Evidence for Non-Conservative Behaviour of Chlorine in Humid Tropical Environments

The knowledge of the biogeochemical cycle of chlorine (Cl)is important since this element is used as a tracer of geochemical and hydrological processes in oceanic or continental environments. More specifically, Cl can be used to correct surface water composition from atmospheric contribution in order to calculate precise chemical weathering rates in watersheds. Beyond the problem of potential Cl sources in a given watershed, which is directly related to the lithology, vegetation, and industrial activities, the Cl normalization is based on the assumption that this element behaves conservatively during surface processes (e.g., chemical weathering, adsorption/desorption processes).The purpose of the present study is to forecast the geochemical behavior of Cl in a forested ecosystem located under humid tropical environment.For this reason, we have analyzed the Cl (and also Ca and Na) concentrations ofsurface waters (rainwater, groundwater, river water) over a two-year period in the Nsimi–Zoetele watershed (Cameroon).The Cl mass balance for the watershed appears to be equilibrated over the studied period (1995–1996) but Cl behavior in Mengong River draining the watershed suggests a non-conservative behavior. Indeed, Cl concentrationsin the Mengong River are low during dry seasons and high during wet seasons, which is the reverse tendency to what is usually observed taking into account dilution and evaporation processes. As Cl concentrations in the Mengong River are lower than those measured in all the feeding reservoirs, Cl should be adsorbed onto the soils of the watershed. However, as the Cl mass balance is equilibrated over the whole-year, Cl should be adsorbed and releasedat a seasonal scale. The results we obtained for this small watershed were not generalized for a larger studied basin (i.e., Nyong River basin). Even if these results should be followed by further investigations, this study suggests that Cl normalization should be used with caution to avoid under- or over-estimation of chemical weathering rates.     

Development of a generic concept to analyze the accessibility of emergency facilities in critical road infrastructure for disaster scenarios: exemplary application for the 2017 wildfires in Chile and Portugal

Natural Hazards - Natural hazards such as earthquakes, floods, or wildfires pose a serious threat to road infrastructure. Especially in emergency situations, the society depends on the road...     

Present weathering rates in a humid tropical watershed: Nsimi, South Cameroon

The study of biogeochemical and hydrological cycles in small experimental watersheds on silicate rocks, common for the Temperate Zone, has not yet been widely applied to the tropics, especially humid areas. This paper presents an updated database for a six-year period for the small experimental watershed of the Mengong brook in the humid tropics (Nsimi, South Cameroon). This watershed is developed on Precambrian granitoids (North Congo shield) and consists of two convexo-concave lateritic hills surrounding a large flat swamp covered by hydromorphic soils rich in upward organic matter. Mineralogical and geochemical investigations were carried out in the protolith, the saprolite, the hillside lateritic soils, and the swamp hydromorphic soils. Biomass chemical analyses were done for the representative species of the swamp vegetation. The groundwater was analysed from the parent rock/saprolite weathering front to the upper fringe in the hillside and swamp system. The chemistry of the wet atmospheric and throughfall deposits and the Mengong waters was monitored.In the Nsimi watershed the carbon transfer occurs primarily in an organic form and essentially as colloids produced by the slow biodegradation of the swamp organic matter. These organic colloids contribute significantly to the mobilization and transfer of Fe, Al, Zr, Ti, and Th in the uppermost first meter of the swamp regolith. When the organic colloid content is low (i.e., in the hillside groundwater), Th and Zr concentrations are extremely low (<3 pmol/L, ICP-MS detection limits). Strongly insoluble secondary thorianite (ThO₂) and primary zircon (ZrSiO₄) crystals control their mobilization, respectively. This finding thus justifies the potential use of both these elements as inert elements for isoelement mass balance calculations pertaining to the hillside regolith.Chloride can not be used as a conservative tracer of hydrological processes and chemical weathering in this watershed. Biogenic recycling significantly influences the low-Cl input fluxes. Sodium is a good tracer of chemical weathering in the watershed. The sodium solute flux corrected from cyclic salt input was used to assess the chemical weathering rate. Even though low (2.8 mm/kyr), the chemical weathering rate predominates over the mechanical weathering rate (1.9 mm/kyr). Compared to the Rio Icacos watershed, the most studied tropical site, the chemical weathering fluxes of silica and sodium in the Mengong are 16 and 40 times lower, respectively. This is not only related to the protective role of the regolith, thick in both cases, but also to differences in the hydrological functioning. This is to be taken into account in the calculations of the carbon cycle balance for large surfaces like that of the tropical forest ecosystems on a stable shield at the global level.     

Bloom of the Yessotoxin producing dinoflagellate Protoceratium reticulatum (Dinophyceae) in Northern Chile

Potential spawning habitat is defined as the area where environmental conditions are suitable for spawning to occur. Spawning adult data from the first quarter (January–March) of the International Bottom Trawl Survey have been used to study the inter-annual variability of the potential spawning habitat of North Sea plaice from 1980 to 2007. Generalised additive models (GAM) were used to create a model that related five environmental variables (depth, bottom temperature and salinity, seabed stress and sediment type) to presence–absence and abundance of spawning adults. Then, the habitat model was applied each year from 1970 to 2007 to predict inter-annual variability of the potential spawning habitat. Predicted responses obtained by GAM for each year were mapped using kriging. A hierarchical classification associated with a correspondence analysis was performed to cluster spawning suitable areas and to determine how they evolved across years. The potential spawning habitat was consistent with historical spawning ground locations described in the literature from eggs surveys. It was also found that the potential spawning habitat varied across years. Suitable areas were located in the southern part of the North Sea and along the eastern coast of England and Scotland in the eighties; they expanded further north from the nineties. Annual survey distributions did not show such northward expansion and remained located in the southern North Sea. This suggests that this species' actual spatial distribution remains stable against changing environmental conditions, and that the potential spawning habitat is not fully occupied. Changes in environmental conditions appear to remain within plaice environmental ranges, meaning that other factors may control the spatial distribution of plaice spawning habitat.     

Neoproterozoic tectonothermal evolution of the Central Eastern Desert, Egypt: a slow velocity tectonic process of core complex exhumation

Regional cooling in the course of Neoproterozoic core complex exhumation in the Central Eastern Desert of Egypt is constraint by ⁴⁰Ar/³⁹Ar ages of hornblende and muscovite from Meatiq, Sibai and Hafafit domes. The data reveal highly diachronous cooling with hornblende ages clustering around 580 Ma in the Meatiq and the Hafafit, and 623 and 606 Ma in the Sibai. These ⁴⁰Ar/³⁹Ar ages are interpreted together with previously published structural and petrological data, radiometric ages obtained from Neoproterozoic plutons, and data on sediment dynamics from the intramontane Kareim molasse basin. Early-stage low velocity exhumation was triggered by magmatism initiated at 650 Ma in the Sibai and caused early deposition of molasses sediments within rim synforms. Rapid late stage exhumation was released by combined effect of strike-slip and normal faulting, exhumed Meatiq and Hafafit domes and continued until 580 Ma. We propose a new model that adopts core complex exhumation in oblique island arc collision-zones and includes transpression combined with lateral extrusion dynamics. In this model, continuous magma generation weakened the crust leading to facilitation of lateral extrusion tectonics. Since horizontal shortening is balanced by extension, no major crustal thickening and no increase of potential energy (gravitational collapse) is necessarily involved in the process of core complex formation. Core complexes were continuously but slowly exhumed without creating a significant mountain topography.     

The use of GPS for marine positioning in Germany—requirements,experience, and concepts

Abstract

While beginning to establish a German Civil GPS Information and Observation Service in 1990, the actual and (near) future GPS market in Germany was analyzed. In addition, the feasibility of using GPS for water authority tasks has been studied during past years. Typical capabilities in this area are real‐time positioning for hydrographic surveying (kinematic application) and precise transfer of levels to tide gauges and verification at offshore positions.

The article describes the user interests, the requirements, some of the test campaigns, and the derived concepts for future applications.     

An infrared imaging search for low‐mass companions to members of the young nearby β Pic and Tucana/Horologium associations

We present deep high dynamic range infrared images of young nearby stars in the Tucana/Horologium and β Pic associations, all ∼10 to 35 Myrs young and at ∼10 to 60 pc distance. Such young nearby stars are well‐suited for direct imaging searches for brown dwarf and even planetary companions, because young sub‐stellar objects are still self‐luminous due to contraction and accretion. We performed our observations at the ESO 3.5m NTT with the normal infrared imaging detector SofI and the MPE speckle camera Sharp‐I. Three arc sec north of GSC 8047‐0232 in Horologium a promising brown dwarf companion candidate is detected, which needs to be confirmed by proper motion and/or spectroscopy. Several other faint companion candidates are already rejected by second epoch imaging. Among 21 stars observed in Tucana/Horologium, there are not more than one to five brown dwarf companions outside of 75 AU (1.5″ at 50 pc); most certainly only ≤5% of the Tuc/HorA stars have brown dwarf companions (13 to 78 Jupiter masses) outside of 75 AU. For the first time, we can report an upper limit for the frequency of massive planets (∼10 M_jup) at wide separations (∼100 AU) using a meaningfull and homogeneous sample: Of 11 stars observed sufficiently deep in β Pic (12 Myrs), not more than one has a massive planet outside of ∼100 AU, i.e. massive planets at large separations are rare (≤9%). (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Catalogue of Shakhbazian compact groups of galaxies. V.

We present the position and references (if available) of all the galaxies of the Shakhbazian survey being the largest survey of compact galaxy groups. For the estimation of the coordinates the Digitized Sky Survey was used. This paper contains the data of 48 Shakhbazian groups north of δ > + 2deg;30' (Shkh 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 22, 23, 25, 26, 28, 29, 31, 34, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56).