Tar ball frequency data and analytical results from a long-term beach monitoring program

Following the spill of fuel oils from the New Carissa in February 1999, approximately 300 km of beaches on the Pacific coast of North America were surveyed. A long-term observation program focused on the documentation of stranded tar balls in the vicinity of the spill site. Systematic beach surveys which were conducted over the period March 1999 to April 2001 and semi-logarithmic scale, time-series plots proved the most useful format for identifying trends. Beach monitoring continued through to August 2001. by which time 212 tar balls had been analyzed by GC/MS for their chemical characteristics. The samples of tar balls collected between February 1999 and August 2001 were qualitatively compared with New Carissa source oils (NCSO) and 101 (48%) were not consistent with NSCO. The presence of tar balls that are not related to an incident can confound attempts to define cleanup or endpoint criteria and to assess possible injury to natural resources.     

Cr-spinel/olivine and Cr-spinel/liquid nickel partition coefficients from natural samples

The Nernst partition coefficient of nickel (D^Ni) between Cr-spinel and silicate melt in natural systems has been investigated using mid-ocean ridge basalts (MORB) and other volcanic rocks. The Cr-spinel/olivine D^Ni values in volcanic rocks are between 1.2 and 0.3, indicating that the Cr-spinel/liquid D^Ni values vary from slightly higher to significantly lower than the olivine/liquid D^Ni values in natural systems. The Cr-spinel/liquid D^Ni values from the MORB samples vary between 6 and 11, slightly higher than those from the S-bearing experiments of Satari et al. [Satari P., Brenan J. M., Horn I. and McDonough W. F. (2002) Experimental constraints on the sulfide- and chromite-silicate melt partitioning behavior of rhenium and platinum-group elements. Economic Geology97, 385-398]. The results of the MORB samples and the experiments of Satari et al. (2002) indicate a negative correlation between the Cr-spinel/liquid D^Ni and the X_Cr values in Cr-spinels (Cr cation number on the basis of 3 total cations in the spinel structure). Variations of Cr-spinel/liquid D^Ni values with Cr-spinel compositions can be estimated from an empirical equation based on the results of the MORB samples and the experiments by Satari et al. (2002). The choice of Cr-spinel/liquid D^Ni = 10 for numerical modeling by Righter et al. [Righter K., Leeman W. P. and Hervig R. L. (2006) Partitioning of Ni, Co, and V between spinel-structured oxides and silicate melts: importance of spinel composition. Chemical Geology227, 1-25] is reasonable for basaltic systems. For picritic and komatiitic systems a lower value of ∼5 is more appropriate.     

Climatic Trends and Temporal Patterns of Phytoplankton Composition, Abundance, and Succession in the Indian River Lagoon, Florida, USA

This paper describes the results of 10 years of water quality monitoring in the Indian River Lagoon Florida, with special emphasis on the relationships between trends in climatic conditions and the distribution, composition, and abundance of the phytoplankton community. The Indian River Lagoon, which spans 220 km of Florida’s east coast, is a region of particular concern because of the rapid rate of human development throughout the region and the hydrologically restricted character of the lagoon, which heightens the potential for algal bloom. Water sampling was carried out on a monthly to twice-monthly basis at six sites located in the northern and central lagoon. The 10-year study included both extended periods of below and above average rainfall. A number of ecologically distinct regions exist within the lagoon, which differ considerably in water exchange properties and watershed inputs. The northern lagoon is characterized by longer water residence times, lower phosphorus concentrations, higher nitrogen concentrations, and more stable salinity conditions than the central lagoon. Mean phytoplankton biovolumes were substantially higher at the sites in the northern lagoon than at the sites in the central lagoon, and algal blooms were more common and intense in the former region. Inter-annual patterns of phytoplankton biovolume were also different in the northern and central lagoon. In the northern lagoon, phytoplankton biovolumes were lowest during the drought period, from the autumn of 1998 to the spring of 2001. By contrast, algal bloom events in the central lagoon were not only less frequent but were not tied to periods of high rainfall. The most widespread and common bloom formers were the potentially toxic dinoflagellate Pyrodinium bahamense var. bahamense and two centric diatoms, Dactyliosolen fragilissimus and Cerataulina pelagica. Many of the biovolume peaks observed over the study period were attributable to these three species. The results of time series modeling of phytoplankton dynamics further highlighted the disparities between the two regions of the lagoon in terms of the suite of parameters that best predict the observed trends in the biomass of phytoplankton. Overall, the outcome of this initial modeling effort in the Indian River Lagoon suggests that time series approaches can help define the factors that influence phytoplankton dynamics.     

Considering dynamic soil structure interaction (SSI) effects on seismic isolation retrofit efficiency and the importance of natural frequency ratio

This paper utilizes and expands on existing coupled BEM–FEM (finite element method) methods for the investigation of the effects of soil structure interaction (SSI) on both an un-retrofitted and seismically isolated typical bridge structure. A simple numerical model of the bridge and surrounding soil is formulated and excited by an earthquake excitation. Utilizing Newmark's β FEM solution method along with the closed form B-spline BIRF method, the structural damped period, composite damping ratio, pier relative displacement, and base shear demand are monitored. From these results, the effects of SSI on this structure are identified. Additionally, the importance of the relative rigidity between the soil-foundation system and the bridge structure is also investigated. The results of the studies indicate that the response of the complete structure system considered is affected by the inclusion of SSI effects. Furthermore, the efficiency of the isolation measures designed using fixed base conditions is decreased by considering SSI over a certain relative rigidity range that is quantified using the structure to soil-foundation natural frequency ratio.     

Spectra of extremely reduced assemblages: Implications for Mercury

Abstract— We investigate the possibility that Mercury's crust is very reduced with FeO concentrations of less than ?0.1 wt%. We believe that such a surface could have a composition of enstatite, plagioclase, diopside, and sulfide, similar to the mineral assemblages found in aubritic meteorites. To test this hypothesis, we investigated the spectra of aubrites and their constituent minerals as analogs for the surface of Mercury. We found that some sulfides have distinctive absorption features in their spectra shortwards of ?0.6 μm that may be apparent in the spectrum of such an object. Determination of the surface composition of Mercury using orbital x‐ray spectroscopy should easily distinguish between a lunar highlands and enstatite basalt composition since these materials have significant differences in concentrations of Al, Mg, S, and Fe. The strongest argument against Mercury having an enstatite basalt composition is its extreme spectral redness. Significant reddening of the surface of an object (such as Mercury) is believed to require reduction of FeO to nanophase iron, thus requiring a few percent FeO in the material prior to alteration.     

Preliminary Photometric Evidence of Starspot Umbrae and Penumbrae on Late-Type Active Stars

We constrain the properties of the spotted regions on the photosphere of the active late-type star DX Leonis by comparing the observed amplitudes of light and color variations with synthetic amplitudes obtained by means of Dorren's spot model and computed for a grid of values of spot temperatures, areas and latitudes.     

Atmospheric water vapor flux,bifurcation of the thermohaline circulation,and climate change

Latitudinal heat transport in the ocean and atmosphere represents a fundamental process of the Earth's climate system. The ocean component of heat transport is effected by the thermohaline circulation. Changes in this circulation, and hence latitudinal heat transport, would have a significant effect on global climate. Paleoclimate evidence from the Greenland ice cores and deep sea sediment cores suggests that during much of glacial time the climate system oscillated between two different states. Bimodal equilibrium states of the thermohaline circulation have been demonstrated in climate models. We address the question of the role of the atmospheric hydrological cycle on the global thermohaline circulation and the feedback to the climate system through changes in the ocean's latitudinal heat transport, with a simple coupled ocean-atmosphere energy-salt balance model. Two components of the atmospheric hydrological cycle, i.e., latitudinal water vapor transport and the net flux of water vapor from the Atlantic to the Pacific Ocean appear to play separate roles. If the inter-basin transport is sufficiently large, small changes in water vapor transport over the North Atlantic can effect bifurcation or a rapid transition between two different equilibria in the global thermohaline circulation; maximum difference between the modes occurs in the North Atlantic. If the inter-basin transport is from the Pacific to the Atlantic and sufficiently large, latitudinal vapor transport in the North Pacific controls the bifurcations, with maximum changes occurring in the North Pacific. For intermediate values of inter-basin transport, no rapid transitions occur in either basin. In the regime with vapor flux from the Atlantic to the Pacific, the on mode has strong production of deep water in the North Atlantic and a large flux of heat to the atmosphere from the high latitude North Atlantic. The off mode has strong deep water production in the Southern Ocean and weak production in the North Pacific. Heat transport into the high latitude North Atlantic by the ocean is reduced to about 20% of the on mode value. For estimated values of water vapor transport for the present climate the model asserts that while water vapor transport from the Atlantic to the Pacific Ocean is sufficiently large to make the North Atlantic the dominant region for deep water production, latitudinal water vapor transport is sufficiently low that the thermohaline circulation appears stable, i.e., far from a bifurcation point. This conclusion is supported to some extent by the fact that the high latitude temperature of the atmosphere as recorded in the Greenland ice cores has changed little over the last 9000 years.     

Aeolian activity in northern Amazonia: optical dating of Late Pleistocene and Holocene palaeodunes

Palaeodunes were examined on the eastern margin of the Rio Branco–Rupununi savanna, northeast Amazonia. Optical dating suggests that the onset of aeolian activity was between 17 000 and 15 000 yr ago, just after the Last Glacial Maximum. Both the palaeodune axes and modern dominant wind directions have northeast to east‐northeast directions, implying no significant shift in atmospheric circulation patterns over northeast Amazonia during the Late Pleistocene to Holocene. Major regional climate change events, such as the Younger Dryas, do not appear to have had any effect on the rates of aeolian deposition at the study site. Aeolian activity appears to have continued to the present day, showing a remarkably constant deposition rate of around 0.13 m kyr^?1 initially, increasing smoothly to the present. Until more palaeodunes in northern Amazonia are dated, it is impossible to determine if this record of gradual aeolian deposition is a reliable regional palaeoclimate indicator, rather than being the result of local bioclimatic and geomorphological effects. Copyright © 2004 John Wiley & Sons, Ltd.     

Photoionized Hβ emission in NGC 5548: it breathes!

Emission-line regions in active galactic nuclei (AGNs) and other photoionized nebulae should become larger in size when the ionizing luminosity increases. This 'breathing' effect is observed for the Hβ emission in NGC 5548 by using Hβ and optical continuum light curves from the 13-yr (1989–2001) AGN Watch monitoring campaign. To model the breathing, we use two methods to fit the observed light curves in detail: (i) parametrized models and, (ii) the memecho reverberation-mapping code. Our models assume that optical continuum variations track the ionizing radiation, and that the Hβ variations respond with time-delays τ due to light travel-time. By fitting the data using a delay-map  Ψ(τ, F _c)  that is allowed to change with continuum flux F _c, we find that the strength of the Hβ response decreases and the time-delay increases with ionizing luminosity. The parametrized breathing models allow the time-delay and the Hβ flux to depend on the continuum flux so that,  τ∝ F ^β_c  and   F _Hβ∝ F ^α_c  . Our fits give  0.1 < β < 0.46  and  0.57 < α < 0.66. α  is consistent with previous work by Gilbert and Peterson, and Goad, Korista and Knigge. Although we find β to be flatter than previously determined by Peterson et al. using cross-correlation methods, it is closer to the predicted values from recent theoretical work by Korista and Goad.