A reconnaissance study of oxygen, hydrogen and strontium isotopes in geochemically diverse lakes, Western Nebraska, USA

Reconnaissance ¹⁸O,, D, and ⁸⁷Sr data for fifteen lakes in the Western Lakes Region of the Sand Hills of Nebraska indicate dynamic hydrologic systems. The rather narrow range of ⁸⁷Sr from lake water (1.1 to 2.1) and groundwater (0.9 to 1.7) indicates that the groundwater is generally unradiogenic. Groundwater residence times and relatively unradiogenic volcanic ash within the dune sediments control the ⁸⁷Sr values. Based on the mutual variations of ¹⁸O and D, the lakes can be divided into three groups. In Group 1, both ¹⁸O and D values increase from spring to fall. The ¹⁸O and D values in Group 2 decreased from spring to fall. Group 3 are ephemeral lakes that went dry some time during 1992. The data and isotopic modeling show that variations in the ratio of evaporation relative to groundwater inflow, local humidity conditions, and the _a has substantial influence on the isotopic composition. In addition, isotopic behavior in ephemeral lakes can be rather unusual because of the changing activities of water and mineral precipitation and redissolution. The annual and interannual isotopic variability of these lakes which is reflected in the paleonvironmental indicators may be the rule rather than the exception in these types of systems.     

Zr-in-rutile thermometry in blueschists from Sifnos, Greece

Zr-in-rutile thermometry on samples of blueschist from Sifnos, Greece, yields temperatures that reflect progressive crystallization of rutile from ca. 445 to 505°C with an analytical precision of + 18/−27 and ± 10°C using the electron microprobe and ± 1.5–3.5°C using the ion microprobe. Individual grains are generally homogeneous within analytical uncertainty. Different grains within a single sample record temperature differences as large 55°, although in most samples the range of temperatures is on the order of 25°. In several samples, Zr-in-rutile temperatures from grains within garnet are lower than temperatures from matrix grains, reflecting growth of rutile with increasing temperature of metamorphism. Although the specific rutile-producing reactions have not been identified, it is inferred that rutile grows from either continuous reaction involving the breakdown of lower grade phases (possibly ilmenite), or from pseudomorph reactions involving the breakdown of relic igneous precursors at blueschist-facies conditions. No systematic variation in rutile temperatures was observed across the blueschist belt of northern Sifnos, consistent with the belt having behaved as a coherent block during subduction.     

Assessing selected natural and anthropogenic impacts on freshwater lens morphology on small barrier Islands: Dog Island and St. George Island, Florida, USA

Abstract The freshwater lens morphologies of the barrier islands Dog Island and St. George Island on the panhandle coast of Florida (FL), USA, are controlled to varying degrees by both natural and anthropogenic factors. Variable-density groundwater flow models confirm that spatial variability of recharge values can account for the observed lens asymmetry on these islands. The depth to the base of the lens does not vary significantly seasonally. Human development has altered recharge patterns in some areas, locally thinning the freshwater lens. Aqueduct water supply to St. George Island represents 7–25% of natural recharge; higher recharge rates are required to simulate the lens on St. George Island than on Dog Island. On both islands, coastal erosion rates are sufficiently rapid that the freshwater lens may not be in equilibrium with current boundary conditions.

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Resumen Las morfologías de los lentes de agua dulce en las islas de barrera: Islas Dog y St. George, en la costa alargada y estrecha de Florida, EUA, están controladas en diferentes grados por factores antropogénicos y naturales. Los modelos de flujo con densidad variable del agua subterránea, confirman que la variabilidad espacial de los valores de recarga, pueden ser la causa de la asimetría observada en los lentes de estas islas. La profundidad hasta la base de los lentes no varía significativamente con las estaciones climáticas. El desarrollo humano ha alterado las tendencias de recarga en algunas áreas, causando adelgazamiento local de los lentes de agua dulce. El abastecimiento de agua del acueducto en la Isla St. George, representa entre 7% y 25% de la recarga natural; por otro lado se necesitan cantidades mayores de recarga para simular los lentes en la Isla St. George que en la Isla Dog. En ambas islas, las tasas de erosión costera son tan rápidas, que las lentes de agua dulce podrían no estar en equilibrio con las condiciones actuales de frontera.

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Résumé La morphologie des lentilles deau douce des îles de Dog et de St. George, situés dans le district côtier de Florida-Etats Unis est contrôlé dans une mesure variable par des facteurs naturelles et humaines. Les modèles découlement à densité variable des eaux souterraines confirment que la variation spatiale de la recharge peut expliquer les asymétries observées des lentilles des cettes îles. La profondeur des lentilles ne présente pas des variations saisonnières importantes. Les activités humaines ont modifié la recharge dans certaines zones en amincissant localement les lentilles deau douce. Lalimentation en eaux de lîle de St. George représente 7–25% de la recharge naturelle; pour simuler les lentilles de lîle de Dog il a été nécessaire dintroduire des valeurs plus élevées de la recharge par rapport aux ceux utilisés pour lîle de St. George. Pour les deux îles lérosion côtière est assez rapide ainsi que les lentilles de eau douce ne sont pas en équilibre avec les conditions à la frontière.

     

Secondary flow caused by differential roughness,Langmuir circulations,and their effect on the development of sand ribbons

The process of Differential Roughness Secondary Flow (DRSF), hitherto little recognized, recently was demonstrated in a wind tunnel and in a flume. It is suggested here the DRSF may, in the natural environment, play an important part in the persistence and sharp definition of sand ribbons, previously initiated by other processes. In 1980 Karl described a series of sand ribbons, alternating with exposed substrate, which he attributed to the effect of Langmuir circulations. Although Langmuir Circulation Secondary Flow (LCSF) may indeed, in some cases, initiate sand ribbons, the sharply-defined edges typical of these features are explained better by DRSF.     

Sediment oxygen profiles in a super-oxygenated antarctic lake

Perennially ice-covered lakes are found in the McMurdo Dry Valleys of southern Victoria Land, Antarctica. In contrast to temperate lakes that have diurnal photic periods, antarctic (and arctic) lakes have a yearly photic period. An unusual feature of the antarctic lakes is the occurrence of O2 at supersaturated levels in certain portions of the water column. Here we report the first sediment O2 profiles obtained using a microelectrode from a perennially ice-covered antarctic lake. Sediment cores collected in January and October 1987 from Lake Hoare in Taylor Valley show oxygenation down to 15, and in some cases, 25 cm. The oxygenation of sediments several centimeters below the sediment-water interface is atypical for lake sediments and may be characteristic of perennially ice-covered lakes. There is a significant difference between the observed January and October sediment O2 profiles. Several explanations may account for the difference, including seasonality. A time-dependent model is presented which tests the feasibility of a seasonal cycle resulting from the long photoperiod and benthic primary production in sediments overlain by a highly oxygenated water column.     

Mediterranean outflow through the Strait of Gibraltar since 18,000 Years B.P.: Mineralogical and geochemical arguments

Data obtained from mineralogical and geochemical analyses of piston and gravity cores, recovered from an area off Lisbon (Portugal) to the Alboran Sea (Mediterranean), serve as a basis for better understanding the past 18,000 years of hydrological exchanges at Gibraltar. Tracers used in this study are smectite, kaolinite, Ta, Th, La. One of the primary sources of particles both into and out of the Mediterranean is the Guadalquivir River. These particles are transported back into the Atlantic in the Mediterranean outflow water, and deposited along the Iberian slope. No evidence for reversal of this outflow current was found in those cores, since 18,000 years B.P.     

Experimental stream acidification — the influence of sediment and streambed vegetation

An acidification experiment was conducted on a small stream in the Loch Ard area of central Scotland. The stream was chosen because of its large, flow related, variation in pH (5.9-4.0). Two acid additions were made to approximately pH 3.5–3.7. The results indicated a strong correlation between labile aluminium and hydrogen, and a noticeable hysteresis in the response of calcium and hydrogen. It is hypothesised that divalent cation response is a result of ion-exchange mechanisms involving the streambed vegetation, with aluminium release resulting primarily from exchange reactions with streambed sediment stores. Data from a program of stream spot sampling have been analysed in an attempt to elucidate the contribution of different sources of aluminium under different flow conditions. Streambed sources of aluminium contribute significantly under low flow conditions; however, at high flow, additional sources of aluminium must contribute to match observed streamwater chemistry.     

Nutrient mediated stress on the marine communities of a coastal lagoon (Puerto Galera, Philippines)

Puerto Galera Bay is a coastal lagoon with a variety of marine habitats and high species diversity. It is an area in the Phillippines where the growing influence of human activities is affecting the quality of its marine resources. This study examined the distribution and behaviour of nutrients and the physical hydrography of Puerto Galera Bay and determined how its physico-chemical nature affected the condition of biotic components in the bay. The relative importance of the nitrogen and phosphorus signals were used as indicators to implicate the influence of sewage and run-off into the bay. A nutrient pool accumulated in the bay as a result of low flushing rates. The interaction of hydrodynamic forcing with the biota have implications on the phytoplankton production and coral communities in the area.     

Short chain ladderanes: Oxic biodegradation products of anammox lipids

Anammox, the microbial anaerobic oxidation of ammonium by nitrite to produce dinitrogen gas, has been recognized as a key process in both the marine and freshwater nitrogen cycles, and found to be a major sink for fixed inorganic nitrogen in the oceans. Ladderane lipids are unique anammox bacterial membrane lipids that have been used as biomarkers for anammox bacteria in recent and past environmental settings. However, the fate of ladderane lipids during diagenesis is as of yet unknown. In this study, we performed oxic degradation experiments (at 20-100 °C) with anammox bacterial biomass to simulate early diagenetic processes occurring in the water column and at the sediment-water interface. Abundances of C₁₈ and C₂₀ ladderane lipids decreased with increasing temperatures, testifying to their labile nature. The most abundant products formed were ladderane lipids with a shorter alkyl side chain (C₁₄ and C₁₆ ladderane fatty acids), which was unambiguously established using two-dimensional NMR techniques on an isolated C₁₄-[3]-ladderane fatty acid. The most pronounced production of these short-chain lipids was at 40 °C, suggesting that degradation of ladderane lipids was microbially mediated, likely through a β-oxidation pathway. An HPLC-MS/MS method was developed for the detection of these ladderane alteration products in environmental samples and positively tested on various sediments. This showed that the ladderanes formed during degradation experiments also naturally occur in the marine environment. Thus, short-chain ladderane lipids may complement the original longer-chain ladderane lipids as suitable biomarkers for the detection of anammox processes in past depositional environments.