Rates of sediment accumulation in pollen cores from small lakes and mires of eastern North America

Data from 291 small lakes and mires in eastern North America provide information on the natural variability of rates of sediment accumulation in these environments over the last 18,000 yr. Accumulation rates were calculated by linear interpolation between radiocarbon and biostratigraphic dates from sediment cores taken for pollen analysis. Within the data set, the rates were lognormally distributed with a mean accumulation rate of 91 cm/10³ yr, and a range from less than 1 to over 3500 cm/10³ yr. The accumulation rate data were divided into five subsets that were temporally or spatially distinct and therefore represent different geomorphic and climatic conditions at the time of deposition. Sediments deposited in basins north of 50°N, south of 40°N, and before 10,000 yr B.P. accumulated at much slower rates than sediments accumulating in midlatitude basins (between 40° and 50°N) between 10,000 and 330 yr B.P. Sediment accumulation over the last 330 yr has, on average, been at rates four to five times faster than any time previously. Inorganic sediments that could be radiocarbon-dated have accumulated at significantly lower rates than organic sediments, reflecting differences in depositional processes. For midlatitude basins during the Holocene, the most likely rate of continuous sediment accumulation within our data set is 65 cm/10³ yr. Rates below 10 cm/10³ yr are likely to be associated with nonconstant processes of sediment accumulation.     

Evaluation of a Carbon Adsorption Method for Sampling Gasoline Vapors in the Subsurface

Monitoring of the vapor phase has emerged as a very convenient method for detecting volatile organic contaminants in the subsurface. It can provide a reliable way of placing ground water monitoring and recovery wells. The most common method uses a driveable ground probe (DGP) to extract a vapor-phase sample followed by direct injection of the vapor into a portable gas chromatograph (GC). However, many regional offices of regulatory agencies and consultants do not have ready access to such equipment. This research explores an alternative–the carbon adsorption method—in which the vapor is withdrawn by the DGP but concentrated on a small activated carbon trap (150mg). The carbon traps can be returned to a central laboratory for solvent extraction and GC analysis. This provides the advantages of increased sensitivity, reduction in field equipment and convenience of in-lab analyses (multiple GC injections are possible). A simple DGP and carbon trap system was constructed and tested at a field site. Vapor-phase concentrations of target compounds present in gasoline were mapped quite conveniently, ranging from 10,000μg/liter (vapor phase) to less than 10μg/L. These concentrations were also shown to decrease in the direction of the ground surface, as expected. Measurements of target compounds in soil showed that the vapor phase contributed a large fraction of the total contaminant burden where a non-aqueous-phase layer (NAPL) had been identified; as important, however, is the rather uniform contamination of the soil outside the NAPL region. Finally, the concentrations of target compounds in the vapor phase and ground water could be related in a manner roughly described by a simple equilibrium model, although exceptions were noted.     

Experimental determination of the solubility of carbon dioxide in molten basalt at low pressure

We report the first measurements of CO₂ solubility in molten basalt at pressures comparable to those at which submarine basalts erupt. A basalt from the Juan de Fuca ridge was equilibrated with CO₂-rich vapor at 1200°C, 100–1500 bar for up to four hours. After quenching, the glass was analyzed for dissolved carbonate ions by infrared spectroscopy. No forms of dissolved CO₂ other than carbonate were detected. CO₂ solubility is roughly a linear function of pressure at these low pressures. The experimentally determined solubility differs from previous estimates based on CO₂ concentrations of submarine glasses, on CO₂ solubilities in basaltic liquids at significantly higher pressures, and on CO₂ concentrations of glasses equilibrated with H₂OCO₂ vapor. Our results are compatible with those obtained previously at higher pressures on a molten Kilauea tholeiite only if there is a significant positive dependence of carbonate solubility on temperature.CO₂ contents of mid-ocean ridge glasses measured by infrared spectroscopy are generally higher than would be expected based on solubilities at the hydrostatic pressures for the water depths from which the glasses were recovered, but the lowest dissolved CO₂ contents agree with the experimentally determined solubilities. We propose that submarine glasses with low CO₂ contents were quenched from magmas that were able to degas because they rose slowly from depth. The common occurrence of glasses with dissolved CO₂ contents in excess of the experimentally determined solubility suggests they were quenched from magmas that ascended too rapidly to degas fully. In conjunction with our solubility data, the highest CO₂ contents allow minimum estimates of depths to magma chambers. Depths of 2.3 km beneath the ridge are indicated for the East Pacific Rise at 21°N, in agreement with geophysical constraints.     

Age dependence of the composition of continental crust: evidence from Nd isotopic variations in granitic rocks

The Nd isotopic systematics of the sources of crustal granitic rocks are used to estimate the Sm/Nd ratio of the continental crust as a function of its age. It is found that the Sm/Nd value of granite magma sources in continental crust increases from about 0.47 to 0.64 times the chondritic value with decreasing age from the Early Archean to the Late Proterozoic. This trend is opposite to that inferred for the crust from rare earth element patterns in sedimentary rocks. The observed trend may apply strictly only to the felsic portions of the crust, but unless older crust contains a much higher percentage of mafic material than young crust (50% versus 0%), the direction of the trend also applies to the bulk crust. Because some portion of the earth's oldest crust has probably been destroyed by subsequent processes, the trend could conceivably be the result of preservational bias rather than a real shift in crustal composition with time. The isotopic data, combined with the crustal age distribution, indicate that the Sm/Nd value of the bulk continental crust is not lower than 0.60 times the chondritic value. This limit and estimates of the Nd concentration of the crust are consistent with the mass balance that equates the Nd in the continents to that missing from the upper mantle down to a depth of about 700 km.     

A demonstration of 1–2 parts in 107 accuracy using GPS

By interferometric analysis ofGPS phase observations made at Owens Valley, Mojave, and Mammoth Lakes, California, we determined the coordinate components of the71–245–313 km triangle of baselines connecting these sites. A separate determination was made on each of four days, April 1–4, 1985. The satellite ephemerides used in these determinations had been derived from observations on other baselines. Therms scatters of the four daily determinations of baseline vector components about their respective means ranged from a minimum of6 mm for the north component of the71-km baseline to a maximum of34 mm for the vertical component of the245-km baseline. To test accuracy, we compared the mean of ourGPS determinations of the245-km baseline between Owens Valley and Mojave with independent determinations by others using very-long-baseline interferometry(VLBI) and satellite laser ranging(SLR). TheGPS-VLBI difference was within 2 parts in10 ⁷ for every vector component. TheGPS-SLR difference was within6 parts in10 ⁸ in the horizontal coordinates, but83 mm in height.     

Pressure, Temperature, and Structural Evolution of the Orfordville Belt, West-Central New Hampshire

Metamorphic P-T paths have been derived for staurolite-kyanitegrade and garnet grade rocks from the Orfordville Belt, west-centralNew Hampshire. P-T paths calculated from garnet zoning are consistentwith parageneses observed in amphibolites as determined froma petrogenetic grid derived for amphibolites. The P-T pathsfrom the staurolite-kyanite zone show a pressure maximum at6.5 to 7.5 kb and {small tilde} 500?C followed by heating anddecompression to approximately 5 kb, 580?C, and a final phaseof near isobaric cooling. The path from the garnet zone is similar,but does not show the final phase of isobaric cooling. Both nappe-stage and dome-stage folds are observed in the OrfordvilleBelt. Comparison of mesoscale structures with mineral growthindicates that the nappe stage deformation occurred near orbefore the pressure maximum and dome stage deformation tookplace along the decompression-heating path. The last phase ofnear isobaric cooling may have resulted from rapid verticalreadjustment of the Orfordville Belt.     

Occurrence of wide-chain Ca-pyriboles as primary crystals in the Salton Sea Geothermal Field,California, USA

Amphiboles and pyroxenes occurring in the Salton Sea Geothermal Field were found to contain coherent intergrowths of chain silicates with other than double and single chain widths by using transmission and analytical electron microscopy. Both occur in the biotite zone at the temperature (depth) interval of 310° C (1,060 m) to 330° C (1,547m) which approximately corresponds to temperatures of the greenschist facies. The amphiboles occur as euhedral fibrous crystals occupying void space and are composed primarily of irregularly alternating (010) slabs of double or triple chains, with rare quadruple and quintuple chains. Primary crystallization from solution results in euhedral crystals. Clinopyroxenes formed mainly as a porefilling cement and subordinately as prismatic crystals coexisting with fibrous amphiboles. Fine lamellae of double and triple chains are irregularly intercalated with pyroxene. AEM analyses yield formulae (Ca_1.8Mg_2.9Fe_1.9Mn_0.1) Si₈O_21.8(OH)_1.8 (310° C) and (Ca_2.0Fe_2.5Mg_2.3) Si₈O_21.8 (OH)_2.0 (330° C) for amphiboles and (Ca_1.1Fe_0.6Mg_0.3) Si₂O₆ for clinopyroxene. Thermodynamic calculations at P_fluid=100 bar of equilibrium reactions of (1) 3 chlorite +10 calcite + 21 quartz = 3 actinolite + 2 clinozoisite + 8 H₂O + 10 CO₂ and (2) actinolite+ 3 calcite+ 2 quartz = 5 clinopyroxene + H₂O + 3 CO₂ using Mg-end member phases indicate that formation of amphibole and pyroxene require very water-rich conditions at temperatures below 330° C.Contribution No. 420 from the Mineralogical Laboratory, Department of Geological Sciences, University of Michigan, Ann Arbor, Michigan