Using inverse modeling and hierarchical cluster analysis for hydrochemical characterization of springs and Talkhab River in Tang-Bijar oilfield,Iran

Hierarchical cluster analysis (HCA) and inverse modeling (PH REdox EQuilibrium (in C language) (PHREEQC)) were simultaneously useful approaches in interpreting surface water hydrochemistry within Talkhab River in the Tang-Bijar oilfield, Iran, where large uncertainties exist in the understanding of the water quality system. Q-mode HCA applied to the data revealed three major surface water associations distinguished on the basis of the major causes of variation in the hydrochemistry. The three water groups were classified as upstream waters (group 1: Ca–SO₄), intermediate waters (group 2: Ca–SO₄–Cl), and downstream waters (group 3: Na–Cl). Geochemical reaction models were constructed using PHREEQC to establish the reactions associated with the different mineral phases through inverse modeling. The hydrochemical compositions of the water groups and the mass balance calculations indicate that the dominant processes and reactions responsible for the hydrochemical evolution in the system are (1) dissolution of evaporites, (2) precipitation of carbonate minerals, (3) silicate weathering reactions, (4) limited mixing with saline water, and (5) ion exchange.     

Self-organised clustering for road extraction in classified imagery

The extraction of road networks from digital imagery is a fundamental image analysis operation. Common problems encountered in automated road extraction include high sensitivity to typical scene clutter in high-resolution imagery, and inefficiency to meaningfully exploit multispectral imagery (MSI). With a ground sample distance (GSD) of less than 2 m per pixel, roads can be broadly described as elongated regions. We propose an approach of elongated region-based analysis for 2D road extraction from high-resolution imagery, which is suitable for MSI, and is insensitive to conventional edge definition. A self-organising road map (SORM) algorithm is presented, inspired from a specialised variation of Kohonen's self-organising map (SOM) neural network algorithm. A spectrally classified high-resolution image is assumed to be the input for our analysis. Our approach proceeds by performing spatial cluster analysis as a mid-level processing technique. This allows us to improve tolerance to road clutter in high-resolution images, and to minimise the effect on road extraction of common classification errors. This approach is designed in consideration of the emerging trend towards high-resolution multispectral sensors. Preliminary results demonstrate robust road extraction ability due to the non-local approach, when presented with noisy input.     

Cenozoic thermotectonic history of the Sunda–Asri basin, southeast Sumatra: new insights from apatite fission track thermochronology

The tectonic and thermal history of Cenozoic rocks from four wells (Asri-1, NE Ria-1, Hariet-1 and Yani-2) in the Sunda–Asri basin has been reconstructed using apatite fission track (AFT) analysis combined with modelling of previously determined vitrinite reflectance (VR) measurements. The wells all penetrate Recent to middle Eocene successions, in which only the Eocene to Oligocene successions have been subjected to temperatures suitable for partial annealing, due to rapid late Miocene to Recent burial. With respect to organic thermal maturities, the zone of minimum annealing coincides with undermature heating and records provenance AFT ages, whilst the zone of partial annealing agrees well with mature heating suitable for generation of hydrocarbons. The integrated AFT and VR data suggest that the Sunda–Asri basin continues subsiding, probably due to extension initiated in the late Eocene, and the successions near the base of the wells were recently exposed to the high present-day temperatures. The recent heating of rocks is consistent with up to 800 m of Plio–Pleistocene burial. Both the AFT and VR results indicate that geothermal gradients remained relatively constant through the Cenozoic.     

Impacts of Methane on Carbon Dioxide Storage in Brine Formations

In the context of geological carbon sequestration (GCS), carbon dioxide (CO₂) is often injected into deep formations saturated with a brine that may contain dissolved light hydrocarbons, such as methane (CH₄). In this multicomponent multiphase displacement process, CO₂ competes with CH₄ in terms of dissolution, and CH₄ tends to exsolve from the aqueous into a gaseous phase. Because CH₄ has a lower viscosity than injected CO₂, CH₄ is swept up into a ‘bank’ of CH₄‐rich gas ahead of the CO₂ displacement front. On the one hand, this may provide a useful tracer signal of an approaching CO₂ front. On the other hand, the emergence of gaseous CH₄ is undesirable because it poses a leakage risk of a far more potent greenhouse gas than CO₂ if the cap rock is compromised. Open fractures or faults and wells could result in CH₄ contamination of overlying groundwater aquifers as well as surface emissions. We investigate this process through detailed numerical simulations for a large‐scale GCS pilot project (near Cranfield, Mississippi) for which a rich set of field data is available. An accurate cubic‐plus‐association equation‐of‐state is used to describe the non‐linear phase behavior of multiphase brine‐CH₄‐CO₂ mixtures, and breakthrough curves in two observation wells are used to constrain transport processes. Both field data and simulations indeed show the development of an extensive plume of CH₄‐rich (up to 90 mol%) gas as a consequence of CO₂ injection, with important implications for the risk assessment of future GCS projects.     

Structure de socle,sismostratigraphie et héritage structural au cours du rifting au niveau de la marge d'Ifni/Tan-Tan (Maroc sud-occidental)

Seismic reflection profiles from the Ifni/Tan-Tan Atlantic margin of southern Morocco, interpreted in the light of well data and field geology from the Western Anti-Atlas, allowed us to establish the seismostratigraphic framework of the syn-rift series and to reveal (i) a compressional structural style in the pre-Triassic basement similar to that established in the adjacent outcropping onshore basement but with an opposed western vergence, (ii) the importance of inherited anterior structures in the formation of Triassic-Liassic rift structures and (iii) an east–west propagation of these rift structures. To cite this article: N. AbouAli et al., C. R. Geoscience 337 (2005).     

Conjunctive use of surface water and groundwater via the bank infiltration method

The bank infiltration (BI) technique may be a viable option if the local climate, hydrological, and geological conditions are conducive. This study was specifically conducted to explore the possibility of using BI to source the polluted surface water in conjunction with groundwater. Three major factors were considered for evaluation: (1) investigation on the contribution of surface water through BI, (2) input of local groundwater, and (3) water quality characteristics of water supply. Initially, the geophysical method was employed to define the subsurface geology and hydrogeology, and isotope techniques were performed to identify the source of groundwater recharge and interaction between surface water and groundwater. The physicochemical and microbiological parameters of the local surface water bodies and groundwater were analyzed before and during water abstraction. Extracted water revealed a 5 %–98 % decrease in turbidity, as well as HCO₃ ⁺, SO₄ ^?, NO₃ ^?, Al, As, and Ca concentration reduction compared with those of Langat river water. However, water samples from test wells during pumping show high concentrations of Fe²⁺ and Mn²⁺. In addition, amounts of Escherichia coli, total coliform, and Giardia were significantly reduced (99.9 %). Pumping test results indicate that the two wells (DW1 and DW2) were able to sustain yields.     

Behavior of Weak Soils Reinforced with End-Bearing Soil-Cement Columns Formed by the Deep Mixing Method

This article reports on a series of small-scale, plane strain, 1 g physical model tests designed to investigate the bearing capacity and failure mechanics of end-bearing soil-cement columns formed via Deep Mixing (DM). Pre-formed soil-cement columns, 24 mm in diameter and 200 mm in length, were installed in a soft clay bed using a replacement method; the columns represented improvement area ratios, a_p, of 17%, 26%, and 35% beneath a rigid foundation of width 100 mm. Particle Image Velocimetry (PIV) was implemented in conjunction with close-range photogrammetry in order to track soil displacement during loading, from which the failure mechanisms were derived. Bearing capacity performance was verified using Ultimate Limit State numerical analysis, with the results comparing favorably to the analytical static and kinematic solutions proposed by previous researchers. A new equation for bearing capacity was derived from this numerical analysis based on the improvement area ratio and cohesion ratio of the soil column and ground model.     

Regression‐based approach to low flow prediction in the Maryland Piedmont region under joint climate and land use change

We examine the low flow records for six urbanized watersheds in the Maryland Piedmont region and develop regression equations to predict annual minimum low flow events. The effects of both future climate (based on precipitation and temperature projections from two climate models: Hadley and the Canadian Climate Centre (CCC)) and land use change are incorporated to illustrate possible future trends in low flows. A regression modelling approach is pursued to predict the minimum annual 7‐day low flow estimates for the proposed future scenarios. A regional regression model was calibrated with between 10 and 50 years of daily precipitation, daily average temperature, annual imperviousness, and the daily observed flow time‐series across six watersheds. Future simulations based on a 55 km² urbanizing watershed just north of Washington, DC, were performed. When land use and climate change were employed singly, the former predicted no trends in low flows and the latter predicted significant increasing trends under Hadley and no trends under CCC. When employed jointly, however, low flows were predicted to decrease significantly under CCC, whereas Hadley predicted no significant trends in low flows. Antecedent precipitation was the most influential predictor on low flows, followed by urbanization. Copyright © 2006 John Wiley & Sons, Ltd.     

Performance studies of the fixed stress split algorithm for immiscible two-phase flow coupled with linear poromechanics

In this work, we measure the performance of the fixed stress split algorithm for the immiscible water-oil flow coupled with linear poromechanics. The two-phase flow equations are solved on general hexahedral elements using the multipoint flux mixed finite element method whereas the poromechanics equations are discretized using the conforming Galerkin method. We introduce a rigorous calculation of the update in poroelastic properties during the iterative solution of the coupled system equations. The effects of the coupling parameter on the performance of the fixed stress algorithm is demonstrated in two field studies: the Frio oil reservoir and the Cranfield injection site.