydrothermal fluid circulation at the scale of a volcanic edifice.     

Improving interpolation of daily precipitation for hydrologic modelling: spatial patterns of preferred interpolators

Detailed hydrologic models require high‐resolution spatial and temporal data. This study aims at improving the spatial interpolation of daily precipitation for hydrologic models. Different parameterizations of (1) inverse distance weighted (IDW) interpolation and (2) A local weighted regression (LWR) method in which elevation is the explanatory variable and distance, elevation difference and aspect difference are weighting factors, were tested at a hilly setting in the eastern Mediterranean, using 16 years of daily data. The preferred IDW interpolation was better than the preferred LWR scheme in 27 out of 31 validation gauges (VGs) according to a criteria aimed at minimizing the absolute bias and the mean absolute error (MAE) of estimations. The choice of the IDW exponent was found to be more important than the choice of whether or not to use elevation as explanatory data in most cases. The rank of preferred interpolators in a specific VG was found to be a stable local characteristic if a sufficient number of rainy days are averaged. A spatial pattern of the preferred IDW exponents was revealed. Large exponents (3) were more effective closer to the coast line whereas small exponents (1) were more effective closer to the mountain crest. This spatial variability is consistent with previous studies that showed smaller correlation distances of daily precipitation closer to the Mediterranean coast than at the hills, attributed mainly to relatively warm sea‐surface temperature resulting in more cellular convection coastward. These results suggest that spatially variable, physically based parameterization of the distance weighting function can improve the spatial interpolation of daily precipitation. Copyright © 2009 John Wiley & Sons, Ltd.     

Field evidence of hydraulic connections between bedrock aquifers and overlying granular aquifers: examples from the Grenville Province of the Canadian Shield

Field evidence of hydraulic connections between a bedrock aquifer and an overlying granular aquifer in the Canadian Shield (Grenville Province) is presented. This issue is rarely considered and investigated despite its important hydraulic and chemical consequences and its widespread occurrence worldwide. The methodology employed is based on complementary field tests conducted at specific experimental sites instrumented both in the rock and in the overlying deposits. One of the bedrock sites revealed a natural hydraulic connection with the overlying granular aquifer caused by the weathered surface of the uppermost bedrock. Another site revealed an artificial hydraulic connection between the bedrock and the granular aquifer created by an improperly sealed casing. A regional study showed that hydraulic connections yield an erroneous interpretation of the true hydraulic properties of the tested aquifer. The detection of hydraulic connections is therefore essential to properly define well-capture areas and contamination conditions. It is recommended to practitioners that pumping tests be performed as well as hydrochemical comparisons of each existing aquifer unit. Falling-head permeability tests are also helpful in verifying the quality of the seal at the bedrock–casing contact. More effective procedural controls and better well-construction practices are necessary to reduce the risks of cross-contamination induced by defective seals.