Reports from the Smithsonian’s Global Volcanism Network,November 2008

Information included in this summary is based on more detailed reports published in the Bulletin of the Global Volcanism Network, vol. 33, no. 11, November 2008 (on the Internet at ). Edited by scientists at the Smithsonian, this bulletin includes reports provided by a worldwide network of correspondents. The reports contain the names and contact information for all sources. Please note that these reports are preliminary and subject to change as events are studied in more detail. The Global Volcanism Program welcomes further reports of current volcanism, seismic unrest, monitoring data, and field observations.     

Reports from the Smithsonian’s Global Volcanism Network,May 2009

Information included in this summary is based on more detailed reports published in the Bulletin of the Global Volcanism Network, vol. 34, no. 5, May 2009 (on the Internet at http://www.volcano.si.edu/). Edited by scientists at the Smithsonian, this bulletin includes reports provided by a worldwide network of correspondents. The reports contain the names and contact information for all sources. Please note that these reports are preliminary and subject to change as events are studied in more detail. The Global Volcanism Program welcomes further reports of current volcanism, seismic unrest, monitoring data, and field observations.     

Reports from the Smithsonian’s Global Volcanism Network,September 2008

Information included in this summary is based on more detailed reports published in the Bulletin of the Global Volcanism Network, vol. 33, no. 9, September 2008 (on the Internet at ). Edited by scientists at the Smithsonian, this bulletin includes reports provided by a worldwide network of correspondents. The reports contain the names and contact information for all sources. Please note that these reports are preliminary and subject to change as events are studied in more detail. The Global Volcanism Program welcomes further reports of current volcanism, seismic unrest, monitoring data, and field observations.     

Monitored Natural Attenuation of Manufactured Gas Plant Tar Mono- and Polycyclic Aromatic Hydrocarbons in Ground Water: A 14-Year Field Study

Site 24 was the subject of a 14-year (5110-day) study of a ground water plume created by the disposal of manufactured gas plant (MGP) tar into a shallow sandy aquifer approximately 25 years prior to the study. The ground water plume in 1988 extended from a well-defined source area to a distance of approximately 400 m down gradient. A system of monitoring wells was installed along six transects that ran perpendicular to the longitudinal axis of the plume centerline. The MGP tar source was removed from the site in 1991 and a 14-year ground water monitored natural attenuation (MNA) study commenced. The program measured the dissolved mono- and polycyclic aromatic hydrocarbons (MAHs and PAHs) periodically over time, which decreased significantly over the 14-year period. Naphthalene decreased to less than 99% of the original dissolved mass, with mass degradation rates of 0.30 per year (half-life 2.3 years). Bulk attenuation rate constants for plume centerline concentrations over time ranged from 0.33 ± 0.09 per year (half-life 2.3 ± 0.8 years) for toluene and 0.45 ± 0.06 per year (half-life 1.6 ± 0.2 years) for naphthalene. The hydrogeologic setting at Site 24, having a sandy aquifer, shallow water table, clay confining layer, and aerobic conditions, was ideal for demonstrating MNA. However, these results demonstrate that MNA is a viable remedial strategy for ground water at sites impacted by MAHs and PAHs after the original source is removed, stabilized, or contained.     

Comparison of nitrate attenuation characterization methods at the Uranium mill tailing site in Monument Valley, Arizona

Several methods for characterizing the occurrence and rate of nitrate attenuation were tested at a field site near Monument Valley, Arizona. Spatial and temporal nitrate concentration data collected from a transect of monitoring wells located along the plume centerline were analyzed to evaluate the overall rates of natural attenuation. The occurrence and rate of denitrification was evaluated through microcosm experiments, nitrogen isotopic fractionation analysis, and solute-transport modeling. First-order denitrification-rate coefficients calculated with each method were comparable. In addition, the composite natural attenuation rate coefficient was similar to the denitrification-rate coefficients, which suggests that microbially induced decay primarily controls nitrate attenuation at the site. This research highlights the benefits associated with a multiple-method approach for the characterization of natural attenuation.     

Settlement and sustainability in the Polish Sudetes

The paper summarises the history of human settlement in the Sudetes from the Bronze Age. A more intensive stage was reached in the Middle Ages when settlers from the west established new villages deep in the mountain valleys. By the beginning of the 20th century the Sudetes were already overpopulated but after a near-complete ethnic replacement from a German to a Polish population in 1945–8, population continued to grow until the 1980s. However, the economic system was hardly sustainable by this time. There were many polluting industries in the region and massive transboundary pollution from adjacent areas of Czechoslovakia and Germany had a devastating effect on the forests. Moreover, subsidised state agriculture placed heavy pressure on vulnerable mountain grazings. Since 1989 there has been a process of deindustrialisation in the Sudetes and surrounding areas and, with the disappearance of the state farms and the reduction in subsidies, agriculture is now better adjusted to the natural potential and is complemented by a promising start with agrotourism. The population of the region is growing relatively slowly (0.8% per annum 1956–1999), with the rural areas now in decline. A sustainable future for the region is now a possibility, but while there is a consensus for continued environmental reconstruction, supported by alternative economies, this will have to be carefully managed in the years ahead when EU accession may bring heavier development pressures than those evident at the moment. This revised version was published online in July 2006 with corrections to the Cover Date.     

Experiments on the ocean sequestration of fossil fuel CO2: pH measurements and hydrate formation

We have carried out a series of in situ experiments to investigate the formation of a CO₂ hydrate (CO₂:5.75 H₂O) for the purpose of evaluating scenarios for ocean fossil fuel CO₂ disposal with a solid hydrate as the sequestered form. The experiments were carried out with a remotely operated vehicle in Monterey Bay at a depth of 619 m. pH measurements made in close proximity to the hydrate–seawater interface showed a wide range of values, depending upon the method of injection and the surface area of the hydrate formed. Rapid injection of liquid CO₂ into an inverted beaker to form a flocculant mass of hydrate resulted in pH initially as low as 4.5 within a few centimeters of the interface, decaying slowly over 1–2 h towards normal seawater values as dense CO₂ rich brine drained from the hydrate mass. In a second experiment, slower injection of the liquid CO₂ to produce a simple two-layer system with a near planar interface of liquid CO₂ with a thin hydrate film yielded pH values indistinguishable from the in situ ocean background level of 7.6. Both field and laboratory results now show that the dissolution rate of a mass of CO₂ hydrate in seawater is slow but finite.     

含硫化物镁铁质-超镁铁质侵入体中橄榄石Mg、Ni含量的制约:原理、模式及Voisey's Bay侵入体样品研究

镁铁质-超镁铁质岩浆结晶分离早期形成镁铁矿物,镁铁矿物中的Ni和Mg是相容元素。随着结晶分离作用的进行,Ni、Mg在硅酸盐岩浆及后形成的硅酸盐物质中的丰度下降。橄榄石中Ni含量及硅酸盐物质MgO/FeO比值都与母岩浆的相关值相关,据此可推断母岩浆的信息,它们之间可由实验测得的系数相联系。当岩浆饱和硫化物时,在结晶分离过程中硫化物珠滴会与镁铁硅酸盐物质一道析出,同时,与硫化物非饱和岩浆相比,过多的Ni会随之析出。这也反映在Ni、Mg含量比无硫化物分离时有更迅速的降低上。Ni、Mg含量变化值可以在VoiseysBay侵入体的模式曲线上反映出,加拿大Labrador的这一侵入体赋存了一个世界级的Ni-Cu-Co硫化物矿床。过去的作法是将侵入体中橄榄石的Ni、Mg含量与Simkin和Smith得出的各种火成岩中橄榄石的Ni、Mg含量相比较以确定Ni亏损,进而假定橄榄石来自硫化物饱和、有经济价值的岩浆。现在的研究显示这种简单的对比会导致错误。将样品数据与模式曲线对比并反映出侵入体矿物结晶堆积特征是重要的方法。使用这一方法,样品数据能很好地被模式曲线拟合。以在VoiseysBay的研究为例,当硫化物液相与硅酸盐矿物被去除后,硫化物非饱和的分离作用期就会显现出来,随后是硅酸盐结晶作用期。     

Chemical fractionations in meteorites—X. Ureilites

Four ureilites (Dyalpur, Goalpara, Haverö, and Novo Urei) were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Rb, Re, Sb, Se, Te, Tl, and U. An attempt has been made to resolve the data into contributions from the parent ultramafic rock and the injected, carbon- and gas-rich vein material. Interelement correlations, supported by analyses of separated vein material (WANKE et al, 1972), suggest that the vein material is enriched about 10-fold in refractory Ir and Re over moderately volatile Ni and Au, and is low in volatiles except Ge, C, and noble gases. It appears to be a refractory-rich nebular condensate that precipitated carbon by surface catalytic reactions at ˜500K and trapped noble gases but few other volatiles. The closest known analogue is a Cr- and C-rich fraction from the Allende meteorite, highly enriched in heavy noble gases and noble metals. By analogy with Allende, the gas-bearing phase in ureilites may have been an Fe, Cr-sulfide.

The ultramafic rock contains siderophiles and chalcophiles (Ni, Au, Ge, S, Se) at ˜0.05 of Cl chondrite level, and highly volatile elements (Rb, Cs, Bi, Tl, Br, Te, In, Cd) at ˜0.01 Cl level. It probably represents the residue from partial melting of a C3V-like chondrite body, under conditions where phase separation was incomplete so that some liquid was retained. The vein material was injected into this rock at some later time.     

Crop yield response to economic, site and climatic variables

This paper examines the effects of climatic and non-climatic factors on the mean and variance of corn, soybean and winter wheat yield in southwestern Ontario, Canada over a period of 26 years. Average crop yields increase at a decreasing rate with the quantity of inputs used, and decrease with the area planted to the crop. Climate variables have a major impact on mean yield with the length of the growing season being the primary determinant across all three crops. Increases in the variability of temperature and precipitation decrease mean yield and increase its variance. Yield variance is poorly explained by both seasonal and monthly climate variable models. Projections of future climate change suggest that average crop yield will increase with warmer temperatures and a longer growing season which is only partially offset by forecast increases in the variability of temperature and rainfall. The projections would also depend on future technological developments, which have generated significant increases in yield over time despite changing annual weather conditions.