Tremolite and H2O activity attending metamorphism of hornblende-plagioclase-garnet assemblages

Estimation of the activity of tremolite component (atr) in calcic amphiboles is an important problem in igneous and metamorphic petrology because equilibria involving tremolite are used in the estimation of the activity of H₂O attending crystallization of igneous and metamorphic rocks. Estimated values of atr from hornblende analyses using both ionic and coupled substitution crystalline solution models can be compared to values of atr calculated from vapor-absent mineral equilibria. In addition, these values of atr can be used in calculations of aH₂O for rocks for which there is an independent estimate of aH₂O. The values of atr calculated from vapor-absent equilibria are generally consistent with those estimated from the different crystalline solution models, but uncertainties in the calculations preclude choosing a preferred solution model. From computed mineral equilibria, it is clear that mineral assemblages with low values of atr can be in equilibrium with high values of aH₂O. Consequently, the low values of aH₂O estimated from hornblende-bearing high-grade rocks with low values of atr may be real. Rocks from Mica Creek, British Columbia, probably achieved extremely low values of aH₂O by vapor-absent metamorphism.     

Mg,Ca and O18O16 exchange in the sediment-pore water system,hole 149, DSDP

The diagenesis and geochemical evolution of deep-sea sediments are controlled by the interaction between sediments and their associated pore waters. With increasing depth, the pore water of Hole 149 (DSDP) exhibits a strong depletion in Mg and a corresponding enrichment in Ca, while the alkalinity remains relatively constant. Dissolved SiO₂ is nearly constant in the upper 100 m of sediment, but is highly enriched in the deepest pore waters. The pore waters exhibit a depletion in K with increasing depth, and $\text{O}{}^{18}\text{O}{}^{16}$ pore water ratios also decrease.The sediment section has three zones of sedimentary regimes with increasing depth in the drill hole: an upper 100 m section of detrital clays, a middle section enriched in calc-akalic volcanics which have undergone submarine weathering to a smectite phase, and a lower section of siliceous ooze which still has a diagenetic smectite phase. The quartz-feldspar ratios and $\text{O}{}^{18}\text{O}{}^{16}$ composition of the silicate phases are in agreement with these interpretations.The submarine weathering of volcanics to a smectite can account for the observed pore water gradients. Volcanics release Ca and Mg to the pore waters causing the alkalinity values to increase. Smectite is formed, depletes the pore waters in Mg and O¹⁸ and causes the alkalinity to decrease. The net reaction allows for the observed relationship between pore water Ca and Mg gradients with little net change in alkalinity. Given the abundance of volcanics in many deep-sea sediments, especially in lower sections which often form near ridge crests, the submarine formation of smectite may be an additional oceanic Mg sink which has not yet been fully considered.     

Petrogenetic relationship between Allan Hills 77005 and other achondrites

Allan Hills (ALHA) 77005 is a newly discovered, unique achondrite from Antarctica. Petrologic similarities with the shergottites in terms of mineralogy, oxidation state, inferred source region composition, shock metamorphic effects and shock ages suggest a genetic relationship. Volatile to involatile element ratios (e.g. K/U, Rb/U, Cs/U, Tl/U) and abundances of other trace elements support this hypothesis. ALHA 77005 may be a cumulate that crystallized from a liquid parental to those from which the shergottites crystallized; alternatively it may be a sample of the type of source peridotite from which shergottite parent liquids were derived by partial melting. Chemical similarities with terrestrial ultramafic rocks suggest that this unique meteorite provides an additional sample of the only other solar system body known to have basalt source regions chemically similar to the upper mantle of the Earth.     

A petrogenetic model of the relationships among achondritic meteorites

The basaltic achondrite, shergottite, nakhlite, and chassignite meteorites appear to define a petrological and geochemical sequence. Assuming that they developed from basaltic liquids produced by low pressure partial melting of plagioclase peridotites, their petrological and chemical distinctions can be understood in terms of the compositional differences between their source periodites. The source regions of basaltic achondrite magmas were alkali-poor, metal-bearing peridotites in which pigeonite and/or orthopyroxene was the only pyroxene. By simultaneously increasing the ratio of high-Ca pyroxene to low-Ca pyroxene, the alkali content of the feldspar, the oxidation state, and the overall volatile content of the basaltic achondrite source peridotite, peridotites capable of yielding the parent liquids of the shergottites can be produced. Further increases can produce peridotites capable of yielding the parent liquids of the nakhlites and chassignites.Addition of a volatile-rich component to the volatile-poor type of peridotite required for the source regions of the eucrites appears to be capable of producing the required series of peridotites. Alternatively, progressive volatile-loss from a volatile-rich material, possibly of roughly cosmic composition, could have produced this sequence of peridotites. A simple two-component model of planetary compositions is, to a first approximation, consistent with the petrology and chemistry of these igneous meteorite groups.     

Soil development in till of various ages in northeastern Pennsylvania

Eleven well-drained soils formed in till parent materials of varying ages in northeastern Pennsylvania were studied to determine changes in the soils with time. Four profiles (three Lackawanna and one Bath) were formed in Woodfordian till (15,000 yr B.P.), and two (Leck Kill) were formed in Altonian till (>28,000, <75,000 yr B.P.). The remaining five (Allenwood) were formed in pre-Wisconsinan till (>75,000 yr B.P.). In these soils, the extractable iron oxide, extractable aluminum oxide, and kaolinite contents increase with age, as do the total clay and fine/total clay ratio. With increasing age, the maximum accumulation of these constituents is found deeper in the profile. The extractable silicon oxide distribution is constant with depth, but it decreases in overall amount with time. Gibbsite is found only in small amounts in the A horizon of Altonian soils, but occurs throughout the profile of pre-Wisconsinan soils, although only in small amounts. In general, differences were found in these soils which separated them into three groups representing varying degrees of soil development. A regression equation was derived to predict the age of soils formed from the Altonian till based on a “clay accumulation index” value for soils of known Woodfordian and Holocene ages. The equation log Y = 1.80 + 0.992(logX) best fit the data, with an r² value of 0.913. Using this equation, a mean age of 41,000 yr was calculated for the Altonian soils. This date was used to derive a second equation to predict ages for pre-Wisconsinan soils. The equation with the highest r² value (0.934) was log Y = 1.81 + 0.998(logX). Dates for soils developed in the White Deer till and the Laurelton till of the pre-Wisconsinan stage were calculated to be 86,000 and 91,000 yr B.P., respectively. These dates fall within ages estimated for the Sangamon Interglaciation and thus would appear to be too young for pre-Sangamonian materials. The probable reason for the “too-young age” is that the C-horizon material of the pre-Wisconsinan soils was weathered and did not provide an accurate estimate of clay accumulation for the prediction equation.     

Location of segregated ice in frost-susceptible soil

X-ray photography has been used to locate the position of a growing ice lens in soil under laboratory conditions in order to establish the temperature of the actively growing face by means of its position in the thermal gradient field. It can be shown that in a general way the phase change temperatures are predictable from the Clapeyron equation. The structure of the ice phase also appears to follow the predictions of the heave rate equation proposed by Penner and Ueda (1978). When heaving occurs at low overburden pressures, there is a tendency for the ice lens to be very discrete and essentially soil free; at higher pressures and under similar thermal gradients it tends to develop in a more diffuse band and over a much wider temperature range.     

Low molecular weight α-hydroxy carboxylic and dicarboxylic acids in reducing marine sediments

The occurrence and distribution of low molecular weight α-hydroxy carboxylic and dicarboxylic acids was studied in reducing marine sediments collected in the Santa Barbara Basin and the Cariaco Trench. Four compounds were found to occur in both basin sediments: glycolic, lactic, oxalic and succinic acids. In general concentrations were low (? 1 μmol/g for the hydroxy acids and ? 100μmol/g for the dicarboxylic acids), and generally decreased with depth. Subsurface maxima were observed for lactate and succinate in the Santa Barbara Basin. Both the vertical profiles and lactate enantiomer ratios suggested microbial origin and control for the distribution of these compounds. A preliminary model for the microbial mediation of the early diagenesis of organic compounds in reducing marine sediments is presented.