Antioxidants and chromium reductases by <Emphasis Type="Italic">Penibacillus</Emphasis> species enhance the growth of soybean under chromium stress

Hexavalent chromium [Cr(VI)] is used in various industries, but its improper and uncontrolled discharge contaminates the environment. In order to circumvent chromium toxicity, several physicochemical and biological strategies have been employed. Among biological approach, microbes convert toxic Cr(VI) to less soluble Cr(III) form and hence can be used to detoxify/remove Cr(VI) from contaminated environment. Considering these, present study was designed to assess the effect of chromium reductases and antioxidants secreted by Penibacillus species to detoxify Cr(VI) and concurrently to augment soybean growth. Bacterial strains (MAI1 and MAI2) were identified as Penibacillus sp. using 16S rRNA gene. Penibacillus species reduced Cr(VI) significantly at pH 7. Maximum Cr(VI) was reduced at 50 and 100 µg/ml of Cr(VI) concentrations. Penibacillus sp. also reduced Cr(VI) significantly at 25 and 35 °C as well as 1 g sodium alginate in 1 g polyvinyl alcohol. Bacterial strains reduced Cr(VI) into Cr(III) which were detected as 33 ± 1 and 35 ± 1 µg/ml in supernatant and 67 ± 2.5 and 65 ± 1 µg/ml in cell debris, respectively, after 120 h. Chromium reductase found in cell-free extract reduced almost all Cr(VI) compared to those observed in cell debris. Both malondialdehyde and antioxidant levels were increased with gradual increase in Cr(VI) concentration. Penibacillus species inoculated soybean plants had better growth and photosynthetic pigments under Cr(VI) stress.     

Assessing agricultural and hydrological drought vulnerability in a savanna ecological zone of Sub-Saharan Africa

Natural Hazards - Despite measures to mitigate drought, study on the extent of agricultural and hydrological drought vulnerability is still neglected in the savanna ecological zone of Nigeria. This...     

Interaction of corporate and urban systems: accumulation of intangible assets

This study develops a conceptual framework of the relationship between corporate systems and urban systems in the process of intangible asset accumulation and conducts case studies involving two distinctive and contrasting global firms. Intangible assets are important in maintaining the competitive advantage of cities and regions. The accumulation of local intangibles is the result of the evolutionary development of the relationship between the corporate system and the urban system. The results of the study suggest that the intangible assets of firms are critical in ensuring their competitiveness within a knowledge-based information society.     

Structural composition and sediment transfer in a composite cirque glacier: Glacier de St. Sorlin,France

This paper considers the links between structure, sediment transport and sediment delivery at Glacier de St. Sorlin, France. Sediment transported by the glacier is concentrated at flow‐unit boundaries as medial moraines, controlled by the position of bedrock outcrops in the accumulation area. Rockfall entrained within primary stratification is tightly folded at flow‐unit boundaries under high cumulative strains and laterally compressive stress. High cumulative strains and laterally compressive stresses lead to the development of longitudinal foliation from primary stratification. Folding elevates subglacial sediments into foliation‐parallel debris ridges, which are exposed in the ablation area. Crevasses and shear planes within the glacier have little control on sediment transport. Debris stripes in the proglacial area are morphologically similar to foliation‐parallel debris ridges; however, they are not structurally controlled, but formed by fluvial erosion. The conclusion of this study is that at Glacier de St. Sorlin proglacial sediment‐landform associations are subjected to intense syn‐ and post‐depositional modification by high melt‐water discharges, hence their composition does not reflect that of sediments melting out at the terminus. The action of melt water limits the potential of the sedimentary record to be used to constrain numerical models of past glacier dynamics in debris‐poor glacierized Alpine catchments. Copyright © 2008 John Wiley & Sons, Ltd.     

Straight from the source's mouth: Controls on field-constrained sediment export across the entire active Corinth Rift,central Greece

The volume and grain-size of sediment supplied from catchments fundamentally control basin stratigraphy. Despite their importance, few studies have constrained sediment budgets and grain-size exported into an active rift at the basin scale. Here, we used the Corinth Rift as a natural laboratory to quantify the controls on sediment export within an active rift. In the field, we measured the hydraulic geometries, surface grain-sizes of channel bars and full-weighted grain-size distributions of river sediment at the mouths of 47 catchments draining the rift (constituting 83% of the areal extent). Results show that the sediment grain-size increases westward along the southern coast of the Gulf of Corinth, with the coarse-fraction grain-sizes (84^th percentile of weighted grain-size distribution) ranging from approximately 19 to 91 mm. We find that the median and coarse-fraction of the sieved grain-size distribution are primarily controlled by bedrock lithology, with late Quaternary uplift rates exerting a secondary control. Our results indicate that grain-size export is primarily controlled by the input grain-size within the catchment and subsequent abrasion during fluvial transport, both quantities that are sensitive to catchment lithology. We also demonstrate that the median and coarse-fraction of the grain-size distribution are predominantly transported in bedload; however, typical sand-grade particles are transported as suspended load at bankfull conditions, suggesting disparate source-to-sink transit timescales for sand and gravel. Finally, we derive both a full Holocene sediment budget and a grain-size-specific bedload discharged into the Gulf of Corinth using the grain-size measurements and previously published estimates of sediment fluxes and volumes. Results show that the bedload sediment budget is primarily comprised (~79%) of pebble to cobble grade (0.475–16 cm). Our results suggest that the grain-size of sediment export at the rift scale is particularly sensitive to catchment lithology and fluvial mophodynamics, which complicates our ability to make direct inferences of tectonic and palaeoenvironmental forcing from local stratigraphic characteristics.     

The Gulf: A young sea in decline

This review examines the substantial changes that have taken place in marine habitats and resources of the Gulf over the past decade. The habitats are especially interesting because of the naturally high levels of temperature and salinity stress they experience, which is important in a changing world climate. However, the extent of all natural habitats is changing and their condition deteriorating because of the rapid development of the region and, in some cases from severe, episodic warming episodes.Major impacts come from numerous industrial, infrastructure-based, and residential and tourism development activities, which together combine, synergistically in some cases, to cause the observed deterioration in most benthic habitats. Substantial sea bottom dredging for material and its deposition in shallow water to extend land or to form a basis for huge developments, directly removes large areas of shallow, productive habitat, though in some cases the most important effect is the accompanying sedimentation or changes to water flows and conditions. The large scale of the activities compared to the relatively shallow and small size of the water body is a particularly important issue.Important from the perspective of controlling damaging effects is the limited cross-border collaboration and even intra-country collaboration among government agencies and large projects. Along with the accumulative nature of impacts that occur, even where each project receives environmental assessment or attention, each is treated more or less alone, rarely in combination. However, their combination in such a small, biologically interacting sea exacerbates the overall deterioration. Very few similar areas exist which face such a high concentration of disturbance, and the prognosis for the Gulf continuing to provide abundant natural resources is poor.     

ToF-SIMS and SEM study on the preferential oxidation of chalcopyrite

Chalcopyrite is known to be slow reacting mineral in hydrometallurgical systems and is considered one of the most inert sulphide minerals with respect to leaching. Such character of chalcopyrite seems to be linked to a formation of a passive layer on its surface. This work reports that freshly fractured chalcopyrite surfaces exhibit highly selective reactivity depending on the exposed fracture planes. ToF-SIMS was used to qualitatively characterize various fracture planes in freshly fractured chalcopyrite particles, prior to and after hydrometallurgical treatment. It was found that, prior to treatment, certain areas exhibited pronounced contamination from atmospheric hydrocarbons; whereas, others were highly unreactive and remarkably free from adventitious hydrocarbon contamination. The positive ion spectra recorded from these areas were found to be dominated by peaks from Fe- and Cu-elements and related compounds. The negative ion spectra for the reactive areas on the other hand showed a high content of oxidized (sulphur) species.The differences between the areas of low and high reactivity, as detected after leaching, were more subtle than prior to leaching; whereas, SEM analysis showed clear evidence for selective attack of ferric sulphate to specific planes. Furthermore, it was shown that, when chalcopyrite is in intimate contact with pyrite, it experiences an enhanced oxidation compared to when there is no electric contact with pyrite.Attempts were made to explain the preferential oxidation observed based on the different chemistry of the fracture surfaces.     

Systematically variable geometry and architecture of incised-valley fills controlled by orbital forcing: A conceptual model from the Pennsylvanian Breathitt Group (Kentucky,USA)

Incised-valley fills preserved within ancient coastal to shallow-marine successions represent important archives of environmental and sea-level change. Most current knowledge about the origin of incised valleys stems from Quaternary case studies; however, research on pre-Quaternary examples can shed light on valley formation and evolution across longer timespans. This article describes different types of incised-valley fills from Lower to Middle Pennsylvanian fluvio-deltaic successions of the Breathitt Group (eastern Kentucky), accumulated in the Central Appalachian Foreland under prevalent glacioeustatic forcing driven by Gondwanan glaciations. Based on well-established criteria for their recognition, numerous incised-valley fills were identified from outcrop and subsurface data through more than 300 m of clastic successions consisting of fourth-order stratigraphic sequences stacked into third-order composite sequences. Incised-valley fills were categorized into three archetypes based on lateral extent and aspect ratio (relatively wide versus narrow valley fills), nature of infill (fully continental versus mixed marine and continental facies associations) and relationships to underlying coal zones (truncating versus non-truncating). The systematic occurrence of each incised-valley fill type at specific stratigraphic positions within every third-order sequence suggests control by a periodic allogenic factor. Valley-fill archetypes are interpreted in terms of variable accommodation-supply ratios driven by variable duration of formative base-level cycles. For example, relatively wide incised-valley fills with alluvial infill evolved during long-lived cycles whose prolonged base-level drawdown maintained low accommodation/supply ratios. Deeper valleys with low aspect ratios and mixed marine-continental infills were generated by short-lived base-level drawdown that forced higher accommodation/supply ratios. Available chronological data for the studied successions consent to estimate base-level cycles spanning 10^4–5 years that were likely modulated by interference patterns of orbital parameters (obliquity and eccentricity) via global climate and glacioeustatic fluctuations. This conceptual model, relating incised-valley fill morphometry and internal architecture to orbital forcing patterns, provides a possible approach to predicting and interpreting incised-valley fill variability through successions accumulated during icehouse conditions.     

Three-dimensional numerical modeling of cohesive sediment transport and wind wave impact in a shallow oxbow lake

It was observed that in some closed inland lakes sediment transport was dominated by wind-induced currents, and the sediment resuspension was primarily driven by wind-induced waves. This paper presents the development and application of a three-dimensional numerical model for simulating cohesive sediment transport in water bodies where wind-induced currents and waves are important. In the model, the bottom shear stresses induced by currents and waves were calculated, and the processes of resuspension (erosion), deposition, settling, etc. were considered. This model was first verified by a simple test case consisting of the movement of a non-conservative tracer in a prismatic channel with uniform flow, and the model output agreed well with the analytical solution. Then it was applied to Deep Hollow Lake, a small oxbow lake in Mississippi. Simulated sediment concentrations were compared with available field observations, with generally good agreement. The transport and resuspension processes of cohesive sediment due to wind-induced current and wave in Deep Hollow Lake were also discussed.