Influence of climate on alpine stream chemistry and water sources

The resilience of alpine/subalpine watersheds may be viewed as the resistance of streamflow or stream chemistry to change under varying climatic conditions, which is governed by the relative size (volume) and transit time of surface and subsurface water sources. Here, we use end‐member mixing analysis in Andrews Creek, an alpine stream in Rocky Mountain National Park, Colorado, from water year 1994 to 2015, to explore how the partitioning of water sources and associated hydrologic resilience change in response to climate. Our results indicate that four water sources are significant contributors to Andrews Creek, including snow, rain, soil water, and talus groundwater. Seasonal patterns in source‐water contributions reflected the seasonal hydrologic cycle, which is driven by the accumulation and melting of seasonal snowpack. Flushing of soil water had a large effect on stream chemistry during spring snowmelt, despite making only a small contribution to streamflow volume. Snow had a large influence on stream chemistry as well, contributing large amounts of water with low concentrations of weathering products. Interannual patterns in end‐member contributions reflected responses to drought and wet periods. Moderate and significant correlations exist between annual end‐member contributions and regional‐scale climate indices (the Palmer Drought Severity Index, the Palmer Hydrologic Drought Index, and the Modified Palmer Drought Severity Index). From water year 1994 to 2015, the percent contribution from the talus‐groundwater end member to Andrews Creek increased an average of 0.5% per year (p < 0.0001), whereas the percent contributions from snow plus rain decreased by a similar amount (p = 0.001). Our results show how water and solute sources in alpine environments shift in response to climate variability and highlight the role of talus groundwater and soil water in providing hydrologic resilience to the system.     

Delineation of precipitation regions using location and atmospheric variables in two Canadian climate regions: the role of attribute selection

The identification of homogeneous precipitation regions is essential in the planning, design and management of water resources systems. Regions are identified using a technique that partitions climate sites into groups based on the similarity of their attributes; the procedure is known as regionalization. In this paper the ability of four attribute sets to form large, coherent precipitation zones is assessed in terms of the regional homogeneity of precipitation statistics and computational efficiency. The outcomes provide guidance for effective attribute selection for future studies in Canada. The attributes under consideration include location parameters (latitude, longitude), distance to major water bodies, site elevation and atmospheric variables modelled at different pressure levels. The analysis is conducted in two diverse climate regions within Canada including the Prairie and the Great Lakes–St Lawrence lowlands regions. The method consists of four main steps: (i) formation of the attribute sets; (ii) determination of the preferred number of regions (selection of the c-value) into which the sites are partitioned; (iii) regionalization of climate sites using the fuzzy c-means clustering algorithm; and (iv) validation of regional homogeneity using L-moment statistics. The results of the attribute formation, c-value selection, regionalization and validation processes are presented and discussed in a comparative analysis. Based on the results it is recommended for both regions to use location parameters including latitude, longitude and distance to water bodies (in the Great Lakes region) to form precipitation regions and to consider atmospheric variables for future (climate change) applications of the regionalization procedure.     

Changes in geophysical properties caused by fluid injection into porous rocks: analytical models

Analytical models are provided that describe how the elastic compliance, electrical conductivity, and fluid‐flow permeability of rocks depend on stress and fluid pressure. In order to explain published laboratory data on how seismic velocities and electrical conductivity vary in sandstones and granites, the models require a population of cracks to be present in a possibly porous host phase. The central objective is to obtain a consistent mean‐field analytical model that shows how each modeled rock property depends on the nature of the crack population. The crack populations are described by a crack density, a probability distribution for the crack apertures and radii, and the averaged orientation of the cracks. The possibly anisotropic nature of the elasticity, conductivity, and permeability tensors is allowed for; however, only the isotropic limit is used when comparing to laboratory data. For the transport properties of conductivity and permeability, the percolation effect of the crack population linking up to form a connected path across a sample is modeled. However, this effect is important only in crystalline rock where the host phase has very small conductivity and permeability. In general, the importance of the crack population to the transport properties increases as the host phase becomes less conductive and less permeable.     

Ceres’ spectral link to carbonaceous chondrites—Analysis of the dark background materials

Ceres’ surface has commonly been linked with carbonaceous chondrites (CCs) by ground‐based telescopic observations, because of its low albedo, flat to red‐sloped spectra in the visible and near‐infrared (VIS/NIR) wavelength region, and the absence of distinct absorption bands, though no currently known meteorites provide complete spectral matches to Ceres. Spatially resolved data of the Dawn Framing Camera (FC) reveal a generally dark surface covered with bright spots exhibiting reflectance values several times higher than Ceres’ background. In this work, we investigated FC data from High Altitude Mapping Orbit (HAMO) and Ceres eXtended Juling (CXJ) orbit (~140 m/pixel) for global spectral variations. We found that the cerean surface mainly differs by spectral slope over the whole FC wavelength region (0.4–1.0 μm). Areas exhibiting slopes ?1 constitute only ~3% of the cerean surface and mainly occur in the bright material in and around young craters, whereas slopes ≥?10% μm^?1 occur on more than 90% of the cerean surface; the latter being denoted as Ceres’ background material in this work. FC and Visible and Infrared Spectrometer (VIR) spectra of this background material were compared to the suite of CCs spectrally investigated so far regarding their VIS/NIR region and 2.7 μm absorption, as well as their reflectance at 0.653 μm. This resulted in a good match to heated CI Ivuna (heated to 200–300 °C) and a better match for CM1 meteorites, especially Moapa Valley. This possibly indicates that the alteration of CM2 to CM1 took place on Ceres.     

The “FIP Effect” and the Origins of Solar Energetic Particles and of the Solar Wind

We find that the element abundances in solar energetic particles (SEPs) and in the slow solar wind (SSW), relative to those in the photosphere, show different patterns as a function of the first ionization potential (FIP) of the elements. Generally, the SEP and SSW abundances reflect abundance samples of the solar corona, where low-FIP elements, ionized in the chromosphere, are more efficiently conveyed upward to the corona than high-FIP elements that are initially neutral atoms. Abundances of the elements, especially C, P, and S, show a crossover from low to high FIP at \({\approx}\,10~\mbox{eV}\) in the SEPs but \({\approx}\,14~\mbox{eV}\) for the solar wind. Naively, this seems to suggest cooler plasma from sunspots beneath active regions. More likely, if the ponderomotive force of Alfvén waves preferentially conveys low-FIP ions into the corona, the source plasma that eventually will be shock-accelerated as SEPs originates in magnetic structures where Alfvén waves resonate with the loop length on closed magnetic field lines. This concentrates FIP fractionation near the top of the chromosphere. Meanwhile, the source of the SSW may lie near the base of diverging open-field lines surrounding, but outside of, active regions, where such resonance does not exist, allowing fractionation throughout the chromosphere. We also find that energetic particles accelerated from the solar wind itself by shock waves at corotating interaction regions, generally beyond 1 AU, confirm the FIP pattern of the solar wind.     

Phosphorites,glass ramps and carbonate factories: The evolution of an epicontinental sea and a late Palaeozoic upwelling system (Phosphoria Rock Complex)

The Permian Phosphoria Rock Complex of the western USA contains an enigmatic assemblage of bioelemental rocks (i.e. phosphorites and cherts) that accumulated in a depositional system with no modern analogue. This study utilizes detailed sedimentological, stratigraphic and petrographic examination to evaluate the genetic relations of phosphorites, spiculitic chert and carbonates of the Ervay cycle (depositional sequence) and propose a unified oceanographic model for their deposition. The Ervay cycle contains three marine and one terrestrial facies association, each of which composes the bulk of a single lithostratigraphic unit. The marine facies associations include: (i) granular phosphorites (Retort Member); (ii) spiculitic cherty dolostones (Tosi Member); and (iii) marine to peritidal carbonates (Ervay Member). Red beds and intercalated gypsum (Goose Egg Formation) accumulated in the vast desert adjacent to the sea. The three marine members are chronostratigraphically distinct, successive and conformably stacked. They are not coeval facies belts. They reflect the progressive evolution of the epicontinental sea from the location of: (i) authigenic phosphogenesis (lowstand to transgression); to (ii) a glass ramp with biosiliceous (sponge) deposition (transgression); to (iii) a carbonate ramp (regression). This succession of switching biochemical sediment factories records the evolution of sea-level, nutrient supply, upwelling, oxygenation and dissolved Si. Intense upwelling, potentially coupled with aeolian input, led to sedimentary condensation and phosphogenesis. Decreased upwelling intensity during transgression increased oxygenation sufficiently for a siliceous sponge benthos. Sponges were favoured over biocalcifiers due to elevated dissolved silica and a low carbonate saturation state. The cessation of sponge dominance and transition to a carbonate ramp occurred due to decreasing upwelling intensity, Si drawdown and an increased carbonate saturation state. These results provide insight into the role of Si loading in faunal turnover on glass ramps and highlight how differences in dissolved Si utilizers in pre-Cretaceous versus post-Cretaceous upwelling systems influence the resultant deposits.     

Floodplain construction by recent,rapid vertical accretion: Waipaoa River,New Zealand

The rate of vertical accretion (typically 14–18 mm h⁻¹) during eight floods in the Waipaoa River basin, with recurrence intervals of 5 to 60 years, was determined by relating the floodplain stratigraphy at McPhail's bend to the 1948–1995 flood history. Overbank deposits remaining after a flood that occurred in March 1996 suggest a rate of vertical accretion of 15 mm h⁻¹. By contrast, because the flow velocity across the floodplain was too high to permit deposition from suspension, during the record flood of March 1988 the rate of vertical accretion was only 6 mm h⁻¹. The sequence of deposition is highly discontinuous, and the rapid vertical accretion is a response to a late 19th to early 20th century phase of deforestation in the headwaters that probably initiated a far greater change in suspended sediment yield than in discharge. Cross-section surveys conducted since 1948 indicate that the high suspended sediment load of the Waipaoa River also promoted in-channel deposition, which effected a progressive reduction in bankfull channel width although, due to the overbank deposition, channel capacity remained constant. © 1998 John Wiley & Sons, Ltd.     

Relic permafrost structures in the Gobi of Mongolia: age and significance

Relict permafrost structures (ice-wedge casts and cryoturbation structures) are present in the Gobi of southern Mongolia. Luminescence dates of sediments are presented to constrain the age of formation of permafrost structures. These data show that there was a phase of permafrost development during the latter part of the Last Glacial (after about 22 to 15 ka) that resulted in cryoturbated sediments and ice-wedge casts. Furthermore, permafrost degradation occurred during late Pleistocene times (13–10 ka) and was absent during the early Holocene. These permafrost structures mark the southernmost evidence of permafrost in northern Asia during late Quaternary times and indicate that the mean annual air temperature was below approximately −6°C during their formation. © 1998 John Wiley & Sons, Ltd.     

Can One-Run-Fixed-Arrhenius Kerogen Analysis Provide Comparable Organofacies Results to Detailed Palynological Analysis? A Case Study from a Prospective Mississippian Source Rock Reservoir (Bowland Shale,UK)

Natural Resources Research - Organofacies analysis, a fundamental component within source rock appraisal based on the study of kerogen within a source rock, is typically produced from microscopy...