A new titanium-bearing calcium aluminosilicate phase: II. Crystallography and crystal chemistry of grains formed in slowly cooled melts with bulk compositions of calcium- aluminum-rich inclusions

Abstract The crystallography and crystal chemistry of a new calcium-titanium-aluminosilicate mineral (UNK) observed in synthetic analogs to calcium-aluminum-rich inclusions (CAIs) from carbonaceous chondrites was studied by electron diffraction techniques. The unit cell is primitive hexagonal or trigonal, with a = 0.790 ± 0.002 nm and c = 0.492 ± 0.002 nm, similar to the lattice parameters of melilite and consistent with cell dimensions for crystals in a mixer furnace slag described by Barber and Agrell (1994). The phase frequently displays an epitactic relationship in which melilite acts as the host, with (0001)_UNK | (001)_mel and <10T0>_UNK | <100>_mel. If one of the two space groups determined by Barber and Agrell (1994) for their sample of UNK is applicable (P3ml or P31m), then the structure is probably characterized by puckered sheets of octahedra and tetrahedra perpendicular to the c-axis with successive sheets coordinated by planar arrays of Ca. In this likely structure, each unit cell contains three Ca sites located in mirror planes, one octahedrally coordinated cation located along a three-fold axis and five tetrahedrally coordinated cations, three in mirrors and two along triads. The octahedron contains Ti but, because there are 1.3–1.9 cations of Ti/formula unit, some of the Ti must also be in tetrahedral coordination, an unusual but not unprecedented situation for a silicate. Tetrahedral sites in mirror planes would contain mostly Si, with lesser amounts of Al while those along the triads correspondingly contain mostly Al with subordinate Ti. The structural formula, therefore, can be expressed as with Si + Ti = 4. Compositions of meteoritic and synthetic Ti-bearing samples of the phase can be described in terms of a binary solid solution between the end-members Ca₃TiAl₂Si₃O₁₄ and Ca₃Ti(AlTi)(AlSi₂)O₁₄. A Ti-free analog with a formula of Ca₃Al₂Si₄O₁₄ synthesized by Paque et al. (1994) is thought to be related structurally but with the octahedral site being occupied by Al, that is      

Evidence for the depletion of ammonia in the Uranus atmosphere

The theoretical disk brightness temperature spectra for Uranus are computed and compared with the observed microwave spectrum. It is shown that the emission observed at short centimeter wavelengths originates deep below the region where ammonia would ordinarily begin to condense. We demonstrate that this result is inconsistent with a wide range of atmospheric models in which the partial pressure of NH₃ is given by the vapor-pressure equation in the upper atmosphere. It is estimated that the ammonia mixing ratio must be less than 10^?6 in the 150 to 200°K temperature range. This is two orders of magnitude less than the expected mixing ratio based on solar abundances. The evidence for this depletion and a possible explanation are discussed.     

Accurate Determination of Electron Densities in Active and Quiescent Prominences: the Mid-Infrared Advantage

We have analyzed all lines in the MIR (8 to 20 micron) spectra of a quiescent and two time-frames of an active prominence. In the quiescent prominence, in addition to those lines found by Zirker (1985), we have identified a higher excitation hydrogen line and two helium recombination lines. Accounting for instrumental broadening, we can further separate out the Doppler and the Stark contributions to the line width. The former yields maximum temperatures of 6200 K, 34000 K and 12000 K and the latter electric field strengths of 7, 17, and 10 V cm^-1 for the above prominences, respectively. We show that these electric fields when divided by 2.2 are equal to the normal electric field in Holtsmark's quasi-static Stark broadening theory. Hence, we obtain electron densities of N₃=2.4(0.3), 9.1(1.2), and 5.5(0.6) in units of 10¹⁰ cm^-3 respectively. Using the same assumptions as made by Zirker, namely, (1) the strongest line (7-6) is optically thin, (2) the population of the lower level (n=6) is determined by direct radiative recombination and photo-ionization, (3) the equality of proton and electron densities, and (4) the thickness of the prominence is at least 10⁸ cm, we derive a new inequality, N_e 1.83 × 10⁸ T^0.75 e^-2195/T. Substituting our maximum temperatures into the right-hand side, we find upper bound N_e values of 9, 43, and 30 in the same units as above. These upper bound values are comfortably higher than our measurement, unlike those of Zirker's derived from the same set of assumptions. We have also observed the helium recombination spectrum which has been postulated by Tandberg-Hanssen as one of three possible ways of equilibrating the triplet/singlet ratio. Surprisingly, it is present in the quiescent as well as in the active prominence. We show that no meaningful values can be found for the turbulent velocities by combining the helium with the hydrogen line widths.     

Can marine fisheries and aquaculture meet fish demand from a growing human population in a changing climate?

Expansion in the world's human population and economic development will increase future demand for fish products. As global fisheries yield is constrained by ecosystems productivity and management effectiveness, per capita fish consumption can only be maintained or increased if aquaculture makes an increasing contribution to the volume and stability of global fish supplies. Here, we use predictions of changes in global and regional climate (according to IPCC emissions scenario A1B), marine ecosystem and fisheries production estimates from high resolution regional models, human population size estimates from United Nations prospects, fishmeal and oil price estimations, and projections of the technological development in aquaculture feed technology, to investigate the feasibility of sustaining current and increased per capita fish consumption rates in 2050. We conclude that meeting current and larger consumption rates is feasible, despite a growing population and the impacts of climate change on potential fisheries production, but only if fish resources are managed sustainably and the animal feeds industry reduces its reliance on wild fish. Ineffective fisheries management and rising fishmeal prices driven by greater demand could, however, compromise future aquaculture production and the availability of fish products.     

Skew eddy fluxes as signatures of non‐linear tidal current interactions,with application to Georges Bank

Abstract

The eddy flux of a conservative scalar in a time‐dependent rotary velocity field may have a component that is normal to the scalar gradient. This component is the “skew flux”, which consists of the scalar transport by the Stokes velocity and a part that is always non‐divergent (and hence does not affect scalar evolution). Since tidal velocity fields usually have rotary features, tidal‐band eddy scalar fluxes may include a skew component that can be useful in indicating the occurrence of non‐linear current interactions.

The skew temperature flux associated with the semidiurnal tide in a continental shelf region is demonstrated using simple models, and moored current and temperature observations from Georges Bank. The observed fluxes on the Bank are largely directed along isobaths, with apparent contributions from the topographic rectification of the barotropic tidal current over the Bank's side and from the rotary tidal ellipses in a frontal region. Simple models indicate that the weaker cross‐isobath fluxes can arise through the influence of frictionally induced vertical structure on topographic tidal rectification, a baroclinic tidal current interaction, or the interaction of baroclinic and barotropic tidal currents. In some cases, the simple models show qualitative agreement with the observed fluxes and currents but, in general, more realistic models and better estimates of the background mean temperature field are required to obtain quantitative estimates of the relative importance of these interactions and other processes. Nevertheless, the observations and models suggest that non‐linear interactions involving both barotropic and baroclinic tidal currents are occurring on Georges Bank.     

Eolian evidence for spatial variability of late Quaternary climates in tropical Africa

Study of the eolian fraction of late Quaternary sediments from the tropical Atlantic reveals that two modes of long-term climate variability have existed in tropical Africa during the last 150,000 yr. Tropical northwest Africa (i.e., the southwestern Sahara and Sahel) was driest during glaciations and stades, but wetter than at present during interglaciations and interstades. This may be a response to ice sheets at higher latitudes, via equatorward displacement of the westerlies and the subtropical high. In contrast, central equatorial Africa (southeast of the Sahara) was most arid during interstades and times of ice growth, and most humid during deglaciation. Wet periods in this area correspond to insolation maxima in northern hemisphere summer. A 23,000-yr precessional rhythm is suggested, supporting a direct link between African Monsoon intensity and orbitally modulated insolation. The late Holocene is the only time observed when both areas are arid during an interglacial episode. This may reflect, in part, anthropogenic disturbance of late Holocene climates.     

Variability in estimates of oil contamination in the intertidal zone of a gravel beach

Estimates of the surface cover of stranded oil on a gravel beach ranged between 25 and 51%. This variability is attributed primarily to wet weather conditions that altered the colour of the surface substrate, thus making identification of oil or oiled sediments difficult. Estimates and the observations from three surveys in wet weather ranged between 25 and 46%; whereas on a dry day the range from four surveys was only 42–51%. Within this small study area (7200 m²) the same observer provided estimates of the surface oil cover that ranged from 1800 to 3680 m². This wide variability for a small section of shoreline would probably be magnified during reconnaissance surveys where long sections of coast are surveyed to determine the degree of contamination. Surveys of beach contamination for cleanup decisions or for damage assessment should be conducted with regard to the environmental (weather) conditions and the degree of accuracy that is required from the survey.